查询词典 hydroxy-ketone

In our study, the synthesis of spice and the resolution of racemates menthol,(R, 5-4-hydroxy-3-methyl-2-(2-propenyl)-2-cyclopenten-1-one (R, S-HMPC were achieved in ionic liquids by three lipase that are usually used in biocatalysis. Meanwhile, some problems associated with enzyme catalysis in ionic liquids were also addressed.

本论文以三种常用于生物催化的脂肪酶作催化用酶，在&绿色&反应介质—离子液体中实现了香料的合成和手性对映体的拆分，同时也对酶在离子液体中催化所存在的问题进行了一些探讨。

Direct enantiomeric separation of racemic mixtures of 13 β-amino alcohols and β-hydroxy sulfides was achieved by HPLC using Chiralcel OD, Chiralcel OJ and Chiralpak AD as chiral stationary phases and hexane/2-propanol mixture as eluent. These racemates were completely separated into enantiomers at least on one of these stationary phases.

在以正己烷-异丙醇为移动相的体系中，用ChiralcelOD，ChiralcelOJ及ChiralpakAD作为手性固定相对13种β-氨基醇及β-羟基硫醚类化合物对映体进行HPLC手性拆分，这些化合物至少能在一支柱上得到基线级分离。

Treatment of pterin (2-amino-4-hydroxy-pteridine) derivatives with N,N-dimethylformamide dimethylacetal [1,(CH 3) 2NCH(OCH 3) 2] usually gave corresponding N 2-(N,N-dimethylaminomethylene)- pterin derivatives in polar solvents.

用N ，N 二甲基甲酰胺缩二甲醇 [(CH3 ) 2 NCH(OCH3 ) 2 ，1]和蝶呤(2 氨基 4 羟基蝶啶)衍生物在极性有机溶剂中反应一般得到脒化产物：N2 (N ，N 二甲基氨基亚甲基)-蝶呤衍生物。

Using free radical 4-hydroxy-2,2,6,6-tetramethyl-1-piperidinyloxyl as catalyst, the phase transfer catalyzed method of oxidation of anilines to 15 symmetrical azobenzenes with a saturated solution of potassium ferricyanide in 2N aqueous potassium hydroxide and dichloromethane was described for the first time.

用2，2，6，6-四甲基-4-羟基-1-哌啶氮氧自由基为催化剂，芳胺类化合物在饱和铁氰化钾的氢氧化钾溶液和二氯甲烷的两相转移催化下合成了15 个对称取代偶氮苯。

The structures were identified by IR, UV,〓 NMR and element analyses. 2. Free radical 4-hydroxy-2,2,6,6-tetramethyl-1-piperidinyloxyl as catalyst, the phase transfer catalyzed method of oxidation eighteen semicarbazides to N-Aryl-2-Phenyl diazenecarboxamide with a solution of potassium ferricyanide in 2N aqueous sodium hydroxide and dichloromethane is described for the first time.

利用2，2，6，6-四甲基-4-羟基-1-哌啶氮氧自由基为相转移催化剂，在饱和铁氰化钾的2N氢氧化钠溶液与二氯甲烷的两相反应液中，催化氧化十八个取代氨基脲得到十八个相应的新型偶氮化合物N，2-二芳基二氮亚烯甲酰胺，均获得了较高的产率。

An intramolecular α-addition of hydroxy or amine-substituted electron-deficient alkyns catalyzed by phosphines was developed.

主要工作是利用我们小组发现的全碳1，3-偶极子在合成螺环化合物方面做了比较细致和深入的研究。

An intramolecular α-addition of hydroxy or amine-substituted electron-deficient alkyns catalyzed by phosphines was developed. An intramolecular β-addition of hydroxysubstituted 2-alkynoates trigged by the tributylphosphine was also achieved.

在上面的研究中发现低活性的亚甲基取代的环内酰胺的[3+2]环加成反应也能顺利进行，因此我们研究并实现了β-位取代的贫电子烯烃的环加成反应，进一步拓展了叔膦催化的[3+2]环加成反应。

Three activated carbons having different surface areas, coconut-shell based, pelletized and bamboo-derived, were modified by mixing them with four thermoplastic precursors, poly, hydroxy propyl cellulose, citric acid, and fluorine-containing polyimide followed by heat treatment at 900℃ for 1h.

三种具有不同比表面积的活性炭—椰壳基AC-C、粒状AC-P和竹基AC-B分别与四种热塑性前驱体—聚乙烯醇，羟基丙基纤维素，柠檬酸，含氟聚酰亚氨混合后，在900℃热处理1h。

Finally, we demonstrate the transformation of β-hydroxy nitriles to a variety of diastereomerically pure and highly functionalized acyclic and heterocyclic γ-amino alcohol derivatives.

最后， 本文介绍了由β-羟基腈向各种纯非对映异构体，多功能性的开环和杂环γ-氨基醇衍生物的转化反应。

And the Honeysuckle's leaves extracts have hydroxy free radical scavenging effects as well. The re-extract by ethyl acetate has obviously scavenging activity when its concentration is 1 mg/mL.

抗氧化实验结果表明，金银花叶乙醇提取物具有一定的抗羟自由基氧化活性，其中乙酸乙酯萃取物在1mg/mL的低浓度下就显示出了较好的效果。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。