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Dimethyl phosphite is an important chemical intermediate, which has widespread availability in chemical industry.

亚磷酸二甲酯是一种重要的化工中间体，有着广泛的应用。

College of Environment and Energy Engineering, Beijing Polytechnic University, Beijing 100022, China ）Abstract The phosphoryl N → O migration reaction and ester exchange reaction on phosphorus of phosphoserine with methyl alcohol involving hexa-coordinate phosphorus intermediate 3 had been studied by MNDO method.

用MNDO方法对磷酰化丝氨酸仿生化反应机理中所形成的六配位磷中间体(3)可能的3个异构体的结构及其反应活性进行了研究。

After thehexa-coordinate phosphorus intermediate formed, the phosphoryl N→Omigration reaction would have the lowest activated energy and should be themain reaction.

六配位磷中间体形成之后，继而发生磷酰基的N→O转位反应的活化能非常低，所以它是主反应。

The phosphoryl N→O migration reaction and ester exchange reaction on phosphorus of phosphoserine with methyl alcohol involving hexa-coordinate phosphorus intermediate 3 had been studied by MNDO method. The three isomers structures of 3 were discussed in detail based on the calculation results.

谭波用MNDO方法对磷酰化丝氨酸仿生化反应机理中所形成的六配位磷中间体(3)可能的3个异构体的结构及其反应活性进行了研究。

Among the six bonds in 3, the P_O bond between the phosphorus and carboxyl oxygen O3 was the weakest one, and could be easily broken to form a new penta-coordinate intermediate 4 which could yield the phosphoryl N→O migration product 5 by breaking the weaker P_N bond.

在六配位磷中间体3的6根键中，丝氨酸的羧基氧O3与磷之间的键最弱，最易断裂生成新的五配位磷中间体4， 4的P_N键断裂得到磷酰基的N→O转位反应产物5。

The three isomers structures of 3 were discussed in detail based on the calculation results. Among the six bonds in 3, the P_O bond between the phosphorus and carboxyl oxygen O3 was the weakest one, and could be easily broken to form a new penta-coordinate intermediate 4 which could yield the phosphoryl N → O migration product 5 by breaking the weaker P_N bond.

在六配位磷中间体3的6根键中，丝氨酸的羧基氧O3与磷之间的键最弱，最易断裂生成新的五配位磷中间体4， 4的P_N键断裂得到磷酰基的N→O转位反应产物5。

In the work, the laser-behavior under exposure of Ar〓 laser was discussed. The kinetic process of photochemical reaction, intermediate, sensitive process of diazophthoquinon system were studied by laser fluorescence spectrum and laser induced fluorescence attenuation. The nonlinear relation between photodecomposition rate of the system and laser power and concentration of solution was investigated in detail.

论文也进行了感光组成物感激光性能的研究：利用激光荧光光谱及激光诱导荧光衰减法实现了实时探测邻叠氮萘醌型光敏剂感激光光化学过程、中间体的产生与结构以及增感作用的研究，该方法在国内外文献中未见有报道。

The lifetime of M intermediate of BRE194Q was less than 1.0 s by photomicrography. The lifetime of M intermediates of BRI119T/T121S/A126T and BRI119T/T121S/A126T/E194Q were 3.0 s and 2.0 s, respectively.

显微视频录像技术记录的PVA膜中样品的M态寿命表明，野生型BR的M态寿命最短，单突变体的M态寿命小于1.0 s，三突变体的寿命为3.0 s，四突变体的寿命为2.0 s。

The lifetime of M intermediate of the three mutants in PVA films were recorded by employing photomicrography. In distilled water, the visible absorption maximum of BRI119T/T121S/A126T and BRI119T/T121S/A126T/E194Q mutants were blue shifted notably by 11 and 12 nm respectively and the BRE194Q's was weakly red shifted in comparison with WT-BR.

与野生型BR相比较，在水溶液中，单突变体的可见吸收光谱的最大吸收峰发生了轻微红移，三突变体和四突变体的最大吸收峰则分别发生了11.0和12.0 nm的明显蓝移。

The lifetime of M intermediate of BR(subscript E194Q) was less than 1.0 s by photomicrography. The lifetime of M intermediates of BR(subscript I119T/T121S/A126T) and BR(subscript I191T/T121S/A126T/E194Q) were 3.0s and 2.0s, respectively.

显微视频录像技术记录的PVA膜中样品的M态寿命表明，野生型BR的M态寿命最短，单突变体的M态寿命小于1.0s，三突变体的寿命为3.0s，四突变体的寿命为2.0s。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。