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The investigation of the catalytic activity and stereoselectivity of ligand 10 was also carried out under another standard set of K〓Fe 〓 conditions (〓/ligand/substrate=0.002: 0.01: 1). The AD reaction of seven olefins gave corresponding diols in 72～99% yield (except for ethyl cinnamate, 48%) and 91～99% ees, which was comparable to those obtained from the reactions using the commercial ligand 〓PHAL.

将单季铵盐手性配体10用于AD反应的另一个催化体系〓BuOH-H〓O/K〓Fe〓中考察其催化活性和立体选择性，在七种烯烃的AD反应中，〓、配体与底物的摩尔比为0.002：0.01：1时，化学产率为72～99％（肉桂酸乙酯除外，为48％），ee值为91～99.9％，与商品配体〓PHAL的催化结果相当。

The intensity sequence of the relative teratogenesis is ligandα、ligandβ and ligandγ.

其中视黄类受体RAR起主要作用，RAR的配体为强致畸物，相对致畸活性由强至弱依次为配体α、配体β和配体γ。

The novel complex (1) in which both benzylic nitrogens and heteroaromatic ones to the same metal ion with the rigid ligand imposed by the large heteroaromatic moiety first time was synthesized; a 2: 1 (ligand: metal ions) type complex which has steric resistance and strong thermochemical driving force was obtained. The crystal structures of characteristic ligand (LA4) and complexes (4, 7, 10), in which one cell includes two moieties: there exist minute difference in coordinated bonds and angles despite the same metal ions with the same ligand, were obtained. It shows that several stable conformation in one complex cell.

首次合成了含邻菲罗啉的具有较大刚性的四氮配体中四个氮原子全部与同一金属离子配位的配合物的晶体结构；得到了一个在空间上存在位阻作用的配体与金属离子2：1结构的晶体；解析了具有特色的一个配体（LA4）和三个配合物（4、7和10）的晶体结构，其中的配体与金属离子的配位作用显示出细微的差异，表明在同一金属配合物的晶胞中，可以同时存在着多个稳定的构象。

In this thesis, a series of complexes based on aromatic multicarboxylic acids have been successfully synthesized in solutions or under hydrothermal conditions. Their structure and properties are investigated.(1) Eight complex compounds have been synthesized and characterized by X-ray single crystal diffractive technology: The eight complexes are listed as following: [Cu242] complex 1 [Cd22(H2O)4]·4H2O complex 2 [Co(H2btc)(H2O)3] complex 3 [Co2(H2O)2]·H2O complex 4 [Ni22(H2O)4] complex 5 [Cu22(H2O)4] complex 6 [Co(H2biim)2(H2O)2](H2btc) complex 7 [Zn(H2biim)2(H2O)2](H2btc) complex 8 The structure of complex 1 is dinuclear complex resulted from weak interactions（0-D chain）; complex 2 is 1-D chain stucture result from interactions of water molecules; complex 3、4、5、6 are coordination polymers using hydrothermal synthses, where the first kind ligand is H4btc, the second kind ligand is phen and Co2+、Ni2+、Cu2+ as center ions, respectively. While the coordination enviroment of Co2+ is the same in complex 3, the coordination geometries around the Co atoms in complex 4 are obviously different because of the different reaction conditions. In complex 4, the 1-D chains are connected into 2-D layer through carboxy groups of ligand H4btc. The structures of complex 5、6 are 1-D chain stucture result from interactions of carboxy groups in ligand H4btc. Complex 7、8 are homeomorphy compounds. Either of them are linked to the 3-D chains through intermolecular hydrogen bonds. Each H4btc lose two protons and H2btc2- acts as negative electron balance.

