查询词典 intramolecular

Because of different twist angle between the arene and aryl-bipyridine, Ppbpy displayed intermixing behaviors of local excited state (1La and 1Lb) and intramolecular charge transfer, but Apbpy only showed the properties of local excited state 1La.

由于芘和蒽与6－苯基-2， 2'-联吡啶间的夹角不同，Ppbpy的激发态具有原位激发态(1La and 1Lb)和分子内电荷转移的性质，而Apbpy的激发态仅仅表现出原位激发态1La 的性质。

The strategy toward the synthesis of spirotryprostatin B is focused on MgI2-catalyzed intramolecular annulation reaction of cyclopropanyl spiroox--indole and imine.

以天然产物的全合成为目标，设计了MgI_2催化的螺氧吲哚化合物与亚胺分子内环合反应，构建目标分子骨架的策略。

In addition, the intramolecular interactions of aromatic amino acids are characterized using AIM theory.

另外，应用分子中的原子理论研究芳香型氨基酸构型的分子内相互作用。

The intramolecular interactions of asparagine coformers are characterized using AIM theory.

我们使用AIM理论对天冬酰胺的分子内相互作用进行了研究。

Some new lignans of dibenzocycloheptadiene and benzofuran analogues were first synthesized successfully by intramolecular nonphenolic oxidative coupling and rearrangement of the 1,4-biaryl-2,3-dimethyl-2,3epoxide substituted butanes with DDQ in TFA.

以DDQ为非酚氧化偶合试剂与1，4-二芳基-2，3-环氧类化合物进行分子内的非酚氧化偶合反应，首次合成了二苯骈环庚二烯类和苯骈呋喃类的新型木脂素，其结构由不同光谱和X-单晶衍射所确证。

It was suggested that the solubility of cotton cellulose in Cl containing carboxyl decreased because of its intermolecular and intramolecular hydrogen bonds.

研究结果表明，含羧基的离子液体会由于分子间氢键的缔合作用降低其对纤维素的溶解性。

In chapter 2,the main research contents and typical works in theoretical research area on amino acids and oligopeptides were introduced.This includes studies performed on structures,electronic properties,weak intramolecular interactions,protonation and deprotonation,conformer conversion,metal ion binding,solution effects and etc.

第2章给出了氨基酸和寡肽分子体系理论计算领域的主要研究内容和研究热点，这包括氨基酸和寡肽分子的稳定结构，电子性质，内部弱相互作用，质子化和去质子化过程，构象转换，金属离子结合及溶液效应等多方面的研究。

In this dissertation, systematic and extensive conformational search has been performed for asparagine and aspartic acid in gas phase and solution and the properties of the stable conformers are studied using DFT based first-principles calculation. The concerned properties include geometry structure, IR spectra, conformer distributions, intramolecular interactions, ionization energies and electron affinities, protonation and deprotonation processes.

在本论文中，我们对天冬酰胺和天冬氨酸在气相和溶液中的稳定构型进行了系统而全面的寻找，并研究了其稳定构型的几何结构、红外光谱、构型分布、分子内相互作用、电离能、电子亲合能、质子化和去质子化过程等相关性质。

We thorough search the stable conformers of aromatic amino acids and arginine and examine the properties of the stable conformers using ab initio and DFT methods. The properties examined include the characteristics of intramolecular interactions, IR and UV spectra, temperature dependent conformer distributions, electron attachment and ionization energies, protonation/deprotonation processes.

木论文对芳香型氨基酸和精氨酸进行了理论研究，研究的性质包括几何结构、电子结构、构刑分布、电离能和电子亲和势、质子化过程、红外谱、紫外谱以及分子内相互作用等方面。

Application of samarium diiodide in mediating intramolecular cyclization reactions was reviewed.

综述了二碘化钐在分子内环化反应中的应用。

Article 144 The Government of the Hong Kong Special Administrative Region shall maintain the policy previously practised in Hong Kong in respect of subventions for non-governmental organizations in fields such as education, medicine and health, culture, art, recreation, sports, social welfare and social

第一百四十四条香港特别行政区政府保持原在香港实行的对教育、医疗卫生、文化、艺术、康乐、体育、社会福利、社会工作等方面的民间团体机构的资助政策。原在香港各资助机构任职的人员均可根据原有制度继续受聘。

Small wonder, then, that the Chinese spend more in the shop than any other group of foreign visitors do .

这样的小惊喜，使中国顾客比任何国家的人消费得更多。