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Based on the deterioration mechanism of corrosive medium, a lot of polymer such as ternary-polymer, adding-felt addition, hydrophobe and polypropylene fiber were added to enhance the performance of anti-corrosion, anti-penetration, conglutination and anti-cracking of original cementious material. The microstrure of cementious material was changed from the simplex hydration product of cement to the superposition structure of the hydrolysate of polymer and the hydration product of cement. A lot of the corrosive ions were prevented from the interior of concrete by this stable structure. The results of tryout indicated that the mending material has the good effect at the corrosion form of corrosive medium.

根据介质腐蚀形式的劣化机理,该文以提高修补材料耐腐蚀性能、抗渗透性能、粘结性能和抗裂性能为出发点,采用添加有机硅改性三元共聚物、增粘剂、孔隙憎水剂等多种聚合物和聚丙烯纤维对原水泥基材料进行改性,使得修补材料的内部微观结构从单纯的水泥水化产物转变成聚合物和水泥水化产物叠合的空间网状结构,这种稳定的结构能有效抵抗各种介质离子的侵蚀,在实际工程上的试用也显示出新修补材料良好的使用效果。

In acidic aquatic environment, hydrotalcite and its calcined product can also play a role in neutralizing H(superscript +) ions and sorbing anions.

在酸性环境下,水滑石及其焙烧产物在对阴离子的吸附过程中都有中和酸性溶液的作用。

To forecast the possibility of tunnel discharge disaster, seven kinds of common ions of the spring in the tunnel site and the tunnel discharge, were taken as the research object. Then used fuzzily gathers analysis method to determine the corresponding fuzzy equivalent matrixs Ro=ro(subscript ijo(subscript n×n) and carried the fifteen samples on reasonable classification.

为预测随道发生涌突水灾害的可能性,以隧址区泉水样及遂道内涌水样中的7种常见离子为研究对象,采用模糊聚类分析方法确定相应的模糊等价矩阵R°=r°(下标 ij°将所取15个水化学样进行合理分类。

IR spectra and UV spectra of the complexes are described. The results show that two phenolic oxygen and two imino nitrogen atoms in H2L coordinate to M ions.

通过对配合物的红外光谱和紫外光谱测定与归属,推测在三个过渡金属Schiff碱配合物中配体是通过酚羟基的氧原子和亚氨基的氮原子进行配位的。

It results from theformation of infusible salt or hydrates by the complexing reaction of metal ion andnegative ions in alkaline solution. The stability mechanism was discussed byemploying scanning electronic microscope and x ray photoelectronspectroscopy.

结果表明,在中性介质中,其稳定性较好,而在碱性介质中的稳定性较差,这是因为在碱性介质中金属离子与介质中的阴性离子络合形成难溶性的盐或氢氧化物,加速了GIC的分解所致。

So the contents of Na〓 and Cl〓 in all inoculative plants were lower, and the ion quantities of N, P, K〓 and Ca〓 were higher than the control. At the same time, all kinds of tissue biomasses of inoculative plants relatively ascended which diluted the salt concentration of the inner plant and increased the accommodating quantities of the root and stem tissues to salt ions such as Na〓 and Cl〓.

结果表明,随着盐胁迫强度的增加,无论接种与否,各品种植株根系、茎部、叶片内Na〓、Cl〓含量均呈上升趋势,N、P、K〓、Ca〓含量呈下降趋势,由于菌根的形成增加了离子选择吸收特性,接种植株各部位Na〓、Cl〓含量低于对照,而N、P、K〓、Ca〓含量则高于对照植株。

The formation mechanism for the C-PPV aggregation we proposed is: complex between K+ and the crown ether derivatives in the C-PPV brings two polymer chains closer together, and the K+ ions create interpolymer bridges, forming aggregations in the solution.

本文合成了可溶的带冠醚取代基的聚苯撑乙烯,其中冠醚基团的氧原子直接连在PPV主链上苯环的2、3位,并研究了聚合物在K~+存在下的自组装形成聚集体的行为。

Second-row early transition metal ions reaction mechanism, intersystem crossing, minimum energy crossing point

中文关键词第二前过渡金属离子反应机理,系间窜越,能量最低势能面交叉点

In Chapter 5, photo-induced absorption is used to study the intersystem crossing from singlet to triplet states of two polyfluorenes after doped with Ir-complex. It is found that the triplet exciton lifetime of PFs is reduced by the dopants. But instead of decreasing, the population density of PF triplet exciton increases by almost one order of magnitude. The finding shows that the ISC rate can increase over 100 times due to the spin-orbital interaction with the Ir ions.

第五章以光诱发吸收光谱技术研究两种聚芴高分子掺杂绿光铱错合物后,聚芴的单重态到三重态的内部系统转换效率的改变;研究发现在掺杂后,聚芴的三重态生命期减短,但出乎意料的是其三重态的态密度并没有随之降低反而有一个数量级的增加,其原因为单重态到三重态的内部系统转换受铱错合物的影响效率增加了100倍。

On the basis of intrapair and interpair correlation model, we have calculated the pair correlation energies of different kinds of systems, analyzed the changing rules of correlation energies of various electron pairs, and developed a reasonable and simple scheme called "Separating Large System into Smaller Ones". The basic idea of this scheme is that the correlation energy contributions of actual components in the ionic compound can be obtained using the correlation energy of ions with integer charge as the boundary conditions and incorporating the HF wave function or the distribution of electron cloud, then the total correlation energy of the system can be estimated by linearly summarizing the correlation contributions of these components.

在对内对间电子相关能理论模型的基础上,进行各类型化学键分子体系电子相关能的计算,分析电子对相关能的变化规律,建立合理的、&化整为零&的电子相关能简捷计算方案,其基本思想是对于离子键体系以整价离子的电子相关能为边界条件,通过HF波函数或电子云分布求得大体系中实际离子的电子相关能后,进行线性加和,即&化整为零、聚零为整&的思想。

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