查询词典 isomerizes

In the reforming operation a light hydrocarbon feed isomerizes on contact with a suitable catalyst to produce gasoline with a higher octane number.

在重整操作中，一个轻质烃类进料与一个合适的催化剂接触而异构化得到具有高辛烷值的汽油。

The results show that this reaction proceeds in two step: 1 silylene and formaldehyde form an intermediate complex, which is a kind of exothermal reaction with no barrier; 2 the intermediate complex isomerizes to sive the product. The barrier for the second step is 51.4kJ·mol^-^1 at MP2/6-31G^*//6-31G^* level (with zero-point energies correction). In view of dynamics and thermodynamics, it is between 300～400K that the reaction will have not only larger spontaneous tendency and equilibrium constant but also quicker reaction rate.

结果表明，此反应历程由两步组成：1硅烯与甲醛生成一中间配合物，是一无势垒的放热反应，2中间配合物异构化为产物，此步势垒经零点能校正后只有51.4kJ·mol^-^1(MP2/6-31G^*//6-31G^*)；从热力学和动力学的综合角度考虑，该反应在300～400K温度下进行为宜，如此，反应既有较大的自发趋势和平衡常数，又具有较快的反应速率。

Carbon cations are important organic reaction intermediates,and hydrogen shift is a key path through which carbon cations isomerizes.

正碳离子是重要的有机化学反应中间产物，而氢原子移位则是正碳离子异构化的主要反应途径。

Attempts have been done to increase the value of light naphtha isomerizes RON 60 to 70's light naphtha into RON 83 to 90's higher Octane number light naphtha to blend RON 95, or 98 higher Octane gasolines.

本研究为提高轻石油脑的应用价值，应用轻油异构化工场将辛烷值只有60~70的轻石油脑提升至83~90，成为掺配95和98高辛烷值汽油重要轻质油料之一。

Pinl is a kind of peptidyl-prolyl cis/trans isomerase. Pinl specifically isomerizes the pSer/Thr-Pro motifs in proteins, relating to kinds of human diseases, especially cancer and AD.

hPinl是一种肽基脯氨酰顺反异构酶，能特异催化蛋白质分子中pSer/Thr-Pro肽键的顺反构型转变，与多种人类疾病相关，尤其是癌症和阿尔茨海默氏病(Alzheimers disease，AD)。

ERp57 isomerizes specific interchain disulfides connecting the major capsid protein, VP1, to a crosslinked network of neighbors, thus uncoupling about 12 of 72 VP1 pentamers.

ERp57能使特异的链键二硫键发生异构化，使主要衣壳蛋白VP1与邻近的蛋白发生网络交联，从而使72个VP1五聚体中12个发生解耦连作用。

A large releases of kinetic energy for channel CH3CS++ H of least energy might result from a dissociation mechanism according to which c-C2H4S+ isomerizes to a local minimum CH3CSH+ and then dissociates through a transition state to form CH3CS++ H. On the other hand, a predicted dissociation energy 11.05 eV for c-C2H4S ?

实验中观察到环硫乙烯离子解离成CH3CS++ H的解离通道释放出大量的平均动能，并采用G3计算预测环硫乙烯离子的解离通道，推测环硫乙烯离子异构化至次稳定态CH3CSH+结构，再经过渡态结构，断裂S-H键生成C2H3S+和H，同时释放出大量的动能。

HCS++ CH3 agrees with a linearly extrapolated threshold at 10.99 ?b 0.04 eV and a predicted dissociation mechanism that c-C2H4S+ isomerizes to CH3CHS+ before dissociating to HCS++ CH3 supports the experimental results.

另一方面，形成HCS++ CH3解离通道线性拟合的门槛値10.99 ± 0.04 eV与G3计算値11.05 eV一致，释放的平均动能与统计计算値相当吻合，以理论计算推测解离途径也显示此解离通道没有逆反应能障。

From the potential energy profile, it can be predicted that, the dominant channel of this reaction consists of three steps: the two reactants first form a three-membered ring intermediate (INT1) through a barrier-free exothermic reaction of 19.2 kJ/mol; three-membered ring intermediate (INT1) isomerizes to a four-membered ring silylene(P2) via the transition state (TS2) with an energy barrier of 22.8 kJ/mol; four-membered ring silylene(P2) further reacts with ethene(R2) to form a silicic bis-heterocyclic compound (P3), which is also a barrier-free exothermic reaction of 132.2 kJ/mol.

用CCSD//MP2/6-31G*方法研究了单重态二甲基亚烷基硅烯与乙烯生成硅杂双环化合物环加成反应的机理，根据该反应的势能面可以预言，该反应的主反应通道有三步组成：第一步是两反应物（R1， R2）首先生成了一三元环中间体（INT1），它是一无势垒的放热反应，放出的能量为19.2 kJ/mol；第二步是三元环中间体(INT1)经过渡态TS2异构化为了四元环硅烯（P2），其势垒为22.8 kJ/mol；第三步是四元环硅烯（P2）进一步与乙烯(R2)反应生成了硅杂双环化合物（P3），该反应也是一无势垒的放热反应，放出的能量为132.2 kJ/mol。

The two competitive reactions both consist of two steps, two reactants firstly form a three-membered ring intermediate (INT1) and a twisted four-membered ring intermediate (INT2), respectively, both of which are barrier-free exothermic reactions of 41.5 kJ/mol and 72.3 kJ/mol; then INT1 isomerizes to a four-membered ring product (P1) via transition state (TS1), and INT2 results in the chlorine-transfer product (P2) via transition state (TS2), with the barriers of 2.9 kJ/mol and 0.3 kJ/mol, respectively.

INT1和INT2分别经过渡态TS1和TS2异构化为了四元环产物P1和生成了氯迁移产物P2，其势垒分别为2.9和0.3 kJ/mol。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。