查询词典 hydroxylation reaction

The material exhibited a good catalytic activity in the reaction of benzene hydroxylation.

所合成的材料在苯的羟基化反应中表现出良好的催化活性。

Influence of individual reaction parameters on MF catalytic hydroxylation of PHP is studied to find out preferable reaction conditions.

研究了各种反应条件对铁酸镁MgFe〓O〓尖晶石类催化剂催化苯酚过氧化氢羟化反应的影响，找到了较好的反应工艺条件。

The catalytic activity was characterized by the reaction of hydroxylation of phenol.

并用苯酚羟基化合成苯二酚作为探针反应，考察了TS-1膜的催化活性。

In this dissertation, we studied the catalysts, reaction conditions and mechanism of one-step hydroxylation of benzene to phenol oxidized by molecular oxygen, which is the cleanest and the most economical process.

所以近年来作为一条比较经济的路线，以苯为原料经过一步氧化，直接羟基化生产苯酚的反应吸引了各国研究者的广泛关注，这也是催化化学中最为艰难、最具有挑战性的研究课题之一。

The oxides with spinel and peroskite structure are the key active components for phenol hydroxylation, and higher contents of them have the higher reaction activity.

形成的尖晶石或钙钛矿结构为苯酚羟基化反应的活性相，具有良好晶态的复合氧化物催化剂的反应活性较高。

The AM1 method was used for a quantum chemistry study of the phenol hydroxylation reaction mechanism. The possible reaction path of the phenol and oxyhydrogen free radical was optimized, and the structures of stable intermediates in the reaction mechanism were also obtained.

本文还首次采用AM1方法对苯酚羟基化反应机理进行了量子化学研究，将苯酚与氢氧自由基的反应沿可能的反应路径进行几何优化，得到反应历程上相关驻点稳定构型的三维结构。

Catalysts in three synthesis routes,the hydroxylation of 4-tert-butyl-phenol,the alkylation of pyrocatechol by tert-butyl alcohol and the alkylation of pyrocatechol by isobutene,were discussed in detail in terms of reaction conditions,catalysts,temperature,reaction time etc.

论述了对叔丁基苯酚羟基化法、邻苯二酚与叔丁醇烷基化法和邻苯二酚与异丁烯烷基化法生产对叔丁基邻苯二酚的合成路线的催化剂。

The experiments also show that adding NaHSO3 into the reaction liquid of hydroxylation reaction can inhibit the catalytic effect of benzoquinone and residual catalyst on the phenolic tars formation caused by oxo-condensation of the diphenols and therefore reduce the tars formation of the diphenols in the reaction solution.

在羟基化反应液中加入亚硫酸氢钠可以抑制对苯醌和残留催化剂对苯二酚氧化缩合生成焦油的催化作用，从而减少了反应液中苯二酚的生焦反应。

The reaction mechanism for the formation of ultimate carcinogens diazohydroxide, diazonium and oxoniumions by α-hydroxylation-NPYR and the alkylation process of C and guanine were investigated including solvent effects at the B3LYP/6-31G(superscript **) level.

采用密度泛函理论，在B3LYP/6-31G水平上，研究了气相和水溶剂中，α-羟基化吡咯烷亚硝胺(-αhydroxylation-NPYR， A)代谢为终致癌物重氮氢氧化物、重氮烷阳离子和氧离子，以及C与鸟嘌呤碱基相互作用的反应机理。

In the hydroxylation of phenol with H〓O〓 in the presence of Ti-ZSM-5, water is best solvent. It produces catechol and hydroquinone simultaneously, and catechol/hydroquinone ratio is approximately 0.85. The results show H〓O〓 utilization ratio increase 14%, when nonoxidizable weak acid HAc is added into the reaction system. Under the conditions of Ti-ZSM-5 as catalyst, phenol/H〓O〓 ratio being 10, a little HAc, temperature 75℃, reaction time 6h, H〓O〓 utilization ratio reaches 74. 6mo1% in the reaction.

对Ti-ZSM-5催化苯酚羟基化的研究结果表明，水是最好的溶剂，羟基化有邻、对苯二酚两种产物，并且邻苯二酚/对苯二酚摩尔比可维持在～0.85左右；向反应体系中加入非氧化性弱酸性助剂HAc时，H〓O〓有效利用率较未加入助剂时可提高14mol%；当催化剂用量为8g/100g苯酚、苯酚/H〓O〓比为10、反应温度75℃、添加少量HAc的条件下，反应6h后，H〓O〓有效利用率可达74.6mol%。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。