查询词典 ionic

The results show that, with the increase in ionic strength, the adsorbed amount of taurine on the resin D290, the distribution coefficient λ and the fraction of zwitterion Tau(superscript ±) all decrease, while the pH value of the solution at the equilibrium and the content of anionic taurine Tau(superscript -) increase. Moreover, it is found that, at a certain taurine concentration, the increase in ionic strength may improve the selectivity of the anion resin for taurine.

研究结果表明：(1)随着溶液离子强度的升高，阴离子树脂对牛磺酸的平衡交换吸附容量逐渐降低，牛磺酸在树脂上的分配系数λ逐渐下降；(2)随着溶液离子强度增大，达到平衡时液相的pH值升高，溶液中牛磺酸阴离子Tau含量迅速增加，而牛磺酸两性离子Tau含量迅速降低；(3)在一定的牛磺酸浓度范围内，溶液离子强度增大，有利于提高离子交换树脂对牛磺酸的选择性。

Taking advantage of better solubility and thermal stability of ionic liquid, the ionic liquid supported acetylacetone catalyst can be simply recycled by water washing or vacuumdistillation.The background of this research is renovation on the traditional oxidation reactions by green chemistry principle.

根据离子液体支载催化剂的两个特性：在水中良好的溶解性和具有很好的热稳定性，在反应结束后通过水洗涤或精馏的方法，很方便的对催化剂进行了回收再利用。

Basing on above researches, we designed a series of ionic liquid supported acetylacetone metal catalysts and non ionic liquid supported acetylacetone metal catalysts. The catalytic abilities of these catalysts were evaluated by using them to catalyze the methane oxidation reaction.

在以上研究的基础上，本论文设计了系列离子液体支载的乙酰丙酮金属催化剂及非离子液体支载的乙酰丙酮金属催化剂，并通过这些催化剂对甲烷氧化反应的催化效果来预测它们的活性。

It is the fluorosilicic ion that exsits in the slurry and plays an important role in flotation, fluorosilicic ion not only reacted with Fe〓 on the surface of aegirine to form ionic compound, but also formed stable Si-F bond in Si-O etching reaction. Only ionic compound was obtained when it was attached to hematite surface according to the theories of coordination chemistry, Compared with SiF〓, Fatty acid ion preferentially acts with Fe〓 on the minerals surface, therefore, SiF〓 Can't obstruct the adsorption of collector on the surface of hematite completly, but can reduce the flotation recovery of aegirine selectively.

运用FTIR、XPS等测试方法仔细研究了氟硅酸盐抑制剂对含铁硅酸盐钠辉石的选择性抑制作用机理，氟硅酸盐在弱酸性条件下对赤铁矿浮选的抑制作用很微弱，而对含铁硅酸盐钠辉石强烈抑制，从而扩大了两者之间的浮选差异；SiF〓是矿浆中起抑制作用的主要成分，SiF〓不仅与钠辉石表面的Fe〓形成离子型配合物，而且还与Si-O键形成稳定的Si-F共价键，而与赤铁矿表面只能形成离子型配合物，根据晶体配位场理论，与SiF〓相比较羧酸根离子将优先与矿物表面Fe〓发生配位作用，因此SiF〓的存在并不能完全阻碍捕收剂在赤铁矿表面的吸附作用，却能够选择性地抑制钠辉石的上浮。

For low molar ratios of Al/Zr, a hypsochromic shift of the initial catalyst absorption band, corresponding to the monomethylation of the catalyst, was observed. Further addition of AlEt2Cl was accompanied by a continuous bathochromic shift of the maximal wavelength corresponding to the formation of more dissociated ionic active species. Then, there would be a coordination of monomer to the ionic active species.

结果表明，无论是AlEt_2Cl还是MAO，少量的助催化剂首先使催化剂发生单烷基化反应，主催化剂金属中心的最大吸收峰波长发生蓝移，而当助催化剂量进一步增加时，金属中心的最大吸收峰波长红移，单烷基取代的催化剂被大量的助催化剂夺去电子成为缺电子的阳离子活性中心，以便烯烃单体的配位插入。

Enzymes of widely different types are catalytically active in ionic liquids or aqueous biphasic ionic liquid systems.

许多酶能在ILs或其形成的两相体系或单相体系中保持催化活性。

On the other hand, a method for the synthesis of-vinyl chalcogenides by the coupling of vinyl bromides with thiols or diphenyl diselenide using copper salts as catalysts in ionic liquids based on amino acids also has been described. The ionic liquids play multiple roles in the reaction: they act as solvent, base, and excellent promoter for the copper-catalyzed coupling reactions.

在新型的氨基酸负离子的离子液体中，开发了一个亚铜盐催化的Z-型溴代烯烃与硫族元素的交叉偶联反应，为立体选择性的制备Z-型烯基硫醚或烯基硒醚类化合物提供了一个新的方法；在此反应体系中，离子液体不仅起到了反应溶剂的作用，而且还起到了金属催化剂的配体和中和反应副产物的碱的作用。

A new method was proposed to prepare water-soluble ionic liquids by using four-compartment electrodialysis.1-Ethyl-3-methylimidazolium tetrafluoroborate (［EMIm］BF4), used as a model ionic liquid, was synthesized.

以1-乙基-3-甲基咪唑四氟硼酸盐（［EMIm］BF4）的制备为例，对四隔室电渗析法制备水溶性离子液体进行了研究。

Transesterification of geranol and vinyl acetate in ionic liquids were investigated to synthesize geranyl acetate using immobilized Candida antarctica lipase B as biocatalyst. The reuse of ionic liquids and lipase were also studied in this reaction.

以固定化的南极假丝酵母脂肪酶为催化用酶催化香叶醇和乙酸乙烯酯在离子液体中的酯交换反应，合成了香料乙酸香叶酯，同时通过该反应了解了酶和离子液体的重复利用性。

When doping the first periodic transition elements in TiO〓, the relationships between the photocatalytic activities and the ratio of electronic affinity energy to the ionic radius and the ionic magnetic moment of heteratomic ion were studied.

通过第一过渡系元素对纳米TiO〓光催化剂的掺杂，发现催化活性与掺杂元素的稳定氧化态的电子亲和势Ea与离子半径r的比值Ea/r有顺应关系，该比值越大，催化活性越低。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。