查询词典 immune reaction

The invention relates to a process for producing polyethylene terephthalate 1, 3-propanediol, which comprises the following steps: using titanic acid ester as major catalyst, using germanium compounds and cobalt compounds as synergic catalyst, conducting esterification reaction for poly terephthalic acid and 1, 3-propanediol according to the molar 1:1.05-2.2 under the nitrogen pressure of 0.1-0.4MPa and 230-265 DEG C, or conducting ester exchanging reaction for poly terephthalic acid and 1, 3-propanediol according to the molar ratio 1:1.8-2.2 in 160-220 DEG C, decompressing reaction to high vacuum 10-150Pa, wherein the final temperature of reaction is 265-275 DEG C, recovering to normal pressure with nitrogen to obtain the PTT product.

本发明涉及一种生产聚对苯二甲酸1，3-丙二醇酯的方法，采用以钛酸酯为主催化剂，锗化合物和钴化合物为协同催化剂，对苯二甲酸二甲酯和1，3-丙二醇按摩尔1∶1.05-2.2，在0.1-0.4MPa氮气压力和230-265℃下进行酯化反应，或对苯二甲酸二甲酯和1，3-丙二醇按摩尔比1∶1.8-2.2，在160-220℃进行酯交换反应，将反应减压至高真空10-150Pa，反应终温在265-275℃，用氮气恢复到常压，得到本PTT产品；大大缩短了反应时间，直接聚合制备特性粘度在0.7-1.05dL/g的PTT切片，使反应产物色相良好，PTT产品可用于纤维加工及工程塑料领域。

Therefore esterification crosslinked reactionbetween polyearboxylic acid and wood can be quantitatively determined.According toexperiment results of stereoscopic configuration choices by crosslinking agents,crosslinkingreaction between model of reaction intermediate and wood,and the intermediate characteristic incrosslinking reaction,crosslinking reaction intermediate was proofed.We can infercrosslinking reactions between polycarboxylicacid and wood want through a mechanism of twosteps reaction process,the first cyclic anhydrides were formed as intermediates by dehydratingbetween hydroxyls in polycarboxylic acids,second esters were occurred by substitution reactionbetween wood hydroxyls and cyclic anhydrides.

从而可全面定量表征木材与多元羧酸类化合物的酯化交联反应；依据交联剂立体构型选择性、反应中间体模型物与木材的交联反应和交联反应中间体的波谱特征实验结果，证实了交联反应中间体，因此可以推测：多元羧酸类化合物与木材化学组分的交联反应是经历两步反应的机理，首先多元羧酸中相邻羧基的羟基之间脱水形成五元环酸酐中间体，然后木材的羟基与酸酐发生亲核取代反应形成酯。

Under the optimal reaction conditions like 140°C of reaction temperature, 2.5 MPa of reaction pressure, 1.5 mg catalyst and 8 h of reaction time, the highest yield of adipic acid and TON were 21.4% and 24 582, respectively.

优选的反应条件是：反应温度为140℃，氧气压力为2.5 MPa，反应时间为8 h，催化剂用量为1.5 mg。在此条件下，己二酸的质量收率可达21.4%，活性转化数可达24 582。

Methods The target compounds were synthesized by Stock enamine reaction,Williamson reaction,Mannich reaction,and arylamine exchange reaction with cyclopentanone as starting material,and their antitumor activities were assayed using human hepatic carcinoma cell line(Bel-7402),human oral cavity epidermis squamocellular carcinoma cell l...

方法以环戊酮为原料，经Stock反应、Williamson反应、Mannich反应和芳胺交换反应合成目标化合物。

It is also confirmed that the reaction of producing pyrrole by reaction of furan with ammonia belongs to bimolecular reaction in which the reactants were competitively absorbed on the surface of catalyst prior to the reaction.

