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A series of fluorene and 2,2'-bipyridine or 1,10-phenanthroline alternate and random copolymers(P1 or P2) have been designed and synthsized, and their interaction with transition metal ions were investigated.The some accomplishments were achieved as follows:(1) It is found that the absorption red shift and fluorescence quench strongly in the presence of transition metal ions.
设计合成了一系列芴与联吡啶、菲洛啉的交替和无规共轭聚合物(P1、P2),通过研究它们与不同过渡金属离子相互作用,获得如下主要成果:(1)由于过渡金属离子的作用,吸收光谱发生不同程度的红移,以及强烈的荧光猝灭现象。
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The hydrogen-bonded dimer and trimer formed between 1,3,5-benzenetricarboxylic acid and bipyridine have been investigated using a density functional theory method and 6-31++G** basis set.
使用密度泛函理论B3LYP方法和6-31++G**基函数对1,3,5-苯三甲酸与联吡啶形成的氢键二聚体和三聚体进行了理论计算研究。
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Cation and anion effects on permeation amount of 2,2'-bipyridyl through the molecularly imprinted polymer membrane was investigated respectively.
分别考察了阳离子和阴离子对印迹膜渗透模板分子的影响。
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The interaction between bipyridyl and In was investigated by the methods of electrochemistry,UV spectra and difference UV spectra,the results of which were explained,the match ratio was got.
研究了In与联吡啶作用的紫外吸收光谱、紫外差光谱及电化学性质,根据二者相互作用时的紫外光谱及差光谱,得到了二者的配位比。
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Finally, the interaction of DNA with electrochemical inactive molecule 2, 2'-bipyridyl was investigated by electrochemistry, the equilibrium constant was estimated.
在此基础上,以纳米氧化锆为连接剂,将DNA玻碳电极表面,以铁氰根为电化学探针研究了镧系离子对DNA电子传递行为的影响;用电化学方法研究了DNA在纳米氧化锆上的吸附作用和非电活性有机小分子与DNA的相互作用,计算了DNA与2,2'-邻吡啶的络合平衡常数。
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The influence of acidity and concentration on fluorescence and absorption spectra were investigated. Using quinine bisulphate as a reference, fluorescence quantum yield of aesculetin in the condition of pH=9.32 was determined to be 0.13 at excitation wavelength 365nm.
考察了酸度与浓度对其荧光性质和吸光性质的影响,以硫酸奎宁为参比,测得秦皮乙素水溶液在pH=9.32,激发波长365nm条件下的荧光量子产率为0.13。
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The influence of acidity on fluorescence and absorption spectra were investigated. Using quinine bisulphate as a reference, fluorescence quantum yield of aesculin in the condition of pH=4.96 was determined to be 0.76 at excitation wavelength 335nm, and in pH=9.40 was 0.80 at 375nm.
探讨了酸度与浓度对其荧光和吸光性质的影响,以硫酸奎宁为参比,测得秦皮甲素水溶液的两种强荧光型体的荧光量子产率,在pH=4.96,激发波长335nm条件下,荧光量子产率为0.76;在pH=9.40,激发波长375nm条件下,荧光量子产率为0.80。
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The factors which affect the average molecular weight of the polymer of AM and DMDAAC were investigated. The optimal reaction conditions are as follows: the concentration of monomer AM was 30%, while DMDAAC was 5%; the reaction temperature was 30℃, the amount of initiators at the low temperature stage was 0.05‰(compared to the weight of the monomers joining the polymerization), while V-50 was 0.025‰, the weight ratio of potassium persulphate to sodium bisulphite is 1:1, the amount of carbamide was 40‰, and complexing agent was 0.05‰, besides, aerate nitrogen gas for 8min, then the high molecular weight polymer (M=1.217×10^7) could be got after 16h reaction.
研究了影响AM与DMDAAC共聚物的平均分子量的因素,得到了优化条件为:单体浓度为30%,DMDAAC与AM摩尔比为5:95,聚合温度为30℃,低温段引发剂用量为0.05‰,K2S2O8与NaHSO3质量比为1:1,偶氮二异丁基脒盐酸盐(V-50)用量为0.025‰,尿素用量为40‰,乙二胺四乙酸二钠(EDTA-2Na)用量为0.05‰,在此优化条件下聚合反应16h后得到分子量为1.217×10^7的阳离子型聚丙烯酰胺。
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Schedel et al. investigated the efficacy of Hirudoid forte in 40 patients with postoperI bitis under double-blind conditions in comparison to placebo.
Schedel等人研究了特强喜疗妥软膏的疗效,以安慰剂为对照,双盲,受试对象为40位患者。
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This method can analyze the concentration degree of thevibratory energy so that the characteristics of the vibration localization of themistuned bladed disk can be investigated.
摄动法是分析失谐叶盘振动响应的重要方法,而不同的摄动法对于叶盘结构的系统参数有着不同程度的依赖性。
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- 推荐网络例句
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The production moved off-Broadway to New York City, where she won the Joseph E. Calloway award for her performance, and was profiled in American Theater Magazine as one of ten young theater artists to watch.
生产提出过百老汇的新的纽约市,在那里她赢得了约瑟夫calloway奖,她的表现,并于异型在美国的战区杂志之一, 10战区的青年艺术家观赏。
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It's a risk tradeoff, and I believe that adding test support code usually wins.
这是一个风险的权衡,我相信添加测试代码通常会占上风。
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Besides, Fantine was only a moderately good workwoman
芳汀究竟还只是一个手艺平凡的工人。