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The Molar conductivity indicates that all the complexes are nonelectrolyte. IR spectra show the ligand is bonded with RE ion through its oxygen atom in hydroxyl group of phenol; NO3 is coordinated as a symmetrical chelating bidentate group; the coordinated atoms of DMF and DMSO are the oxygen atoms in carbonyl and sulfoxyl groups. Fluorescence spectrum suggests that the Tb3+complexes have characteristic luminescence and its fluorescence intensity is enhanced after doping with La3+, Gd3+, Y3+, influence of doping ions and neutral ligands have also been discussed.

摩尔电导率表明，所有配合物均为非电解质；红外光谱及核磁共振氢谱表明，对叔丁基杯[8]芳烃通过酚羟基的氧原子与稀土离子配位；硝酸根为双齿螯合配位；DMF和DMSO则分别通过羰基氧和亚砜基氧与稀土离子配位；配合物的荧光光谱表明，所有Tb的配合物具有较强的特征荧光，掺杂La~(3+)、Gd~(3+)、Y~(3+)离子对Tb~(3+)的荧光有较强的增强作用。

Cu and Co ions are coordintated with six oxygen atoms from two water molecules and four ligands to form an octahedral geometry. Each ligand links two metal ions in a μ2-bridge coordination mode and two-dimensional wavelike structures are formed.

Cu和Co均为六配位，八面体构型，每个金属离子与4个配体和2个水分子配位，每个配体采取μ2-桥联模式，形成二维层状结构。

The analysis results of crystal structure shows that the stoichiometric mononuclear Ni complex molecule C(subscript 37.5H45Cl2N10O12Ni was composed of two mononuclear Ni complex units {Ni[C35H33N10O](ClO4)2(CH3OH)2.5(H2O)0.5, Ni coordinated to the ligand to form hexacoordinated distorted octahedral configuration, and the orbital contribution and atomic net charge results has provided a good testimony for the coordinated condition in the crystal structure.

晶体结构分析表明，Ni单核配合物的化学经验式C37.5H45Cl2N10O12Ni的单胞中含有两个配合物分子{Ni[C35H33N10O](ClO4)2(CH3OH)2.5(H2O)0.5}，Ni与配位原子形成六配位的扭曲八面体结构。ab从头算所得原子轨道贡献和原子净电荷布居分析结果与晶体结构中的配位情况相符。

The energy levels of free metallic ion were calculated with a 13 parameters model including the 2-body and 3-body interactions. The Stark energy levels of crystal field were calculated using the model proposed by Newman based on 1 electron orbital approximation The f-f oscillator strength calculation includes the contribution of electrostatic-induced, ligand polarization, vibronic-induced, magnetic dipolar transitions.

其中，自由f离子能级计算采用包括双电子与叁电子组态相互作用的二三参数模型，晶体场Stark分裂计算采用单电子轨道近似，用Newman角叠加模型计算晶体场参数。f-f跃迁振子强度计算包括静电诱导偶极跃、配体极化偶极跃、振动诱导电偶极跃迁及磁偶极跃迁的贡献。

There is a parallel shift of the dose-response curve of the ligand to left. Present study suggests that there may be an internal molecular/chemistry interaction between quinolones and BPAA, producing a new structure which has a high affinity on the GABAA receptor sites.

本研究直接反映了联苯丁酮酸和BPAA与喹诺酮类药物在体内与GABAA受体的相互作用，其作用机制可能是两种药物发生了化学/分子作用，形成一种与GABAA受体有着极高亲和力的新结构。

Periodic law also directs the element and its compounds on the nature of the system, the structure of the modern theory of the material basis for the development of several aspects of the work, to develop into the valence bond theory chemical bonding, molecular orbital theory and ligand field theory.

周期律还指导了对元素及其化合物性质的系统研究，成为现代物质结构理论发展的基础经过几方面的工作，发展成为化学键的价键理论、分子轨道理论和配位场理论。

In our pervious works, GEMDOCK has been tested on 100 protein-ligand complexes with 79% successful rate.

在我们之前的研究中，GEMDOCK已经被测试在100个蛋白质与配体的复合物上，并且达到79%的成功率。

For example, octahedral diimine complexes of RuII, OsII, ReI and RhIII with the dipyrido[3,2-a:2',3'-c]phenazine ligand have been well known for their DNA intercalation capability.

1例如，对RuII，OSII的，REI和八面体二亚胺配合物 RhIII与dipyrido [3，2 - 1：2'，3'- C的]吩嗪配体已为众所周知的DNA嵌入能力。

Photosensitizer ; solar cell ; phenolate ligand ; fluorescent spectra ; flash photolysis ; redox potential

光敏染料；太阳能电池；含酚配体；荧光光谱；闪光光解；氧化还原电位

However, it is hard to prepare high valent Mn complexes with ligand with only neutral chelating nitrogen atom of two dpa arms in 〓. In order to get a Mn dimmer complex with high oxidation states of manganese to increase the possibility of storing more oxidizing equivalents necessary to oxidize water evolving oxygen, some N atoms are replaced by anionic phenolate groups.

本文以高价金属的稳定、氧化还原性能的改善、各金属离子之间联系的增强等作为主要研究内容，来改进以往模型中金属价态较低，氧化还原电位高，不利于形成氧化活性中间体；多核配合物的研究较少，且各金属活性中心相互协同作用弱等问题。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。