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The calculated results show: the ground state structures of PtNi5, Pt2Ni4 and Pt3Ni3 clusters are quadrangular bi-pyramid, and Pt4Ni2 and Pt5Ni clusters are triangular bi-pyramid with hat and triangular pyramid with quadrilateral, respectively. From the point of view of thermodynamics, PtnNim clusters are stable because of the negative enthalpy of formation; the positive NICS of PtNi5 clusters show anti-aromaticity, The negative NICS of Pt2Ni4 and Pt5Ni clusters show aromaticity. The number of the IR absorption peak of Pt3Ni3 is the most. The IR and raman absorption peak of PtNi5 , IR of Pt2Ni4, Raman of Pt3Ni3 and Pt4Ni2 have only one. The absorption peak of Pt5Ni appears in the bigger frequencies only, and is zero almost in the small frequencies.

研究结果表明:PtNi5、、Pt2Ni4、Pt3Ni3团簇的基态结构都为四角双锥结构,Pt4Ni2 和Pt5Ni团簇的基态结构分别是戴帽三角双锥和三角锥戴四边形结构;PtnNim团簇的生成焓都为负值,表明团簇在热力学上是稳定的;由NICS值可得,PtNi5团簇具有反芳香性,Pt2Ni4和Pt5Ni团簇具有芳香性;从光谱分析来看,Pt3Ni3团簇的IR较强吸收峰的个数最多,PtNi5团簇的IR和Raman、Pt2Ni4团簇的IR、Pt3Ni3和Pt4Ni2团簇的Raman只有一个强吸收峰值,Pt5Ni团簇的峰值只出现在频率较大的位置,频率小的位置几乎为零。

"Hi we're Vespertine from Spain. We wrote this song "Hope Will Come for China… the earthquake which happened on May 12th has been a horrible tragedy, as we read on newspaper and saw on TV, that tens of thousands of victims have lost the ir home, the ir family including the ir own lives. the desperate faces of parents and the dead children… the se images and photos have been haunting in our heads and we feel deeply sad and sorry for the victims especially the people of Wen Chuan… While the positive attitude and strong spirit of the victims and the way Chinese people help each o the r have shown us the most respective side of human race.

我们是来自西班牙的Vespertine乐队,此次专为中国创作了这首名为《Hope Will Come》的歌曲……5月12日的这场地震是一次惨绝人寰的悲剧,我们在报纸上以及电视上看到数万人流离失所,失去亲人甚至自己的生命,父母亲们绝望的面孔与不幸死去的儿童……这些画面与图片在我们脑海里始终萦绕不去,我们为受灾的人们感到深刻的悲伤与难过,尤其是汶川的人们……而与此同时,灾民们积极的态度与坚强的灵魂,以及中国人民团结起来相互帮助的事实让我们看到了人性最值得尊敬的一面。

IR, UV-Vis, 1H NMR The IR, UV-Vis and 1H NMR of selenadiazoles were investigated. Their IR peaks were classified as the corresponding groups or bonds; The relation of their structure with the conjugative effects, absorbtion wavelength and molar absorb coefficients were discussed with the UV-Vis. The value of selenadiazoles in analytical chemistry and the varieties of structure with the pH were discussed.

IR,UV-Vis,~1H NMR 对硒二唑类化合物的IR吸收峰进行了归类与指认,讨论了SPO、SPDO的异构体的分子结构;探讨了UV-Vis、吸收波长和摩尔吸光系数与分子结构的相对应关系,以及紫外吸收光谱性质在分析化学上的应用价值和溶液的pH值引起SPO、SPDO的结构变化。

