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Suppressor is the key part for IC instrument, and developing a high performance suppressor for IC instrument is quite important to gradient ion chromatography, to analysis of some ions which have strong affinities with the functional groups located on the surface of the pellicular ion exchange column packing.

抑制柱是离子色谱仪的一个核心部件，研制具有较高抑制容量的抑制柱对于离子色谱法的梯度淋洗、对于在分离柱上保留时间长的离子分析具有重要的意义。

Cu2-Co2-KBr with high catalytic activity and selectivity shows synergistic effect between metal ions.Under the reaction conditions of mCu(Ac2:mCo(Ac2:m= 0.1:0.5:0.1, n:n=0.14, glacial acetic acid as solvent, overdosage sodium percarbonate, 65℃, the conversion can reach 45.9% and the selectivity for p-methoxy benzaldhyde is about 68.3%.

结果表明，Cu2-Co2-KBr具有较高的催化活性和选择性，体现出金属离子之间的协同作用，对甲基苯甲醚在mCu(Ac2：mCo(Ac2：m=0.1：0.5：0.1，n：n=0.14，冰醋酸作溶剂，稍过量的过碳酸钠，65℃的条件下，转化率可达45.9%，生成对甲氧基苯甲醛的选择性为68.3%。

Complete active space self-consistent field calculations with aug-cc-pVTZ basis sets were performed for twelve low-lying electronic states of the methyl peroxy radical CH3O2 and its positive and negative ions in C symmetry.

在C对称性和aug-cc-pVTZ基组水平下，采用全活化空间自洽场方法研究了CH3O2自由基基态及其阴阳离子的12个低激发态。

Complete active space self-consistent field calculations with aug-cc-pVTZ basis sets were performed for twelve low-lying electronic states of the methyl peroxy radical CH3O2 and its positive and negative ions in C s symmetry.

侯春园，郑清川，舒鑫，张红星*摘要：在 Cs 对称性和aug-cc-pVTZ基组水平下，采用全活化空间自洽场方法研究了CH3O2自由基基态及其阴阳离子的12个低激发态。

Further application of the partially perturbative density functional theory to MX2-NX-H2O solution indicates that the present theory is better than the Poisson-Boltzmann equation and can be used to predict the structures and ion-partitioning of high-valent ions in charged nanopores.

对混合电解质溶液MX2-NX-H2O的结果同样表明本文的部分微扰的密度泛函理论要好于传统的Poisson-Boltzmann方程，且能够预测高价离子在带电纳米孔内的结构与分配。

The results showed that terephthalic acid in the carboxyl oxygen and the phenanthroline nitrogen atoms with transition metal ions (Co2 +, Cu2 +, Fe3 +) coordination.

结果表明，对苯二甲酸中羧基氧和邻菲罗啉中的氮原子均与过渡金属离子（Co2+、Cu2+、Fe3+）配位。

In this research, two novel compounds in which alkylenedithiomethylene Malonic acid act as the main coordination agents and the compounds containing N atom (such as pyridine, Phenanthroline Ethanediamine and 4,4'-Bipyridinyl) act as the associating coordination agents have been synthesized by the means of solution and solid-liquid diffusing reactions. 9 coordination complexes and polymers have been designed and synthesized in which the transition metals Cu and Zn acted as the centre ions. These compounds have been characterized by X-ray single crystal diffraction analysis, and some properties of them have been tested and analyzed.

本论文设计合成了两种结构新颖的含有二硫缩烯酮结构的丙二酸类化合物，以此为主要配体，以含氮化合物(吡啶、邻菲罗啉、乙二胺和4，4'-联吡啶)为辅助配体，采用常规溶液合成和固-液相扩散等方法，设计合成了9个过渡金属Cu和Zn离子配合物和配位聚合物，采用单晶X-射线衍射等技术对晶体结构表征，并对其部分性质进行了测试和分析。

Several aminated Fullerene derivatives were synthesized by the reaction of C〓 with phenylamine, diphenylamine and triethylamine etc., the phenomena of fragmentation and aggregation of the aminated Fullerene derivatives in UV laser desorption ionization mass spectrometer was observed, a few nitrogenous poly-Fullerene ions, such as C〓NH, C〓N〓H〓, C〓N〓H〓, C〓N〓H〓, C〓N〓H〓 etc.

对C〓富勒烯与苯胺、二苯胺、三乙胺等形成的加合物在紫外激光解吸电离作用下可以发生不同寻常的裂解和聚合现象进行了研究，认为其形成机理为：上述加合物在紫外激光解吸电离作用下，发生裂解产生C〓NH、C〓N及C〓等离子，然后它们之间发生聚合，形成如：C〓NH、C〓N〓H〓、C〓N〓H〓、C〓N〓H〓、C〓N〓H〓等含氮原子的聚富勒烯离子。

Separation of complexes of different pheophytins with the same rare earth ion was firstly accomplished by reversed-phase HPLC, but the attempt of separation of complexes of pheophytin with different rare earth ions was unsuccessful.

首次实现了对同一稀土不同叶绿素配体所形成的配合物之间的色谱分离，然而不同稀土同一叶绿素配体所形成的配合物之间的分离尝试未获得成功。

Correlation coefficient: 0.9962 . Positively charged'free'complex ions should be readily quenched by 〓, but when it is bound to DNA, it can be protected from the quencher because the highly negatively charged 〓 would be repelled by the negative DNA phosphated backbone, hindering quenching of the emission of the bound complex.

从理论上讲，带正电的配合物的阳离子应该可以被大阴离子淬灭，但是在DNA存在下，金属配合物插入到DNA的碱基对中，而〓被带负电荷的DNA磷酸骨架强烈排斥，从而避免了〓的淬灭，因此大的Stern-Volmer曲线斜率相应于对配合物较弱的保护形式。D。

"Please accept this talisman as a token of our thanks."

请收下这个护身符以表达我们的感谢。

If I have that magic, I will be more acceptable in the society.

如果我拥有那种魔法，我将更加被这个社会所容纳。