合成了8个结构新颖的配合物，并用X-射线单晶结构分析方法确定了晶体结构，分别为： [Cu242] 配合物1 [Cd22(H2O)4]·4H2O 配合物2 [Co(H2btc)(H2O)3] 配合物3 [Co2(H2O)2]·H2O 配合物4 [Ni22(H2O)4] 配合物5 [Cu22(H2O)4] 配合物6 [Co(H2biim)2(H2O)2](H2btc)配合物7 [Zn(H2biim)2(H2O)2](H2btc)配合物8 配合物1是一个依靠弱作用连接的双核铜结构；配合物2借助水分子形成一维链状结构；配合物3、4、5、6是以H4btc为第一配体、phen为第二配体，通过水热法合成的配合物，其中，Co2+、Ni2+、Cu2+为中心离子；配合物3中的二价钴离子具有相同的配位环境，不同反应条件下得到的配合物4中的二价钴离子存在不同的配位环境，在配合物4中，一维链通过H4btc上的羧基形成一个二维层结构；配合物5、6是借助H4btc上的羧基形成的一维链状结构；配合物7、8属于异质同晶结构，它们的分子通过分子间氢键形成三维网状结构，H4btc上的羧基失去2个质子，作为一个二价负离子起到电荷平衡作用。

The main contributions of this thesis are:(1) Seven mononuclear complexes of tetradentate ligand NTB have been obtained using N〓 or SCN〓 as the additional ligand;(2) Seventeen binuclear complexes of Fe , Zn , Co , Cu have been designed and the complexes of Co , Cu exhibit antiferromagnetic properties;(3) Changing the bridged-ligand such as PO〓, CO〓, o-phth, mai, Ag (CN 〓, Au 〓, etc , fourteen tetranuclear complexes of polypridine ligand have been synthesized;(4) Two antiferromagnetic 1D chain complexes of KH〓pdc ligand have been prepared from hydrothermal reactions; in addition, one ferromagnetic 1D chain copper complex of tpdp which is bridged by oxalate has been obtained.

本论文的主要贡献为：(1)合成了配体NTB的七个新型单核配合物；(2)合成了十七个铁、锌、钴及铜系列混桥双核配合物，其中双核钴和双核铜配合物为反铁磁偶合；(3)选用多吡啶配体tpdp和TPA，改变桥联配体，合成了十个四核配合物；(4)选择配体KH〓pdc，采用水热合成方法得到了反铁磁性一维链状锰、铜配合物；以草酸根为桥联配体，合成了配体tpdp的一维链状铜配合物，该化合物为铁磁偶合，文献较少报道。

The carboxyl of the tripodal ligand is a goodbridging group. The building blocks are linked together by the bridging group andother weak interactions (hydrogen bond and π-π stacking interaction, etc), thusgenerating a one, two or three-dimensional metal complexes.2. Studies on the fluorescence properties of the lanthanide complexes indicated that:(1) The excitations in the ligand-based π-π〓 transitions cause the structuredemission of lanthanide complexes while the ligand luminescence is completelyquenched showing that ligand-to-metal energy transfer occurs.

三脚架配体所带的羧基是一个很好的桥联基团，配合物的结构基元通过这种基团的桥联作用及其它一些弱的作用力(如氢键、π-π堆积作用等)联系起来，构成了一维、二维或三维的超分子空间结构。2、稀土配合物的发光研究发现：(1)用配体的π-π〓跃迁波长进行激发，配合物均显示出稀土离子的特征发射峰，同时，配体的荧光峰没有出现，这说明在三脚架配体与稀土离子间进行了有效的能量传递。

If you do not want to continue, delete the WU and you will get one of the 100 ligand ones.

如果你不想继续算，就删掉它吧，而且你将会立即收到新的 100 ligand 的任务。

I have submitted a new 50 Ligand WU job to try to get the processing time down.

我已经上传了一个新的 50 Ligand 任务，试着把计算时间降下来。

I will leave the 50 Ligand WU job active for a week to allow results to be returned.

我打算明天回收以前的任务，并上传一个新的。50 Ligand 的任务在一星期后再回收。

The marine complex drug includes:1The complex of macrocycle containing nitrogen as ligand.2The complex of macrocycle containing oxygen as ligand.3The complex of bio-poly-molecule as ligand.4The complex of bio-mini-molecule as ligand.

海洋配位化合物药物可分为4大类，1）含氮大环配合物2）含氧大环配合物3）生物高分子配合物4）生物小分子配合物。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。