The UV and IR spectroscopic studies of the monomer films showed that the photoreaction ratio of monomer (about 50%) was higher than the corresponding photosensitive polymer (about 10%, PVCi). The polarized IR spectra proved that obvious anisotropic absorption was displayed in the irradiated photosensitive film. With polarizing microscopy method, we found that these kinds of photoalignment films exhibited good alignment ability, and the stability of the photoalignment film could reach about 100℃. 2 A photosensitive self-assembled monolayer was fabricated that contained photo-cycloadditable groups, such as, coumarin and cinnamate. The reaction process were detected by contact angle method because the IR absorption of monolayer was very weak. The photosensitive self-assembled monolayer promote uniform alignment of nematic liquid crystals by LPUV, and it thermal stability could reach about 130℃. 3 A cationic bolaform amphiphiles was synthesized that had two photosensitive double bonds, and can be polymerized by ultraviolet. A layer-by-layer self-assembled deposition film was prepared in aqueous solution by using this material and poly (sodium 4-styrenesulfonate). The UV-Vis. spectra proved that the multilayers film was uniform and layer-by-layer. When LPUV irradiated the film, the photopolymerizable double bond underwent [2+2] cycloaddition, and the production of the reaction distributed along the polarized direction of incident LPUV. Polarized UV-Vis. spectra indicated that the irradiated self-assembled multiplayer film was anisotropic, and the dichromic ration is about 0.09, it is higher than the spin-coating method of photosensitive polymer or monomer. We used this anisotropic film as alignment layer of nematic liquid crystals, and obtained a uniform and stability alignment result, the static contrast ratio is about 100, which is very close to application of liquid crystal device. This thesis is an instance that the photochemical material was used in the physics region of liquid crystals, the route that was from photosensitive monomer, self-assembled monolayer film to self-assembled multiplayer film was undergone, by this logical research method photoailgnment of liquid crystal was extended and consummated.

围绕上述思路开展了如下工作:1合成了三种可进行光二聚反应的光敏小分子单体,LPUV 辐照制作了光控取向膜;用紫外-可见光谱法和红外光谱法分析了薄膜中的光化学反应,发现小分子的光反应程度可达到50%以上,至少比光敏高分子高出5倍;薄膜的偏振红外光谱证实,经过LPUV 辐照后薄膜出现了明显的各向异性;将小分子光控取向膜制成液晶器件,在偏光显微镜下观察看到均匀一致的液晶取向;并且热稳定性达到100℃左右,接近实用化要求。2制备了含肉桂酸、香豆素基团的自组装单层膜;采用接触角的方法监测自组装反应的动力学过程;紫外-可见光谱证实了自组装单层膜在石英基板表面形成;自组装单层膜经LPUV 辐照后能诱导液晶均匀取向,而且热稳定性可达130℃,热稳定性进一步提高。3合成了含有光敏双键的双季铵盐,在水溶液状态下将它和聚乙烯基苯磺酸钠沉积生成layer-by-layer 自组装多层膜,紫外-可见光谱证实这是一个逐层均匀的沉积;在LPUV 照射下,自组装膜中的光敏双键按照偏振方向发生[2+2]环加成反应,形成取向膜,用二向色性值评价的分子取向度高于高分子及小分子光控取向膜的水平;实验证明用自组装多层膜制成的液晶器件亮暗态均匀,静态对比度约为100,达到实用化器件的水平。

Methods Wistar rats of 6 months old were randomly divided into normal control groupand IR group. Each group had eight rats. Euglycemic insulin clamp technique was used to determine IR and glycose infusion rate was used to IR. Cardiocyte apoptosis was evaluated by TUNEL. Heart weight and body weight were measured to calculate HW/BW. Fine structure of heart and ultramicrostructure of cardiocyte were observed.

6月龄Wistar大鼠,分为正常对照组和IR组,正常血糖胰岛素钳夹技术测定各组大鼠IR,葡萄糖输注速率表示IR情况;测量大鼠心脏重量和体重并计算心脏重量与体重之比;原位末端酶标记法检测各组大鼠心肌细胞凋亡情况;观察心脏微细结构和心肌细胞超微结构;免疫组化检测心脏间质Ⅰ、Ⅲ型胶原水平。

We found, GLP-1-IR cells in various guts of rat, pig and foetus of human with distribution scatteredly among the basal portion of intestinal glands. The cell shape corresponded with open type cells, i.e. L-cells. The density of GLP-1-IR cells was different in races, but the distribution regularity of GLP-1-IR cells was same. It showed that a continuous increase from the proximal to the distal portion of small and bowel.

结果发现:在各段肠管都可见到GLP-1-IR细胞;GLP-1-IR细胞散在于肠腺的柱状上皮细胞之间,多位于肠腺的基底部,呈开放型内分泌细胞形态,即L细胞;不同种属问GLP-1-IR细胞密度不同,但分布规律相同,即自小肠和大肠的近端向远端逐渐增大。

Originally, Chuehmin, Chueh-hui, the ir sister Shu-hua and the ir cousin Shu-ying had pleaded with Madam Chou to let Chin stay as the ir guest over the holidays.

