查询词典 intramolecular

According to the variations of the luminescence efficiency and the phase shifts, the intramolecular energy transfer and relaxation processes of different complexes are discussed.

根据发光效率的变化和光声位相偏移，对它们的分子内能量传递和弛豫过程进行了研究。

The models of intramolecular and intermolecular energy transfer and relaxation processes are established.

Phen〓的发光效率大大减小，这是由于不同配合物分子间能量传递过程差别引起的，由此建立了分子内和分子间能量传递和弛豫过程模型。

The intramolecular proton transfer reactions have attracted great experimental and theoretical interests due to its importance to chemistry and biochemistry.

分子内质子转移反应由于其在化学和生物化学领域的重要性而在实验和理论上都引起了广泛的重视。

It contains 6 cysteines, forming 3 intramolecular disulfide bonds.

结构中含有6个半胱氨酸，形成3对分子内二硫键。

This result is in good agreement with the intramolecular character of the PMMA γ relaxation motions.

DMA测试也表明，低温处存在明显的局部运动。

Below the cac, there is mostly intramolecular association.

下面嘉年华，有多半是内协会。

Molecular configurations in LB films undergo change from keto form to zwitterion assurface pressures increase,companied by intermolecular hydrogen bonds decreaseand intramolecular hydrogen bonds increase.

在LB膜中，随表面压增加，分子间氢键减少，分子内氢键增加，SBC18头基构型在转折区发生醌式→双性离子构型转变。

When surface pressures are lower than the turnover(5～30mN/m),intermolecularhydrogen bonds were formed with keto form and phase transition was higher ca.60℃;most of SBC18 formed intramolecular hydrogen bonds companied withzwitterion form and phase transition was lower ca.48℃ while at surface pressurehigher than the turnover(≥45mN/m),which is caused by the different interchaininteraction arising from various hydrogen bonds for SBC18 LB film deposited atdifferent surface pressures.

低于相应π-A等温线转折(5～30mN/m)时，以分子间氢键为主，头基主要以醌式构型存在，相变温度较高(≈60℃)；高于转折(≥40mN/m)时，以分子内氢键为主，头基主要以双性离子构型存在，相变温度较低(≈48℃)。

Methanol molecule participates in the proton transfer process, which takes place by a intermolecular six-membered proton-transfer transition state structure instead of the intramolecular four- membered. Consequently, the activation energy of the proton-transfer process is reduced greatly,resulting in the carbon-carbon bond formation process become the rate-determining step. The results are consistent with Aggarwal's the latest dynamics experiments.

CH3OH分子参与质子转移过程，使得原本通过四元环结构过渡态的质子转移过程通过六元环结构过渡态实现，从而极大地降低了质子转移过程的活化能，碳-碳键形成过程进而成为反应的速度控制步骤，研究结果与Aggarwal等的最新动力学研究成果相吻合。

The complicated electronic features of the coordinated polymer has primarily been understood by investigation of the relationship of the intramolecular electron transfer, the intermolecular electron transfer and the aggregate structure, which provides certain experimental and theoretical basis for the development of novel metallo-organic photo-electronic functional materials.

通过研究分子内、分子间电荷转移和聚集态结构三者之间的关系，初步掌握了配位聚合物的复杂电子特征，为开发新型金属有机光电子功能材料提供了一定的实验和理论依据。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。