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In addition, it is also demonstrated that the haloid ions co-absorbed on the assembly play an important role in controlling the charge transfer between PATP and silver substrate.

4利用聚乙烯吡咯烷酮共聚对聚苯乙烯微球的表面改性进行碘催化剂的固定化，制备粒径均一、可循环使用的催化剂微粒。

They are:In the third chapter, the crystal structures of these new dca complexes are described anddiscussed in detail. Besides two mononuclear complexes, 1 and 2, complexes 3～15 arecoordination polymer with novel and interesting structural characteristics. 3, 6, 7, 8, 9 are 1Dpolymers, 4 and 5 are of 2D extending structure, while 10, 11, 12, 13, 14, 15, 16, 17 form thefirstly reported series heteronuclear dca coordination polymer, in which (except 10) differentbuilding blocks, with different metal ions in them, construct interesting architecture, like α-and β-type 〓 chains, ladder chain 〓, scaffold structure of 12, and "sandwich"layer structure in 15 and 16, etc..

这些配合物是：第三章中，我们详细描述讨论了这些新型的二氰胺配合物的晶体结构，除两个单核配合物1和2之外，其余十五个为配位聚合物并具有新颖和有趣的结构特征。3，6，7，8，9是一维配位聚合物，4和5则呈现二维扩展结构，而10，11，12，13，14，15，16，17属于首次报道的一系列的二氰胺异金属配位聚合物，其中(除10外)含有不同金属离子的构造&砌块&可构建出有趣的结构，如α-和β-型〓链，梯形链〓，12中的脚手架结构，以及15和16中的&三明治&层状结构等。

The AM method and the new formula are applied to study the full vibrational energy spectra and molecular dissociation energies of some electronic states of some homonuclear and heteronuclear diatomic molecules and some diatomic ions.

然后应用AM方法和离解能新公式对一批同核和异核双原子分子，以及双原子分子离子电子态的完全振动能谱和离解能进行了研究。

The pigment of Berberis heteropoda Schrenk is a type of anchocyanin and it is strong in resistance against light and to some extent, good in enduring heat and low consistence oxide. But it is poor in resistance against reductant and preservative. It can be applied to the condition of PH. It is also found that sucrose and most of metal ions do not exert negative effects on the stability of the pigment, except Fe3+, Fe2+and low consistence Pb2+, which have some extent effects. Adding stability matter can improve its stability. The harm trace elements contains are within requirement of the National Standard on food safety, As the lexicological study indicates that the pigment does not have any toxicity and mutagenesis, it can be used as edible pigment.

结果表明：大孔树脂吸附-解吸附法纯化黑果小檗色素实验室工艺简单易行，色素回收率高；黑果小檗色素属于花色苷类色素；耐光性好；对热有一定耐受性；对低浓度氧化剂有一定耐受性；耐还原性差；对防腐剂耐性差；适用PH＜6条件下使用；蔗糖和大多数金属离子对色素无不良影响，但Fe~(3+)、Fe~(2+)、Sn~(2+)和低浓度pb~(2+)对色素有影响，加入稳定剂后，可提高色素的耐热性、耐氧化性、耐防腐剂能力；经对有害微量元素进行检测和毒理试验表明，该色素安全无毒，可以作为天然食用色素使用。

In this thesis, a series of complexes based on aromatic multicarboxylic acids have been successfully synthesized in solutions or under hydrothermal conditions. Their structure and properties are investigated.(1) Eight complex compounds have been synthesized and characterized by X-ray single crystal diffractive technology: The eight complexes are listed as following: [Cu242] complex 1 [Cd22(H2O)4]·4H2O complex 2 [Co(H2btc)(H2O)3] complex 3 [Co2(H2O)2]·H2O complex 4 [Ni22(H2O)4] complex 5 [Cu22(H2O)4] complex 6 [Co(H2biim)2(H2O)2](H2btc) complex 7 [Zn(H2biim)2(H2O)2](H2btc) complex 8 The structure of complex 1 is dinuclear complex resulted from weak interactions（0-D chain）; complex 2 is 1-D chain stucture result from interactions of water molecules; complex 3、4、5、6 are coordination polymers using hydrothermal synthses, where the first kind ligand is H4btc, the second kind ligand is phen and Co2+、Ni2+、Cu2+ as center ions, respectively. While the coordination enviroment of Co2+ is the same in complex 3, the coordination geometries around the Co atoms in complex 4 are obviously different because of the different reaction conditions. In complex 4, the 1-D chains are connected into 2-D layer through carboxy groups of ligand H4btc. The structures of complex 5、6 are 1-D chain stucture result from interactions of carboxy groups in ligand H4btc. Complex 7、8 are homeomorphy compounds. Either of them are linked to the 3-D chains through intermolecular hydrogen bonds. Each H4btc lose two protons and H2btc2- acts as negative electron balance.

合成了8个结构新颖的配合物，并用X-射线单晶结构分析方法确定了晶体结构，分别为： [Cu242] 配合物1 [Cd22(H2O)4]·4H2O 配合物2 [Co(H2btc)(H2O)3] 配合物3 [Co2(H2O)2]·H2O 配合物4 [Ni22(H2O)4] 配合物5 [Cu22(H2O)4] 配合物6 [Co(H2biim)2(H2O)2](H2btc)配合物7 [Zn(H2biim)2(H2O)2](H2btc)配合物8 配合物1是一个依靠弱作用连接的双核铜结构；配合物2借助水分子形成一维链状结构；配合物3、4、5、6是以H4btc为第一配体、phen为第二配体，通过水热法合成的配合物，其中，Co2+、Ni2+、Cu2+为中心离子；配合物3中的二价钴离子具有相同的配位环境，不同反应条件下得到的配合物4中的二价钴离子存在不同的配位环境，在配合物4中，一维链通过H4btc上的羧基形成一个二维层结构；配合物5、6是借助H4btc上的羧基形成的一维链状结构；配合物7、8属于异质同晶结构，它们的分子通过分子间氢键形成三维网状结构，H4btc上的羧基失去2个质子，作为一个二价负离子起到电荷平衡作用。

Different from the conventional catalyst immobilization methods, the self-supporting strategy utilizes homochiral metal-organic coordination polymers generated by self-assembly of chiral multitopic ligands with metal ions without using any support.

与传统的负载模式不同，手性自负载催化剂通过含双或多官能团的手性配体与金属通过自组装形成一类有机-无机聚合物，因此无需使用任何载体，即能够有效地实现手性催化剂的回收和再利用。

The nl shell energies of high ionization ions have been calculated by using the improved screened hydrogenic ionization model.

采用改进的屏蔽氢离子模型计算高剥离态离子的nl壳层能量，并与实验值及其他理论值进行了比较。

However, these two factors are not independent in a finite β plasma, especially in a pure hydrogenic plasma without fast ions where βe /βi=Te/Ti .

在没有快离子的纯氢等离子体中存在着这样的关系：β e /βi=Te/T i 。

Effects of sulfate ions and hydrolytic temperature on the TiCl4-derived TiO2 powders properties were investigated in detail.

研究了四氯化钛水解法制备的二氧化钛纳米晶工艺中水解温度和硫酸根离子对粉体性能的影响。

Liquid-liquid extraction of hydrophile organic solvent is a new,green,high-efficiency separation technique,which has been applied in the field of extraction of heavy metal ions and purification of biologic active substances.

亲水有机溶剂液-液萃取分离是一种绿色高效分离新体系，由于兼有工艺简单、快速高效、环境友好等特点，受到研究人员的重视。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。