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The crystal structures of two complexes have been determined by X-ray diffraction as: complex (11) is distorted octahedron configuration,α=15. 9002 (6), b=16. 2413 (5), c=23. 4401 (8)〓,β=90°, V=6053. 2 (4)〓, Z=8 and R=0.0531; complex (8) is trigonal bipyramidal configuration,α=9. 3476 (8), b=17. 4236 (13), c=9. 7836 (8)〓,β=91. 197 (3)°, V=1593. 1 (2)〓, Z=2 and R=0.0325, which shows that three secondary amine groups (N-1, N-2, N-3) of the glycosylamine ligand forms the equatorial plane, and the tertiary amine (N-4) and one Cl〓 are pointed on the apical positions.

分别对其进行X-ray衍射分析可以得出：配合物(11)的晶体数据为α=15.9002(6)，b=16.2413(5)，c=23.4401(8)〓，β=90°，V=6053.2(4)〓，Z=8 and R=0.0531，为畸变的八面体构型，而配合物(8)中，α=9.3476(8)，b=17.4236(13)，c=9.7836(8)〓，β=91.197(3)°，V=1593.1(2)〓，Z=2 andR=0.0325，为三角双锥构型，糖胺配体的三个氮原子（N-1，N-2，N-3）位于赤道平面上，而另外一个氮原子（N-4）和一个Cl〓位于轴向上。

Base-catalysed hydrolysis is a typical course involving deprotonation leaving of Cl- and formation of the trigonal bipyramidal intermediate; edge displacement and ligand folding courses involve leaving of Cl- and formation of the square pyramidal intermediates.

典型的途径有经式异构体的碱催化水解，过程通过脱氢、脱氯以及三角双锥中间过渡态或中间体的形成来完成；另一途径为边沿取代及配体翻转历程，过程通过脱氯及四角锥的形成来完成。

It was found that when the 2,2'-bipyridyl was used as a ligand for metal complex formation,an abnormal new peak was observed obviously whether in fluorescence or absorption spectrum.It indicated that a new species was formed owing to the reaction between them.

发现当以联吡啶为络合物配体时，无论荧光和吸收光谱中均出现反常的新峰，这和 1-溴乙基苯与吡啶间发生了成盐反应有关。

The substituted group on the bipyridyl ligand in complex 2 could lose C2H4 neutral molecule under a higher CID fragmentation (such as CID 110 V), and its single charge ion is more stable than its double charge ion.

而络合物2在较高的CID电压下(1l0V)会发生联吡啶环上取代基的中性C2H4小分子丢失，其单电荷离子比二价电荷离子稳定。

A mixed ligand complex of manganese carbohydrazide azide, Mn2(N3)2 (CHZ=carbohydrazide), was synthesized and characterized by using elemental analysis and Fourier transform infrared spectrum.

合成了以碳酰肼为配体，以叠氮离子为混合配体的配合物：Mn2(N3)2，并对其进行了元素分析及红外表征。

In addition, nonlinear optical properties calculations reveal that the static first hyperpolarizabilities(β0) are greatly enhanced through the introduction of the carboxy group into the bpy ligand.

同时， 化合物非线性光学性质的计算结果表明，三种化合物均具有较大的一阶超极化率，联吡啶配体中吸电子基团的增加，使得分子内电子转移增强，导致一阶超极化率增大。

Fromylsalicylic, the derivative of salicylaldehyde, is an important organic ligand that can be used to synthesize centrosymmetric polynuclear complexes.

牛磺酸是一种含硫氨基酸，它作为一种非蛋白质类氨基酸，是人体必需的重要氨基酸之一，其独特的生理、药理功能，决定了它在医药、食品、化工等方面有着广泛的应用。

Methods The bone marrow mononuclear cells of rat were treated with 30 ng/mL macrophagecolony-stimulating factor and 50 ng/mL re- ceptor activator of NF-кB ligand and cultured for 6 days.

结论以M-CSF和RANKL作为诱导因子，对大鼠骨髓单个核细胞进行诱导培养可以获得具有典型的破骨细胞形态特征，可以表达特征性标志酶基因，且数量大、纯度高。

New flexible ligand derived from this achiral biphenylbackbone was applied in Cu-catalyzed enantioselective 1,4-conjugate additionsof Et_2Zn to chalcone.

进一步衍生得到的非手性联苯型P，N 配体，在Cu催化Et_2Zn对查耳酮的1，4-共轭加成反应中也进行了考察。

In the Cu-catalyzed enantioselective 1,4-conjugate addition of diethylzinc to acyclic enones, the reaction conditions, such as the amount of diethylzinc, solvents, temperature and the reaction time, were investigated in detail with 9a as the standard ligand and chalcone as the typical substrate.

考察了Et_2Zn量、溶剂、反应温度和反应时间等因素对反应的影响，得到了配体与Cu的摩尔比为2.5、1.5倍Et_2Zn用量、甲苯为反应溶剂、-20℃下反应6小时为不对称催化1，4-共轭加成的优化反应条件。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。