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In chapter four, the preperation of ytterbium diiodide was examined. The reductive cleavage of Se-Se bond and S-S bond induced by ytterbium diiodide was investigated. The reaction of diselenides and disulfides with allylic bromide promoted by ytterbium diiodide was also examined. The intermolecular Barbier-type reaction induced by ytterbium diiodide was studied. In the last section of this chapter, the intermolecular reductive coupling of nitriles with azides induced by samarium diiodide was investigated.

第四章,研究了二碘化镱的制备方法,以及二碘化镱作为一种优良的单电子转移试剂在有机合成中的应用:二硒醚的Se--Se键和二硫醚S-S键的还原断裂,及其在合成烯丙基硒醚,硒代酯和烯丙基硫醚,硫代酯中的应用,实验结果表明二碘化镱也能促进分子间的Barbier反应,而文献认为二碘化镱不能促进分子间的Barbier反应;最后研究了二碘化钐促进的叠氮化合物与腈的交叉还原偶联反应,一步高收率地制备脒的方法。

In this article, we have been investigated that synthesizing and properties of shape memory polyurethane. The shape memory polyurethane was synthesized from PCL diol, MDI(4, 4'-diphenylmethane diisocyanate) and BDO (1,4-butanediol) in this experiment. We analyzed that the effect of differential mole ratio of monomers to synthesized SMPU. Besides, the various concentrations of Nano-silver were mixed with SMPU. Mechanical properties and shape memory behavior of SMPU nanocomposite films were investigated.

本研究目的为藉由改变4,4'-二苯甲基二异氰酸盐(4,4'-diphenylmethane diisocyanate, MDI)/聚己内酯二元醇(polycaprolactone diol, PCL diol)/1,4-丁二醇(1,4-butanediol, BDO)等不同莫耳比制备形状记忆型聚氨基甲酸酯(Shape Memory Polyurethane, SMPU);并探讨改变不同单体莫耳比及添加不同浓度奈米银溶液对其物性及形状记忆性的影响。

For the question of distribution and acceleration of ionospheric ions O+,H+ and He+ in the magnetosphere, the ions static distribution function is found by solving the dynamic equation, and the up-flowing ion static distributions with various Kp indexes are investigated. The ions distribution function during the geo-magnetic dipolarization is simulated, and the upflowing ion acceleration in the magnetotail is investigated.

针对磁层中电离层离子O+、H+和He+分布与加速问题,采用动力论方程求解了离子定态分布函数,研究了不同Kp指数条件下上行离子的定态分布;模拟了磁场偶极化过程中离子分布函数随时间的变化,研究了上行离子在磁尾的加速。

Cu-C composite is one of the most potential materials for pantograph slide plate, which is an important component of pantograph system in locomotive. The principle of wettability between Cu and C was investigated in this paper. The element of Mo was selected to improve the wettability between Cu and C. The fabrication process of cold compression sintering fiber reinforced Cu-C composite and its effect on the composite property were studied. The wear and friction mechanism of Cu-C composite was investigated initially by electriferous friction test.

Cu-C材料是目前最具应用前景的电力机车受电弓滑板用材料之一,本文研究了Cu与C之间的润湿原理,利用Mo元素有效改善了Cu与C之间的润湿性;并对冷压烧结法制备纤维增强Cu-C复合材料的工艺过程及其对性能的影响进行了研究;通过带电摩擦试验对Cu-C复合材料带电摩擦磨损机理进行了初步探讨。

The condition factors in ethanolysis reaction,namely the reaction of rapeseed oil with ethanol catalyzed by lipase LVK,to produce bio-diesel were investigated,and the factors included molar ratio of ethanol to oil,catalyst dosage,reaction temperature,reaction time,and so on;the effect of organic solvent and the procedure of ethanol addition were also investigated.

得出脂肪酶催化菜籽油乙醇解制备生物柴油的最佳反应条件为:醇油摩比5:1、催化剂用量10%、反应温度40℃、反应时间为36 h、正己烷15%。

Two synthetic routes starting from 1,3-dihydroxyacetone and formamidine acetate as well as imidazole-4,5-dicarboxylic acid as starting material were investigated, and the reductive reaction of ethyl imidazole-4-carboxylate was also investigated.

本文对以1,3-二羟基丙酮和醋酸甲脒为原料和以4,5-二羧酸咪唑为原料合成4(5)-羟甲基咪唑的两条工艺进行了研究并优化,同时对4(5)-羧酸咪唑乙酯的还原反应进行了探索性实验。

We investigated the receiver functions in a horizontally-layered medium with arbitrary oriented hexagonally symmetric anisotropy, and discussed the phenomenon of shear-wave splitting and energy deviation in an anisotropic medium. The anisotropic structure yields patterns of receiver function amplitudes and arrival times on both the radial and transverse components that are a systematic function of source-receiver back azimuth. We also investigated the influence of varying anisotropy parameters, e.g.

采用具有任意方向对称轴的横向各向同性介质系统,探讨了各向异性介质中接收函数表现出的横波分裂、能量偏离等特征,并系统剖析了各向异性介质对称轴方位角、倾角以及各向异性层位分布对接收函数方位变化花样的影响。

Heterotypic sex chromosome was investigated on the metaphase chromosome of half-smooth tongue-sole and homotypic sex chromosome were investigated on the metaphase chromosome of half-smooth tongue-sole.

将GFP报告基因通过脂质体介导的方法转入SFEC和HTLC中并成功地获得了表达,转化率为20%左右。

Determination of functional components in foods and Chinese herbs as well as evaluation of biological activity – Both foods and Chinese herbs investigated include soybean, Ziziphus jujuba , Lycium barbarum , Gynostemma pentaphyllum , Taraxacum formosanum , Rhinacanthus nasutus , Scutellaria barbata , etc. Functional components investigated include carotenoid, chlorophyll, flavonoid, phenolic acid, polysaccharide, saponin, isoflavone, etc. In my lab we have developed many LC-MS methods for determination of these components and proved their antiproliferation effect on cancer cells and anti-inflammatory activity.

食品及中草药有效成分测定及其对生物活性的影响-探讨的食品包括大豆、蕃茄、芒果等等,中草药包括红枣、枸杞、七叶胆、蒲公英、仙鹤灵芝草、半枝莲等等,有效成分则包括类胡萝卜素、叶绿素、类黄酮、酚酸、多醣、皂苷、异黄酮等等,本实验室已成功开发多种LC-MS方法测定这些成分并证实这些成分具有抑制癌细胞增生及抗发炎的功效,已有多篇论文发表於国际著名期刊。

The working principle of the deployment control mechanism of appendages is investigated in detail, the feedback control model is established. And the effect of parameters to synchronized motion is discussed, in addition the nonsynchronous motion is investigated through the analysis of the principle for deployment control mechanism and driving mechanism and simulation.

针对在工程实际中发现的帆板展开运动不同步现象,本文详细分析了最常见的附件展开控制机构—CCL的工作机理,建立了CCL的反馈控制模型,并给出其具体的数学表达式,讨论了机构参数对帆板运动同步性的影响,进而通过对展开控制机构和展开驱动机构的机理分析和数值模拟讨论了帆板的不同步现象,并提出了减小不同步量的策略。

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Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时,他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

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The enrich the peopling of Deng Xiaoping of century great person thought, it is the main component in system of theory of Deng Xiaoping economy, it is a when our country economy builds basic task important facet.

世纪伟人邓小平的富民思想,是邓小平经济理论体系中的重要组成部分,是我国经济建设根本任务的一个重要方面。