查询词典 immiscible

Purposes:With ethanol, ethyl ether, chloroform, benzene, ether and other immiscible oil, and with some solvents can be formed azeotrope.

用途：与乙醇、乙醚、氯仿、苯、石油醚等混溶，并与可其中一些溶剂形成共沸物。

Suitable water-immiscible organic solvents include aromatic hydrocarbons, eg toluene, xylene, naphthalene, tetrahydronaphthalene and methyl naphthalene; chlorinated aromatic hydrocarbons, eg chlorobenzene, fluorobenzene, chloronaphthalene and bromonaphthalene; esters, eg butyl acetate, ethyl acetate, methyl benzoate, ethyl benzoate, benzyl benzoate, butyl benzoate, phenylethyl acetate, butyl lactate, benzyl lactate, diethyleneglycol dipropionate, dimethyl phthalate, diethyl phthalate, dibutyl phthalate, di(2-ethylhexyl) phthalate; alcohols having six or more carbon atoms, eg hexanol, octanol, benzyl alcohol, phenyl ethanol, phenoxy ethanol, phenoxy propanol and phenoxy butanol; ethers having at least 5 carbon atoms, preferably C 5-14 ethers, eg anisole and phenetol; nitrocellulose, cellulose ether, cellulose acetate; low odour petroleum distillates; turpentine; white spirits; naphtha; isopropylbiphenyl; terpene; vegetable oil; mineral oil; essential oil; and natural oil; and mixtures of any two or more thereof.

适用于水互溶的有机溶剂包括芳香族碳氢化合物，如甲苯，二甲苯，萘，四氢萘和甲基萘；氯代芳香族碳氢化合物，如氯苯，氟，氯萘和萘；酯类，如醋酸丁酯，醋酸乙酯，苯甲酸甲酯，苯甲酸乙酯，苄酯，苯甲酸正丁酯，苯，醋酸丁酯乳酸，乳酸苄，二甘醇二丙酸酯，邻苯二甲酸二甲酯，邻苯二甲酸二乙酯，邻苯二甲酸二丁酯，二（2乙基己基）酯；醇有6个或更多碳原子，如己醇，辛醇，苯甲醇，苯乙醇，苯氧基乙醇，丙醇和苯氧基苯氧丁醇；醚至少有5个碳原子，最好荤5-14醚，如苯甲醚和phenetol；硝化棉，纤维素醚，醋酸纤维素，低气味石油蒸馏；松节油；白酒，石脑油isopropylbiphenyl；萜类，植物油，矿物油，挥发油；和天然油，以及任何两个或两个以上其混合物。

T. , the isolated yield reached to 92% and the selectivity was above 99%. The product was immiscible with TSILs and could be separated simply by decantation after the reaction.

由于生成的乙酸苄酯不溶于催化体系，反应产物与催化体系分层，通过简单的倾析便可实现产物分离，简化了分离过程。

The product was immiscible with the catalyst and could be separated simply by decantation after the reaction. As environmental benign catalysts, the TMPSHSO4 could be reused for nine times without noticeable lowering of catalytic activity.

结果表明，[HSO4]具有很高的催化活性，n(C6H8O7)：n(C4H9OH)=1：3.5时在125~130℃下反应3.0h，酯化率达到99%；反应结束后产物与催化体系分层，简化了分离过程；离子液体可以循环使用9次，催化活性无明显变化。

Keywords Al base immiscible alloy;directional solidification;solid/liquid interface;repulsion/engulfment/entrapment;microstructure development

Al基难混溶合金；定向凝固；固/液界面；排斥/吞并/捕获；组织演变

Then, on the basis of above achieved constituent binary results, thermodynamic properties of 10 ternary liquid alioys (Cd-Bi-Pb, Cd-Pb-Sb, Cd-Pb-Sn, Mg-In-Cd, Zn-In- Cd, Cd-Bi-Sn, In-Bi-Pb, Sn-AgPb,Zn-In.Pb, Al-Cu-Zn), 3 quaternary ones (Cd-Bi-Pb-Sn, Zn-Sn-Cd-Bi, Zn-Sn-Cd-Pb) and 1 quinary. one (Zn-Sn-Pb-Cd-Bi) are predicted. For most of investigated multicomponent systems, the calculated activities are in good with the experimental ones, and in particular for multicompoment immiscible ones, the predicted results are satisfactory and exciting. At the same time, the comparison result between the three equations shows that Wilson equation and T-K-Wilson one are more stable than NRTL one, that maybe is because NRTL equation contains a third parameter, and so ,to some degree, Wilson model and T-K-Wilson model are superior to NRTL model. And also the comparison between local composition models and other models such as Pelton- Flengas?method, Krupkowski formalism, mass action concentration model and Hoch- Arpshofen model shows that local composition models are more convenient and credible.

在此基础之上应用局部组成型模型对10个三元液态合金（包括Cd-Bi-Pb、Cd-Pb-Sb、Cd-Pb-Sn、Mg-In-Cd、Zn-In-Cd、Cd-Bi-Sn、In-Bi-Pb、Sn-Ag-Pb、Zn-In-Pb、Al-Cu-Zn），3个四元液态合金（包括Cd-Bi-Pb-Sn、Zn-Sn-Cd-Bi、Zn-Sn-Cd-Pb）和1个五元液态合金（Zn-Sn-Pb-Cd-Bi）的活度进行了预测，预测效果良好，尤其对Zn-In-Pb系和Zn-Sn-Cd-Pb等多元液-液共存体系热力学性质的预测也取得了令人满意的结果；同时对三个方程的比较分析表明：Wilson方程和T-K-Wilson方程在多元系热力学性质的预测中表现稳定，而NRTL方程由于引入了物理意义不清楚的第三参数，使得其具有不确定性和不稳定性的特点，因此Wilson方程和T-K-Wilson方程较NRTL方程更为优越；此外对局部组成型模型与其它模型（如Pelton-Flengas方程、Krupkowski方程、作用浓度模型和Hoch-Arpshofen模型）的比较表明：局部组成型模型同样是优秀的，甚至在某些方面更为简便和可靠。

Positive correlation between Mg~# and P_2O_5 and negative correlation between P_2O_5 and FeO suggest that addition of P is not the key role for the separation of immiscible oxide melts. In contrast, negative correlation between Mg~# and Fe_2O_3/FeO ratios implies that the increasing of oxygen fugacity is very likely the main factor to induce immiscibility of oxide melt.

Mg#与P2O5的正相关以及P2O5与FeO含量的负相关，表明P不是导致氧化物熔体不混熔的主要原因；而Mg#与Fe2O3/FeO的负相关则说明，岩浆演化过程中氧逸度的升高可能是导致氧化物熔体不混熔的主要原因。

In the objective is used two immiscible liquids: one as insulator, another in the role of conductor.

在目的是用了两个混溶的液体：一，作为绝缘体，另一的角色，指挥。

It is practically immiscible with water, has a high boiling point and low vapour pressure.

它特别不溶于水，沸点更高，蒸汽压更低。

The fluids are immiscible and in contact over an interface.

该流体是不混容的并在接触面上接触。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。