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It was found that the main active center is the iron ions which are in the exchange sites in addition to heteroatom FeZSM-5 itself.

进一步研究发现杂原子FeZSM-5分子筛催化剂上主要活性中心是处在阳离子交换位上的铁离子，同时，由于铁原子进入分子筛骨架，使杂原子FeZSM-5本身也具有一定的反应活性。

This is a new development after the discovery of the protonolysis of the C-Pd bond in the presence of halide ions and β-heteroatom elimination in presence of nitrogen-containing ligands in our group.

这是我们小组继发现卤离子效应下质子解淬灭C-Pd键，以及含氮配体下β-杂原子消除再生两价钯的研究后，又一新的进展。

But only a trace of transition metal ions incorporate into the framework of zeolites may provide very interesting catalytic property. Therefore the characterization of a trace of heteroatom in zeolite is very important.

然而，即使很少量的杂原子进入到沸石骨架内就会引起催化性质的较大变化，因此微量杂原子的表征也十分重要。

The procedure can be simply described as follows: heteroatoms source such as AlCl3 or TiCl4 is added into the reaction system together with silica source and surfactant and heteroatom species will uniformly dispersed in the form of ions.

调节pH值的目的在于使杂原子物种不再以离子形式而以酸根形式存在从而可以与孔壁上的硅羟基通过缩合结合在一起从而进入介孔骨架。

In one embodiment, the invention is a system for initiating free radical polymerization comprising: a in one part, one or more amido-borate compounds containing one or more anionic amido-borate moieties comprising an organoborate wherein the boron atom is bonded to a nitrogen atom of ammonia or an organic compound containing one or more nitrogen atoms, such as a hydrocarbyl amine, a hydrocarbyl polyamine, or an aromatic heterocycle containing one or more nitrogen atoms and optionally containing one or more heteroatoms or heteroatom containing functional moieties, and one or more cationic counter ions and b in a second part, a liberating compound which reacts with the nitrogen atom bound to the boron atom upon contact with the amido-borate to form an organoborane radical.

在一个实施方案中，本发明是引发自由基聚合的体系，包括：a在一个部分中，一种或多种含有一个或多个包含有机硼酸根的阴离子酰氨基-硼酸盐部分和一个或多个阳离子抗衡离子的酰氨基-硼酸盐化合物，其中的硼原子键合到氨的氮原子或含一个或多个氮原子的有机化合物，例如烃基胺、烃基聚胺或含一个或多个氮原子和任选含一个或多个杂原子或含杂原子的官能部分的芳族杂环的氮原子上，和b在第二部分中，在与酰氨基-硼酸盐接触时与键合到硼原子上的氮原子反应形成有机硼烷基团的释放化合物。

In this dissertation, we optimized the thinkness of each layer of TFEL devices using the layered optimization method to obtain ZnS: Ce〓 TFEL devices. Accoding to the energy level structure of Ce〓, two criteria for distinguishing the EL of Ce〓 were found out, from which it was conduded that the TFEL of ZnS: Ce〓 comes from 5d→4f transition of Ce〓. The measurement of brightness waveform showed that the TFEL of ZnS: Ce〓 was the luminescence from independent centers. and there were the field induced-delocalization in this process anf it〓s the cause of low TFEL efficiency of ZnS: Ce〓. In this dissertation, different influence factors on TFEL of ZnS: Ce〓 were sdudied. The influence of different host lattice is different: The blue/green ratio of ZnS: Ce〓 in hexagonal system of ZnS is larger than that in cubic system of ZnS, and the TFEL peaks in hexagonal system of ZnS moves toward longer wavelength compared with that in cubic system of ZnS. The adding buffer layer was used in this stage. The solubility of Ce〓 in ZnS was small and it was another limit to TFEL brightness of ZnS: Ce〓 device. The solubility of Ce〓 increased ten times when using Li ions as flux, so that the TFEL brightness of ZnS: Ce〓 was enhanced. It was found that the appearing of ZnO in active layer improves the TFEL of ZnS: Ce〓: the brightness and the wave range of ZnS: Ce〓TFEL were enhanced.

本文采用TFEL的分层优化方案，优化组合了各膜层厚度，选择最佳制备条件，得到了ZnS：Ce〓的TFEL；根据Ce〓的能级结构，找到了判别Ce〓的EL的两个简单依据，并据此断定ZnS：Ce〓的TFEL的两个发射峰分别属于Ce〓的〓和〓跃迁；亮度波形测量表明ZnS：Ce〓的TFEL属于分立中心发光，分析认为在此过程中存在着较严重的场致离化，这也是ZnS：Ce〓的TFEL效率较低的一个原因；本文考查了影响ZnS：Ce〓的TFEL的各种因素，发现：基质的晶体结构对ZnS：Ce〓的TFEL有所影响，在六角相ZnS中Ce〓的TFEL优于立方相ZnS中Ce〓的TFEL：发射峰的蓝-绿比相对较大，且光谱向短波方向移动，在此项研究中本文采用了在发光层前增镀过渡层的办法，过渡层为六角晶相的ZnO；限制ZnS：Ce〓的TFEL器件亮度的一个原因是Ce〓在ZnS中的溶解度低，本文用Li离子作助溶剂增大了Ce〓的溶解度，增大幅度为一个量级，并且ZnS：Ce〓的TFEL亮度明显提高；从ZnS：Ce〓的TFEL光谱来看ZnS：Ce〓的TFEL波长覆盖范围较小，亮度也不高，达不到做为白色TFEL材料的要求，需要寻找新的白色TFEL材料；在研究ZnS：Ce〓的TFEL中还发现：发光层中ZnO的出现有利于ZnS：Ce〓的TFEL：发射峰变宽、亮度增大。

In chapter 4, we study the conformations and properties of histidine and its related ions.

第四章研究了气相组氨酸及其相关离子的构型和性质。

These methanols were treated with BF3 in CH2Cl2 to generate the diferrocenylmethyl carbocations. Without separation from the reaction mixture, the ions were treated with some amines RNH2 [R=C2H5, n-C3H7, n-C4H9, HOCH2CH2, HOCH(CH3)CH2, HOCH2CH(C2H5)] to afford the ferrocenylamines in high yields. The present methodology for preparing α-ferrocenylamines from α-ferrocenyl alcohols enjoys such advantages as simple procedure and inexpensive starting materials.

它们对酸的敏感性很高，与BF3在二氯甲烷中作用可形成稳定的二茂铁基甲基碳正离子，无需从溶液中分离出来，便可与胺RNH2[R=C2H5，n-C3H7，n-C4H9，HOCH2CH2，HOCH(CH3)CH2，HOCH2CH(C2H5)]作用得到产率颇高的二茂铁基胺，这种由α-二茂铁基醇制备α-二茂铁基胺的方法具有简单、快速和原料廉价的特点。

In this homologue the transporter binds to two sodium ions and a substrate molecule.

LeuT是依赖于Na+/Cl–的神经传输物质转运蛋白在细菌中的一种同源结构。

Based on the study of the interaction of heavy metal ions with MP-11, the interaction of horseradish peroxidase with La〓 was preliminary studied.

在研究MP-11与重金属离子相互作用的基础上，初步研究了辣根过氧化物酶与La〓相互作用，发现当La〓与HRP的摩尔比较小时，HRP的二级结构变化较小。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。