研究还表明，氨和呋喃催化脱水合成吡咯的反应，属于吸附在催化剂表面上的双分子反应，二者在催化剂表面呈竞争吸附，因此两反应物之间应有一个最佳摩尔比。

The latest applications of boronic acids as catalyst to organic synthesis are reviewed, focusing on the catalytic activities and reaction mechanism of different catalysts discovered in condensation reaction, carboxylic acid reduction reaction, and Diels-Alder reaction.

吴记勇 ；方浩*；徐文方摘要：综述了有机硼酸类作为催化剂应用于有机合成反应中的最新研究进展，重点介绍了所发现的各种有机硼酸催化剂在缩合反应、羧酸还原反应、Diels-Alder反应中的催化活性以及反应机理。

We studied the effect of water on the palladium acetate-catalyzed coupling reaction of aryl boronic acid with aryl bromide or acyl chloride in ionic liquid or PEG, and found that water had a remarkable rate accelerating effect on the Suzuki reaction and Suzuki-Type reaction when other reaction conditions were uniform.

研究了水对离子液体或聚乙二醇中Pd2催化的卤代苯或苯甲酰氯与苯硼酸的Suzuki和Suzuki-Type偶联反应收率的影响。

In the bromization reaction of LA,the reaction conditions such as reaction temperature,drop time of Br_2 and reaction medium were optimized.

以来源于生物质资源的乙酰丙酸为原料，通过改进的溴化和水解反应合成了5-HLA。

The effects of solvent on the bromization reaction and oxidant on the formolation reaction of the target product were studied. The results show that the optimum solvent for the bromization reaction and the optimum oxidant for the formolation reaction of the target product were carbon tetrachloride and ceric ammonium nitrate, and their yields were 86.7% and 89.3% respectively.

同时就溴化反应中的溶剂以及甲酰化反应中的氧化剂对两类反应的影响分别进行了研究，结果表明溴化反应的最佳溶剂为四氯化碳，反应产率达到86.7%，甲酰化反应的最佳氧化剂为硝酸铈铵，产率达到89.3%。

The factors affect on the degree of substitution of product, yield and apparent viscosity, such as the mol rates of EPTAC with -NH2, reaction temperature, reaction time and the content of water in system have been discussed in detail. FTIR spectrometer and UV spectrometer are used to characterize the structure of the derivative and it is proved that substitution reaction mainly occurs on the -N element .The particle size and morphology of chitosan and quantemary ammonium salt of chitosan are analysised by comparing photos of their scanning electron microscope. The degree of substitution of HACC is determined by acid -base conductometric titration. An error in current formula of DS has pointed out and a correct formula has presented.On the base of experience of above experiment, the reaction conditions of HACC were systematically investigated through orthogonal design, and then the best conditions are found. Water-solubility and dependence of pH are studied.

壳聚糖和环氧丙基三甲基氯化铵在异相条件下发生反应，通过单因素实验，制备了一系列不同性能的壳聚糖季铵盐，本文首次详细讨论了反应条件(反应摩尔比、反应时间、反应温度、水含量)对产率及产物性能的影响；用红外光谱和核磁共振对结构进行表征分析时，发现季铵盐阳离子基以N位上取代为主；通过电镜图片对壳聚糖和季铵盐衍生物外观形貌进行对比，采用酸碱电导滴定法测定产物的取代度，并对常用取代度公式做了修正。

" I' d like to get some rough idea about music in the baroque ear, please."

请简要介绍一下巴罗克时期的音乐，好吗？

The results showed that the peak latency and pattern of SEPs elicited by electrical needling in LI-l1 and MP were similar. The amplitude of SEPs elicited by electrical needling in LI-l1 was higher than that of MP. There was no obvious SEPs generation when MM was electrical needling.

结果显示，电针刺激曲池穴和其邻近桡侧伸腕长肌运动点诱发性脑电波的波形和波峰时间是类似的，只是穴位的诱发性脑电波波幅较大，而电针刺激非穴位点并没有明显的诱发性脑电位。