查询词典 isomerization

It was found that the thermodynamically unfavourable isomerization of quadracyclane to norbornadiene could be accomplished in the presence of toluene or durene as a co-sensitizer.

首次发现在甲苯、杜苯等芳烃共敏化下，可以使原来不能进行的、热力学不利的四环烷→降冰片二烯异构化得以进行，并根据CIDNP结果提出这是由于生成了敏化剂/底物/芳烃三元基激络合物使反应的势能面改变造成的并促进单线态的系间窜跃。

We studied DBU-mediated Ireland-Claisen rearrangement. Using DBU as the base for enolization of allylic esters of unsaturated acids 9-16, we found a novel DBU-mediated tandem Ireland-Claisen rearrangement /isomerization reactions and established a consecutive Ireland-Claisen rearrangement /Cope rearrangement.

利用DBU作为烯醇化碱，对含有活泼质子的烯酸烯丙酯类化合物9-16的Ireland-Claisen重排进行了系统的研究，创建了一条新颖的DBU-促进的Ireland-Claisen重排/异构化串联反应及Ireland-Claisen重排/Cope重排的串联反应路线。

Hydrogen pressure. Moreover, it was found that the hydrogenation reaction ofα-hexene was accompanied with a isomerization reaction.

聚丙烯腈负载纳米钯催化剂在催化加氢α-辛烯的实验中，纤维直径和钯颗粒较小的催化剂显示了更好的催化性能。

Theoretical studies on various geometrical structures of Hypophosphorous acid were carried out using DFT theoretical methods,at the B3LYP/6—311++G** level.Intramolecular proton transfer isomerization has also been studied using the intrinsic reaction coordinate.

采用量子化学密度泛函B3LYP方法，在6—311++G**基组水平上全优化得到了硫代次磷酸的硫酮式和硫醇式两种构型异构体以及相应的对映异构体，同时对分子内质子转移异构化反应微观机理进行了理论分析。

Theoretical studies on various geometrical structures of Hypophosphorous acid were carried out using DFT theoretical methods, at the B3LYP/6-311 ++ G(superscript **) level. Intramolecular proton transfer isomerization has also been studied using the intrinsic reaction coordinate.

采用量子化学密度泛函B3LYP方法，在6-311++G基组水平上全优化得到了硫代次磷酸的硫酮式和硫醇式两种构型异构体以及相应的对映异构体，同时对分子内质子转移异构化反应微观机理进行了理论分析。

Keywords hypophosphorous acid;thiol isomer thione isomers;enantiomer;proton transfer;isomerization reaction

单硫代次膦酸；硫酮式异构体；硫醇式异构体；对映异构体；质子转移异构化

Deriving conjugated linoleic acid under different condition often leads to incompletability and isomerization.It also affects the accuracy of analysis.

对共轭亚油酸进行三氟化硼-甲醇衍生化时，采用不同条件处理共轭亚油酸，常常导致共轭亚油酸的不完全和异构化，从而影响到分析的准确度。

The catalytic isomerization of isoborneol in the presence or Zn laden or Cu laden catalysts,in liquid phase or gas phase,is reported.

研究异龙脑在常压下被含锌或含铜催化剂催化的液相和气相异构化反应，讨论了反应条件对产物分布的影

In the first route, the isomerization process of α-isophorone into a β-isophorone requires high temperatures, and only about 4% of the conversion was obtained for the conjugate effect of α-isophorone.

在第一条路线中由于α-异佛尔酮的共轭效应，使得α-异佛尔酮异构化为β-异佛尔酮的过程中需要很高的温度，且仅有4%左右的转化率。

In order to supply basic thermodynamic data for the separation design of acetyl acetone from the isomerization reaction of isopropenyl acetate,vapor-liquid equilibrium data of isopropenyl acetate-acetyl acetone system under 101.3 kPa was measured using Ellis equilibrium still.

为了给乙酸异丙烯酯异构化生产乙酰丙酮工艺的产物分离设计提供基础热力学数据，用埃利斯平衡蒸馏器测定了101.3 kPa下乙酸异丙烯酯-乙酰丙酮体系的汽液平衡数据，结果表明，该二元体系未形成共沸物，实验数据通过了Herrington面积法的热力学一致性检验。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。