查询词典 intramolecular

A series of diazonium salts of 4-(N-methyl-N-phenylamino)-3-amino-1,8-naphthalic anhydride 5a, its naphthalimide derivative 5b, and 5e were designed and synthesized,and it was the first time to discover that aromatic radical-induced intramolecular aromatic 1, 5-hydrogen transfer was also involved in the nitrogen-contianed system during Pschorr cyclization.

实验设计合成了4--3-氨基-1，8-萘酐的重氮盐5a、其衍生物N-丁基-4--3-氨基-1，8-萘酰亚胺的重氮盐5b和N--4--3-氨基-1，8-萘酰亚胺的重氮盐5c，并首次发现了通过普朔尔环化反应以氮甲基化的氮为桥原子的体系存在着芳香自由基诱导的芳香1，5-氢转移。

Polyfluoroalkyl iodides could react with unsaturated olefin acids in the presence of sodium dithionite by radical addition to give adducts. It was found that these adducts could form polyfluoroalkyl substituted γ or δ-lactones due to intramolecular nucleophilic substitution in the alkali solution.

研究发现：多氟烷基碘化物在连二亚硫酸钠存在下与不饱和烯酸经自由基加成得到的产物，能在碱性条件下进行分子内亲核取代反应形成五元或六元环的含氟内酯类化合物。

A large number of bond-type complexes, as long as the hydrogen of the molecules covalently coupled to the molecular approach in an electronegative atom up, that constitutes a hydrogen bond, there are intramolecular hydrogen bonds and intermolecular hydrogen bonds of the points, will affect the formation of complex reaction carried out, such as in solution adding dioxa cyclohexane, or tetrahydrofuran, will reduce the alkylation reaction rate.

氢键型络合物为数众多，只要含氢的分子以共价键方式耦合到分子中一个电负性原子上去，即构成氢键，有分子内氢键和分子间氢键之分，络合物的形成将会影响反应的进行，如在溶液中加入二氧杂环己烷或四氢呋喃，都会降低烷基化反应速率。

In some cases, its epimer 4 was also obtained. 22 compounds were synthesized, among them 18 were new.3. Using the intramolecular Pictet-Spengler reaction to form the pentacyclic skeleton of Et-743, the byproducts 25 were obtained under various conditions. The structures of them were determined to be 1, 2-dihydro-isoquinoline compounds, and the mechanism of the reaction was proposed.B. The synthesis of the analogs of Et-743Because of the failure of removing the protective groups in compounds 14, the synthetic strategy was adjusted.

对于苄基保护的羟基化合物13a，顺利得到化合物30，然后与不同的羧酸反应得到18个酯化合物33-50；对于苄氧羰基保护的氨基化合物13b，由于脱除保护基的化合物31在空气中不稳定，所以我们采取不经分离纯化，直接与羧酸反应得到酰胺化合物53-62，然后再分别对其C-21位的羰基进行还原氰基化，得到10个酰胺目标化合物63-72，另外，我们还对羟基转化为氨基的反应进行了探索。3。

Appling proteomics,we can detect various of characteristic proteome,which induce intramolecular or extramolecular aggregation in α-crystallin and reduce its activity and accelerate the cataract formation.

白内障发生时，多种疾病特征性的蛋白质组改变，可导致α-晶体蛋白分子内或分子间的交联，分子伴侣活性下降，加速白内障的形成。

A model for computing the electric field dependent rate constants of gas-phase intramolecular electron transfer reactions by classical path method has been proposed within the activated-complex framework.

用经典轨迹方法，在过渡态理论框架下，提出外电场中气相分子内电子转移反应的速率常数计算模型，并用电子定域初始猜测诱导UHF-SCF技巧实现了两电子定域准透热态的分离。

Keywords: Molecular assembly; DNA; Cyclodextrin; Flourescent probe; Intramolecular charge transfer

中文关键词：组装；DNA；荧光探针；环糊精；分子内电荷转移

Molecular assembly; DNA; Cyclodextrin; Flourescent probe; Intramolecular charge transfer

此外，合成了含硼酸的具有分子内电荷转移的荧光探针，研究它与人血清白蛋白、DNA及药物的作用机理。

Therefore, it is presumed that the planarity of HPB from intramolecular hydrogen bonding is one of the driving forces for gelation.

因此， 这是假设的，从分子planarity HPB 氢键是一种动力为胶凝性。

All these dyes allowed detection for anions such as F~- and AcO~- in CH_3CN, which is likely to be related to the enhancement of intramolecular charge transfer induced by instance deprotonation of compounds.

在加入碱性较大的阴离子后，化合物1-4的乙腈溶液的紫外可见吸收光谱均发生了明显的红移，表明1-4是一类较好的阴离子化学传感器。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。