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The well-documented chelating properties of bipyridine and the sensitivity of the optical properties of AuNPs have been employed to detect low concentration of metal ions in water.

因为联吡啶具有好的钳合能力,加上金奈米粒子的灵敏的光学性质,所以可以用来侦测水中低浓度的金属离子。

In the procedures of syntheses, we chose 2,2"-bipyridine (2,2"-bipy), 4,4"-bipyridine (4,4"-bipy), 1,10-phenanthroline (1,10-phen) and 8—hydroxyquinoline as neutral ligands, and lead, copper, zinc, cadmium and manganese as metal ions in our research.

使用的中性配体为2,2′-联吡啶(2,2′-bipy)、4,4′-联吡啶(4,4′-bipy)、1,10-邻菲罗啉(1,10-phen)和8—羟基喹啉,研究的金属离子为主族金属Pb以及过渡金属Cu、Zn、Cd和Mn。

The result of temperature dependence magnetic susceptibilities measurements indicates that weak ferromagnetic coupling interaction exists between Cu ions, which are connected by 4,4'-bipyridine.

变温磁化率测定结果表明,在配合物中,通过4,4'-联吡啶联接的Cu离子之间存在弱铁磁偶合作用。

The structure measurement indicates that only a small amount of Bi3+ ions can not enter the A-site of La2/3Ca1/3MnO3 lattice. Because of the low melting behavior of bismuth oxide, the superfluous Bi will segregate as insulating bismuth oxides and bismuthate. Because of the segregation of Bi, the surface of the main phase has different ferromagnetic property from that of the core, namely the magnetic inhomogeneity of the samples is enhanced, which results in the broader ferromagnetism-paramagnetism transition and magnetoresistance plateaus in samples with the high Bi content.

结构测试表明Bi并不能进入La2/3Ca1/3MnO3的晶格锰位,由于A位元素的过量和铋氧化物的低熔点特性,烧结过程中Bi元素析出形成了绝缘性的第二相;并且Bi的析出导致样品主相的表面存在与主相体心磁性质不同的铁磁相,即样品的磁不均匀性增强,使得高Bi含量的样品表现出宽的铁磁-顺磁转变和磁电阻平台效应。

Result showed that tetrasubstituted calix [4] arenes in lower rim were stronger complex abilities than bisubstituted calix [4] arene with transition metal, heavy metal and rare earth ions. But when introducing the aminephenolicalcohols in the 1, 3-bisubstituted calix [4] arenes, the complex abilities were improved.

结果表明:在Lower rim上四取代的杯[4]芳烃配体比1,3-二取代的杯[4]芳烃配体对过渡金属离子,重金属离子及稀土离子有更好的配位能力,但当1,3-二取代的取代基上引入醇胺链型配体时,对金属离子也有很好的配位能力。

Cancer patients here on Earth who undergo new forms of radiation therapy using protons or carbon ions , said Borak, could also benefit from the dosimeter.

他还说在地球上正接收质子或碳离子新辐射疗法治疗的癌症患者也会从该放射量测定器收益。

The optimal measuring conditions were investigated. The results indicated that the catalytic reaction to Pt and bromocresol purple was the first-order reaction. The apparent activation energy was 217.4kJ/mol and the maximum absorption wavelength of fading reaction was at 434 nm. The linear range of Pt was 0.16-4.0μg/L and the detection limit was 2.5×10^(-11)g/mL. Most of common ions had no interference with the determination, while ten multiples of Ru, Rh and Os had interference with the determination of Pt. Therefore.

选择了最佳测定条件,实验结果表明,催化反应对铂和溴甲酚紫为一级反应,反应的表观活化能为217.4kJ/mol,褪色反应的最大吸收波长为434nm,方法测定R哪的线性范围为0.16~4.0μg/L,检出限为2.5×10^(-11)g/mL,大多数常见离子不干扰测定,10倍以上的Ru,Rh和Os对测定有干扰,可在测定前分离除去。

SO〓〓/M〓O〓 solid superacid was applied to the photocatalytic oxidation of organic pollutants for the first time. Porous SO〓〓/TiO〓 solid superacid catalysts with high specific surface area were prepared by sol-gel method. The photocatalytic degradation of bromomethane was used as model reaction. The influence of impregnation with H〓SO〓 solution on the structure of catalysts and their photocatalytic performance was systematically studied by using X-ray diffraction, X-ray photoelectron spectroscopy, N〓 sorption analysis applying BET method, UV-Vis diffuse reflectance spectroscopy, FTIR spectroscopy, O〓-TPD and photocatalytic activity measurement. The acidity of TiO〓-based catalysts was investigated by Hammett indicator method, NH〓-TPD and IR spectra of pyridine adsorbtion. The mechanism of superacidifing effects on photocatalytic performances such as the photocatalytic degradation rate of bromomethane, apparent kinetic constant and apparent quantum efficiency was discussed.The results indicated that SO〓〓 is combined with metal ions of TiO〓 in a chelating bidentate mode.

本文首次将SO〓〓/MxOy型固体超强酸催化剂用于光催化氧化有机污染物研究,采用溶胶-凝胶法制备了具有多孔性和大比表面结构的二氧化钛基固体超强酸光催化剂SO〓〓/TiO〓,以光催化降解溴代甲烷为模型反应,系统地研究了H〓SO〓浸渍处理对催化剂表面酸性及其气相光催化性能的影响,结合XRD、BET、XPS、FTIR、Hammett指示剂法、吡啶吸附红外光谱、NH〓-TPD、O〓-TPD、紫外可见漫反射光谱等多种表征手段,深入地讨论了超强酸化对TiO〓的改性机理,阐明了引起SO〓〓/TiO〓超强酸催化剂光催化降解溴代甲烷的转化率、表观反应速率常数和表观量子效率变化的本质原因。

The results showed that brucite owned strong capacity of adsorbing heavy metal ions.

结果表明,水镁石作为一种吸附剂具有较强的吸附重金属离子的能力。

The total amount of Mg and Fe ions in the equilibrium solution depends on the solubility of resulting double salts. The reaction speed is decided by the speeds of ionization of ammonia salts and brucite together.

平衡溶液中镁、铁离子的总量取决于生成复盐的溶解度,反应的速度是由铵盐电离的速度和水镁石电离的速度共同决定的。

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It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发,分析对称连杆曲线上鲍尔点的产生条件,提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品,年生产总值3000万美元,产品价廉物美、选料上乘、质量保证,深受国内外客户的青睐

The eˉtiology of hemospermia is complicate,but almost of hemospermia are benign.

血精的原因很,以良性病变为主。