查询词典 intramolecular

Multibranched porphyrin ; two-photon absorption ; two-photon fluorescence ; intramolecular energy transfer

卟啉多枝分子；双光子吸收；双光子荧光；分子内能量转移

These two oxadiazole-based multibranched chromophores show the molecular architecture of "D-A-A'-A-D" for BO-G2 and"D'-A-D-A-D'"for NO-G2, which have the different ability of intramolecular charge transfer .

吸收光谱和荧光光谱证实，NO-G2具有较大的激发态和基态偶极矩差值，存在着明显的分子内电荷转移和非线性吸收。

The enhanced two-photon absorption found in these chromophores was attributed to the fact that the multibranched chromophores had both an extended π-conjugated system and an increased intramolecular cooperative effect compared to the one-branched chromophore.

这些多枝结构化合物的双光子吸收截面较大，双光子吸收增强来源于多枝分子中扩展的π共扼体系和重复单元的协同效应。

The selective quenching by Hg2+ of the fluorescence of compound 1 was rationalized in terms of the formation of a nonfluorescent Hg2+-1 complex with enhanced intramolecular charge transfer compared to compound 1 itself.

基于等摩尔连续变化法、红外光谱和核磁滴定实验结果提出了传感分子1与Hg2+的1∶1型结合模式，其中1-位S原子和2-位胺N原子为Hg2+配位原子；结合光谱变化讨论了Hg2+结合显著增强分子内电荷转移的荧光猝灭机理。

Synchronous fluorescence showed that the addition of POM could enhance the fluorescence intensity of CV, which was explained in terms of the hindrance of the formation of the nonfluorescent twisted intramolecular charge transfer states of CV by the assembled POM-CV system, and the surfactant CTAB could enhance the luminescence by coordinated assembly.

具有同样Keggin结构的4种稀土杂多阴离子与结晶紫的作用总体一致，稀土元素不同体系的光活性会表现出一定的差异。实验证实，阳离子表面活性剂CTAB的存在会进一步增强体系的发光活性。三者协同作用，形成了更稳定的杂多阴离子－CV-CTAB三元超分子体系，而β-CD的存在对稀土杂多酸盐与结晶紫的超分子体系稳定不利。

The mechanisms of intramolecular biaryl nonphenolic coupling were explored by reactions of different 1,4-biaryl substituted butanes with DDQ in TFA.

通过对含不同取代基的芳环化合物、1，4-二芳基丁烷链上含不同取代基化合物与DDQ在TFA中进行非酚氧化偶合和重排反应的研究，对分子内的二芳基非酚氧化偶合反应机理作了深刻的探讨。

The compoud 1 can be converted to intramolecular coupled cyclic olefine (2) as a main product in the presence of iron catalyst.

控制反应条件，在铁催化下可以生成偶联烯烃化的环烯产物(2 )为主要产物；不加催化剂，加热回流反应得到分子内亲核取代反应产物环丙烷化合物 3

Absorption spectra indicate that there is little or no interaction between chromphores in the ground state. However, the fluorescence emission of oxadiazole and triphenylamine moieties are almost quenched, which shows that in the excited ground state there exists very effective intramolecular singlet-singlet energy transfer .

研究发现，这些多发色团化合物在基态发色团之间没有作用或作用很小，而其中噁二唑和三苯基胺单元的荧光被严重的猝灭，这说明在激发态下，萘酰亚胺发色团与噁二唑、三苯胺功能团之间发生了分子内单线态—单线态能量转移。

Herein, a series of compounds, BP-C〓-NBD (n=2, 3, 4, 5, 6, 8, 10), was synthesized. Nanosecond flash photolysis, phosphorescence emission and lifetime, as well as photoisomerization reaction of norbornadiene were used to understand the intramolecular triplet energy transfer in detail.

我们设计、合成了以多亚甲基连接的二苯酮与降冰片二烯（BP-C〓-NBD，n=2，3，4，5，6，8，10）系列化合物，利用纳秒时间分辨技术、低温磷光发射、磷光寿命以及光敏异构化的方法，对其分子内三重态能量传递过程进行了详细地研究。

The intramolecular proton transfers of phenol hydroxyl group to quinonoid carbonyl in Elsinochrome A are very sensitive for the change of molecular structure.

痂囊腔菌素A的酚羟基与醌羰基之间的分子内质子传递对其的结构变化最为敏感。7。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。