查询词典 isosteric

Gas chromatography, gas-liquid-solid polymer PLOT column, isosteric heats of adsorption

etex碳填充柱中加入1·5%的角鲨烷，通过增加峰的对称性提高了对低分子量碳氢化合物的分辨能力·Bruner等'''首先将石墨化碳黑毛细管柱，用液相改性后制备成石

Adsorption isotherms of propane, butane, propane and liquified petroleum gas on the quartz beads were determined respectively by means of the method of vacuum weighing , and the relationship between the isosteric adsorption enthalpy change and adsorbance was also reported.

用石英玻璃微珠模拟了HP－1，HP－20M，HP－17毛细管色谱柱内壁，用真空重量法测定了丙烷、丁烷、丙烯、液化石油气样品在3种模拟毛细管内壁表面的吸附等温线，并计算了等量吸附热随吸附量的变化关系。

With the thermodynamic theory in physics-chemistry, the thesis creates and analyzes the following thermodynamic parameters reflecting the sorption characteristics of rough rice: A〓, net isosteric heat, binding energy and transfer potential and capacity of absorbed water.

稻谷内液相水及稻谷表面气相水可作为一个热力学体系，利用热力学基本理论，建立了水分活度、热差焓、吸附结合能、质传递势与质容量等热力学参数。

The results show that the optimal value of CoCl2 concentration is 0.2 mol/L and the maximum adsorbed amount is 19.674 mg/g onto this adsorbent. The adsorption capacity of phosphine onto CoCl2-modified ACF decreases with the increase of temperatures. The maximum absorbed amounts are 19.674 mg/g at 298 K, 13.537 mg/g at 313 K and 11.087 mg/g at 328 K, respectively. It is found that the Freundlich equation is more suitable for the description of phosphine adsorption process than the Langmuir equation. The isosteric heat of adsorption decreases with the increase of the surface loading on CoCl2-modified ACF, which means that CoCl2-modified ACF adsorbent has an energetically heterogeneous surface. Meanwhile, adsorptive phosphine removal performance may be a dominant of physical adsorption when the heat of adsorption is 16-24 kJ/mol, the CoCl2-modified ACF adsorbent will be one of the candidates for tail gas purification of airtight calcium-carbide furnace and recycle of phosphine.

研究结果表明：浸渍液浓度最佳值为0.2 mol/L，此改性ACF对PH3的饱和吸附量为19.674 mg/g；PH3在CoCl2改性ACF上的吸附量随温度升高而迅速降低，在298，313和328 K时PH3的饱和吸附量分别为19.674，13.537和11.087 mg/g；Freundlich吸附等温方程较好地模拟了PH3在改性ACF上的等温吸附；PH3气体在改性ACF上的等量吸附热随吸附量的增大而减小，表明改性ACF吸附剂表面能量的不均匀性；吸附热在16~24 kJ/mol范围内，过程为物理吸附，有利于密闭电石炉尾气的净化。

Hydrophobic-hydrophilic macroporous polydivinylbenzene/polyacrylethylenediamine interpenetrating polymer networks (PDVB/PAEM IPN) were prepared by the sequential suspension polymerization method. These were composed of two networks, of which one was hydrophobic and the other was hydrophilic. The objective of this work was to study the adsorption thermodynamics and adsorption kinetics of this hydrophobic- hydrophilic IPN. The focus was on adsorption isotherms of vanillin at different temperatures, and these fit well into the Freundlich adsorption isotherm. The isosteric adsorption enthalpy, adsorption Gibbs free energies and the adsorption entropy could be calculated according to thermodynamic functions.

采用分步悬浮聚合法制备了具有疏水性能的聚二乙烯基苯(polydivinylbenzene， PDVB)为第一网，具有亲水性能的聚丙烯酰乙二胺(polyacrylethylenediamine， PAEM)为第二网的疏水／亲水大孔聚二乙烯基苯／聚丙烯酰乙二胺互穿聚合物网络(interpenetrating polymer networks， IPN)，研究这类疏水／亲水IPN组成的树脂对吸附质的吸附热力学和吸附动力学；测定了该树脂对香兰素在不同温度下的吸附等温线，吸附等温线符合Freundlich等温吸附方程，利用热力学函数关系计算出了吸附焓、自由能和熵变。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。