查询词典 imino

The process was methanolysis α-imino ether acid hydrogen chloride salt from methyl-cyanide.

研究了以乙腈为原料经α-亚氨基乙醚盐酸盐醇解制备原醋酸二乙酯的工艺方法，对醇解的投料比、反应时间及中和pH值等工艺条件进行了研究，得出较优惠的工艺条件。

It was found that the more easily systhesized and stable N, N-acetal or N, Ohemiacetal can replace N-tosyl imino ester to react with phenols in the presence of TiCl〓, and α-arylglycine derivatives were also obtained in high yields and high regioselectivity.

进一步研究发现，更易合成的N，N-或N，O-缩醛可以作为亚胺酯的替代物和酚类化合物发生傅克反应。路易酸TiCl〓能有效地促进酚类化合物和亚胺酯的傅克反应较高产率、较高区域选择性的得到2-羟基α-芳香甘氨酸衍生物。

After extraction by ethanol and purification by cationic ion-exchange column, a method of using reversed-phase high-performance liquid chromatography and precolumn derivatization with o-phthalaldehyde and 9-fiuorenylmethylchloroformate is employed for determination of free amino acids in tobacco . This method assures that amino acids with amino and imino groups can be determined simultaneously. The results of duplication experiment and recovery experiment are acceptable.

本试验用乙醇提取烟叶中的游离氨基酸，并用阳离子交换树脂纯化，再用邻苯二甲醛、氯甲酸芴甲酯联合柱前衍生、反相高效液相色谱分析测定了烟叶中的游离氨基酸，该方法能同时测定烟叶中的带氨基和亚氨基基团的氨基酸，并且分析方法的重现性和回收率均令人满意。

The molecules involving azo and imino functional groups can coordinate with Hg2＋ to result in a large blue shift from 453 to 363 nm corresponding to a notable color change from orange to pale yellow in aqueous methanol solution (H2O/CH3OH＝1/4, V/V), which can be applied to naked eye detection of Hg2＋.

这些传感器分子包含偶氮和亚胺功能基团，在水/甲醇溶液（体积比1/4）中，可以与汞离子配位，使紫外-可见光谱中吸收峰发生由453到363 nm的蓝移，引起一个明显的溶液由橙色到淡黄的颜色变化。因而，这些传感器有肉眼检测汞离子的潜在应用。

In the forth part, in the presence of chiral phosphoric acid, highly enantio-enriched (up to 98% ee)α-aryl glycine derivatives could be synthesized via asymmetric transfer hydrogenation of the α-aryl imino esters using Hantzsch ester as the hydrogen source.

第四部分工作中，利用Hantzsch酯作为氢源，高对映选择性地实现了手性磷酸催化芳基酮酸酯亚胺的不对称仿生氢化反应，以最高98％的对映选择性得到苯甘氨酸衍生物。

A type of novel dis-substituted α-arylglycine derivatives was synthesized in high yields and high regioselectivity via the stepwise Friedel-Crafts reaction of phenols with N-tosyl imino ester promoted by TiCl〓.

发现在Mg／MeOH／超声波条件下，能高产率的得到N-Tos裂解后N-Boc保护的α-芳香甘氨酸衍生物，实现了一条简单、实用的合成N-Boc保护的α-芳香甘氨酸衍生物的方法。

If we used potentiostatic electrosynthesis method, a kind of black polymer film was found on cathodic surface when 〓 was more negative than-1. 40V . XPS analysis demonstrated that the film formed from excited pyruvic acid, tetrahedral intermediate and imino acid.

时，电极表面上吸附的丙酮酸，四面体中间体和亚胺酸受激而生成黑色的聚合膜，通过XPS技术对聚合物进行了定性、定量和结构分析。

In addition, ioding was found to be an efficient catalyst for the imino Diels-Alder reaction of N-arylimine and enol ethers and the reaction provided tertrahydroqinolines in good yields. One pot synthesis of tetrahydroqinolines from aldehyde, aniline and enol ethers was also achieved using iodine as the catalyst. The chemical yield of the"one pot"reaction was comparable with that obtained using preformed N-arylimine.

此外我们也发现碘能够有效地催化N-芳基亚胺与烯醇醚的Diels-Alder反应，以很高的化学收率得到了四氢喹啉衍生物，并且发现碘也能够直接催化芳香醛、苯胺、烯醇醚的三组分&一锅&反应，获得的化学产率与使用预制的N-芳基亚胺相当。

Aniline-BP was used as CTC system to initiate the polymerization ofMMA under UV irradiation, PMMA prepolymer with aromatic imino endgroup was prepared.

以苯胺-BP为CTC体系，在紫外光辐射下，引发甲基丙烯酸甲酯聚合，得到了含有芳亚胺端基的聚甲基丙烯酸甲酯预聚物。

Upon mild oxidation of Ⅸwith iodine in potassium iodide, a disulfide, which was characterized as 3,3'-dithiobis [2-(l-hydroxyethylidene)-3-imino propionitrile], was formed.

将IX用碘/碘化钾温和地氧化得到二硫化物（XIV，即3，3'-二硫-双2-（1-羟乙叉基）-3-亚胺基丙腈。

But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊！不用提了。提到肉，真是糟透了。