本来觉民、觉慧、淑英、淑华几个人曾经怂恿他们的母亲把琴留在这里过新年,但是张太太说家里有事情,终于把琴带回去了。

In addition,we give an explanation for the origin of the different conductive mechanisms in the insulating phase,i.e.,the variable range hopping originate from the energy gap produced by the dimerized Ir-Ir chains,while the thermal activation originate from the non-dimerized Ir.

另外,指出了CuIr_2S_4体系在低温绝缘相的导电机制,跃迁电导项来源于Ir-Ir二聚所产生的能隙,而热激活电导项来源于未二聚的Ir。

By analyzing the deficiencies of offensive realism, this paper advances three evaluating laws: 1 alienation, i.e., during the developing process of IR theory, there is both self-affirmation and self-negation to gain its contemporary legitimacy; 2 assimilation: i.e., IR theory evolutes from entirely different to continuous conjunction, showing its characteristics when harmonizing with others to gain its contemporary rationality; 3 fundamentalisation: like any other kinds of thinking, when IR theory has come into being, it gets the trend of fundamentalization, i.e., affirm itself by negating the opposites to gain its contemporary teleonomic.

文章在分析进攻性现实主义的不足时提出了国际关系理论的三大演绎律1)异化:即理论发展过程中既有不断肯定自我的过程,也有不断否定自我的过程,以获得现时代的合法性;2)同化:即各理论从泾渭分明到不断通约,在融合中展示自身特质,获得现时代的合理性;3)原教旨化:与任何其他人类思维形式一样,理论一旦形成,都具有原教旨倾向,即不断否定对立面来肯定自身,获得现时代的合目的性,并以此探讨对待国际关系理论的一般性问题。

While the adsorptions of 1-propanol and 1-Br-propane at 100℃ give rise to 1-propoxy species, which mainly converted to propanal at higher temperature. IR spectrum arising from the interaction of propene with the catalyst at 100 ℃ shows the IR bands of allyl alcoholate and isopropoxy species. As the temperature was increased to 150℃, the bands ascribable to the adsorbed acetone and acrolein were observed. Based on these results, it is suggested that isopropoxy species is one of the intermediates for SOP to acrolein over MoPO/SiO〓 catalyst.

2原位IR光谱实验结果表明:200℃时丙烷/O〓混合气在催化剂表面吸附后的IR谱与同温度下异丙醇吸附的IR谱相似,均检测到吸附态丙酮物种和丙烯醛物种的IR谱峰;溴代异丙烷和异丙醇在催化剂表面吸附后均转化为异丙氧基,异丙氧基主要转化为丙烯和丙酮,丙烯进一步转化为丙烯醛;溴代正丙烷和正丙醇在催化剂表面吸附后均转化为正丙氧基,正丙氧基主要转化为丙醛;丙烯在催化剂表面吸附后转化为σ-氧烯丙基和异丙氧基,升温后σ-氧烯丙基转化为丙烯醛而异丙氧基转化为丙酮。

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相关中文对照歌词
Violeta (Fricote)
Calentándote
Que La Dejen Ir Al Baile Sola
Musica Killa
Pode Ir
Déjame Ir
Vueltas En El Aire
First Time
Deixo Você Ir
Me Gustas Tu
推荐网络例句

Apllied the data of QuickBird-2——the highest resolution remote sensing,and based on the theory and methodology of fractal geometry,we have quantitatively studied remote sensing lineations in Gaolong gold deposit of Guangxi.

采用Quick Brid-2高分辨率卫星遥感数据,通过分形几何学的盒计维数法,定量研究广西高龙金矿区遥感线性构造。

So, sometimes, to change the color can not be your food (referring to the above-mentioned crustacean) has been a sign of boiling over.

所以,有时,来改变颜色,不能你的食物一直是沸腾了的迹象。

MILAN - Nils Liedholm told 'Tuttosport':'It is not a decisive game but actually an important one.

米兰--利德霍尔姆接受全体育采访时说:罗马与米兰的比赛虽不是决定性的,但的确是场重要的比赛。