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The novel complex (1) in which both benzylic nitrogens and heteroaromatic ones to the same metal ion with the rigid ligand imposed by the large heteroaromatic moiety first time was synthesized; a 2: 1 (ligand: metal ions) type complex which has steric resistance and strong thermochemical driving force was obtained. The crystal structures of characteristic ligand (LA4) and complexes (4, 7, 10), in which one cell includes two moieties: there exist minute difference in coordinated bonds and angles despite the same metal ions with the same ligand, were obtained. It shows that several stable conformation in one complex cell.

首次合成了含邻菲罗啉的具有较大刚性的四氮配体中四个氮原子全部与同一金属离子配位的配合物的晶体结构;得到了一个在空间上存在位阻作用的配体与金属离子2:1结构的晶体;解析了具有特色的一个配体(LA4)和三个配合物(4、7和10)的晶体结构,其中的配体与金属离子的配位作用显示出细微的差异,表明在同一金属配合物的晶胞中,可以同时存在着多个稳定的构象。

A series of fluorene and 2,2'-bipyridine or 1,10-phenanthroline alternate and random copolymers(P1 or P2) have been designed and synthsized, and their interaction with transition metal ions were investigated.The some accomplishments were achieved as follows:(1) It is found that the absorption red shift and fluorescence quench strongly in the presence of transition metal ions.

设计合成了一系列芴与联吡啶、菲洛啉的交替和无规共轭聚合物(P1、P2),通过研究它们与不同过渡金属离子相互作用,获得如下主要成果:(1)由于过渡金属离子的作用,吸收光谱发生不同程度的红移,以及强烈的荧光猝灭现象。

A positively-charged chemical species where the positive charge is localised on a carbon atom. Both carbenium ions (which have three bonds to a positively charged carbon) and carbonium ions (which may have five or more bonds to a positively charged carbon) are examples of carbocations.

碳阳离子:正电荷位于碳原子上的一种正电性的化学物种,碳正离子(三个键连接在带正电的碳上)和碳鎓离子(有五个甚至更多的键连接在正电性的碳上)都属于碳阳离子。

The results showed that the modified electrode was easier to electrocatalyze nitrite ions in the acidic condition. It had a better linear relationship between catalytical currents and the concentration of nitrite ions.

结果表明,该修饰电极在酸性条件下易于对NO2-催化,并且催化电流与NO2-的浓度在一定范围内呈现良好的线性关系。

The molar ratio of sulfate ions to carboxylate ions is determined by conductometric titration method and the molecular weight is tested by high performance gel permeation chromatography. The precision of these two methods is also studied. To improve the detection sensitivity, guanidine hydrochloride is used as the best derivation reagent of 911. A systematic research is done on the optimum derivatization condition of 911 and Guanidine hydrochloride. The M /G ratio of 911 has direct relation to its biological activity.

论文首先对911的基本理化性质进行了系统的分析,以电导滴定法和高效凝胶渗透色谱法分别测定了分子中硫酸根羧酸根的比值和911的分子量,并探讨了两种分析方法的精密度。911分子没有紫外吸收,为提高检测灵敏度,本文采用荧光标记法,通过对三种荧光试剂与几种寡糖和多糖衍生效果的综合比较,最终确定了盐酸胍为最佳衍生试剂,并以911为代表详细探讨了衍生化反应的最优条件。911糖链结构与褐藻胶主链结构类似,以甘露糖醛酸和古罗糖醛酸的嵌段形式存在,分子中M/G比值与911的物理化学性质和生物活性有直接关系。

These data were used to infer the molecular formula and the elemental compositions of all the fragmental ions through software interpretation and, by further applying fragmentation regularities of mass spectrometry, the majority of ions were fully assigned. A base peak at m/z 402 in the mass spectrum was found as the molecular ion. The fragments were created mainly from the fragmentations of the tetrahydrofuran rings and the hydroxyl group. The most fragment products contain the dimethoxy phenyl group.

利用这些数据通过软件导出了分子式和所有碎片离子的元素组成,由此进一步根据质谱裂解规律对石梓醇分子的电子轰击质谱的主要裂解碎片给出了完全的归属,质谱中发现基峰为分子离子峰(m/z402),裂解碎片主要来自双骈四氢呋喃环的裂解和羟基引起的裂解,绝大部分裂解产物包含二甲氧基苯基基团。

Any decision-whether made by government, by a corporation, or by an in dividual person-must take into account future cond IT ions more than present cond IT ions.

一个决策,不管政府、企业抑或个人做出的,都应该考虑将来的情形多于目前的情形。

In this thesis, inorganic ions were assembled to films by the interactions of the ions with functional groups of the polyelectrolyte, and then inorganic nanoparticles/polyelectrolyte composites films were prepared through chemical reaction. The properties and application of the films in electrocatalysis were studied.

本论文利用无机离子与聚电解质功能基团间的相互作用,用层层自组装的方法将无机离子组装到膜中,然后通过化学反应制备无机纳米粒子/聚电解质复合膜,考察了复合膜的性质及在电催化方面的应用。

The germinative number of horsebeans and peas were raised by 44% with activated water by tourmaline. 200μl 1 X 10~6/ml mouse's H_(22) cell, 200μ 4X 10~6/ml splenic cell, 200μl 1 × 10~6/ml epidermal cell were all inhibited after the action of tourmaline. It is analyzed that the factors which effected the multiplication of the cells included direct action which are tourmaline's electric field, far-infrared, negative ions and solvent ions, and indirect effect which are small water clusters and pH value.

电气石活化水使蚕豆和绿豌豆种子发芽速度均提高44%。0.5g电气石分别对200μl 1×10~6/ml的小白鼠H_(22)肝癌细胞,对200μl 4×10~6/ml小白鼠脾细胞,对200μl 1×10~6/ml的小白鼠表皮细胞的增殖起抑制作用,分析认为,电气石影响细胞增殖的因素包括电场、红外线、负离子和溶出离子对细胞的直接作用和通过改变水分子结构、培养基pH值的间接作用。

Among them,the chemosensory properties of two molecular tweezers derived from diethoxycarbonyl glycoluril for metal ions were studied by fluorescent spectroscope.It was found that they both exhibited selective recognition towards Fe~(3+)among 13 metal ions investigated in DMF/CH_3OH(50:1, v/v)with fluorescence quenching,and formed 1:1 stoichiometry complex with Fe~(3+).

通过荧光光谱滴定考察了其中两个二乙基酯基甘脲分子钳异构体对13种不同金属离子的识别作用,研究表明在DMF/MeOH(50:1 v/v)中,它们能够很好地选择性地识别Fe~(3+)离子,与Fe~(3+)离子形成1:1的复合物并且呈现荧光淬灭效应,可作为Fe~(3+)的荧光化学传感器。

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This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。

There is no differences of cell proliferation vitality between labeled and unlabeled NSCs.

双标记神经干细胞的增殖、分化活力与未标记神经干细胞相比无改变。