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In this paper, the current states of research about the basic theory of stationary state perturbation method are firstly reviewed, on base of them, and studied some physics issues mainly about hydrogen atom. The stark effect of the energy level (n = 4) of hydrogen atom is calculated and the stark effect of three dimensional hydrogen atom is discussed by the use of the parabolic coordinates, then the perturbative matrix elements for each energy level are given.

本文首先综述了关于定态微扰论基本理论的研究现状,在此基础上利用定态微扰论对某些物理问题,主要是对氢原子问题展开了研究,计算了氢原子n=4能级的斯塔克效应,并利用抛物线坐标法求解了三维氢原子的斯塔克效应,给出了氢原子斯塔克效应中微扰矩阵元的普遍公式。

To investigate the mechanisms of biohydrogen production by anerobic fermentation of solid organic waste, gas chromatography is used to analysis the biogas and volatile fatty acid in anaerobic bio-reactor. Firstly, the ability of hydrogen production by digested sludge from the West Lake, Enteobacter aerogences, digested sludge from sewage farm, the fluid of methane pool and dejecta have been studied. The rule of the ability of hydrogen production by different bacteria under different control condition. Simultaneity, the importance of the synergistic effect on hydrogen production has been proved.

本文首先选用西湖底的厌氧活性污泥、产气肠杆菌、污水处理厂的淤泥、沼气池发酵液以及猪粪等不同菌群对废弃食物——马铃薯进行厌氧发酵产氢特性实验研究,得到马铃薯在各不同菌群及工况下的发酵产氢能力,同时发现产氢菌间的协同作用很重要,在控制好发酵条件的情况下,产氢菌群发酵通常会好于单一产氢菌的发酵。

Anaerobic synecology of the hydrogen-producing fermentation system was investigated under certain test condition in this thesis. In the continuous flow system of anaerobic hydrogen-producing fermentation, the succession of hydrogen-producing acidogenic microbiology may be regressive process. By regressive process we means that the original community getting from nature which structure being complex with a high ability would degenerate gently to a certain climax community which structure being simple with less ability.

产氢发酵系统的微生物群落生态学研究证明,在连续流发酵产氢反应系统中产氢产酸发酵细菌群落的演替过程,是在人为控制的生境条件下,微生物从自然群落这种稳定性大、组成及生化反应过程复杂的生态群落,向稳定性小、组成和生化反应过程相对简单的某一产酸发酵顶极群落进行的"逆行演替"。

Palygorskite was a kind of mineral hydrogen storage material with strong adsorption capacity and structural nanochannels. If we could decorate hydrogen storage metal Pd to the surface of the Pal, this compared to the undecorated Pd to the Pal, the hydrogen storage content would maybe increase.

坡缕石矿物(Palygorskite,Pal)是一种具有一定氢吸附能力的具有纳米结构孔道的矿物储氢材料,如将储氢金属钯修饰在坡缕石表面,与未经钯修饰的坡缕石相比,其储氢量有望得到进一步提高。

The content Of isoalkanes decreased when NiSO_4 was loaded, for supported Ni oxidecould promote the dehydrogenation of the precursors of aromatics by unimolecular reactionwhich did not generate negative hydrogen ions, and the carbonium ions could not obtainsufficient negative hydrogen ions to promote hydrogen transfer reaction.

负载氧化镍以后异构烷烃含量下降,氧化镍可以通过脱氢促进芳构化反应,使正碳离子得不到足够的负氢离子饱和使氢转移反应得到抑制。

The results show that a little amount of heteropolymolybdovanadophosphate can remarkably speed the degradation, the best conditions of the oxidative degradation of chitosan with hydrogen peroxide catalized by heteropolymolybdovanadophosphate in homogeneous condition are as follows: the ratio of catalyst and chitosan is 1 to 10, concentration of hydrogen peroxide is 0.15%, the temperature is 80℃, reaction time is 2h. 0.2g chitosan was degraded under the best condition and the molecular weight by viscometry was degraded from 1460000 to 7812. then water-soluble chitosan was obtained by this method; The heterogeneous method is a high efficient way, the best condition of this method are as follows: the ratio of catalyst and chitosan is 2 to 100, the volume of 30% hydrogen peroxide is about 3mL, the temperature is 90℃, reaction time is 5min~30min.

研究结果表明,适量磷钼钒的存在可显著加速壳聚糖的降解,磷钼钒催化过氧化氢均相氧化降解壳聚糖的适宜反应条件是:催化剂与壳聚糖的质量比为1∶10、过氧化氢百分浓度为0.15%、反应温度为80℃、反应时间为2h,在此条件下对0.2g溶解在100 mL 0.5%稀醋酸中的壳聚糖进行降解,可使壳聚糖的粘均分子量由原来的146万下降到七千多(7812),成为水溶性低分子量壳聚糖,从而达到应用的要求;在异相条件下以磷钼钒为催化剂催化过氧化氢氧化降解壳聚糖是一种高效快速的方法,此法降解壳聚糖的最佳反应条件是:催化剂与壳聚糖的质量比为2∶100;30%过氧化氢的用量为3mL左右;反应温度为90℃、反应时间为5min~30min。

Result indicated the increase of destroyed zoogloea and enhancement of activities of enzymes of nitrogen-fixing, de-hydrogen as well as α-amylase, leading to a decrease of period of hydrogen-producing and an increase of rate of hydrogen-producing.

与对照组相比,可溶解性化学需氧量增加了4.5倍,溶出率提高了350.00%;COD降解率提高了12%,是自然降解率的1.19倍,产氢周期缩短至6.5d,最大产氢率为67.91mL/g,平均产氢率提高到21.6mL/g,是对照组的3.9倍,效果较好。

Enterobacter aerogenes was irradiated by He-Ne laser to optimize the laser mutagenesis condition, and to test the heredity, aciduric and hydrogen-producing potential of the mutant. An aciduric mutant with steady hydrogen-producing capability, which was able to grow at acidic pH of 3.0, was obtained. Its capability of hydrogen production was measured in the batch culture experiment.

闻建平,陈宇,刘铭辉(天津大学化工学院生物工程系,天津300072)摘要:运用He—Ne激光辐照产气肠杆菌,对激光诱变参数进行优化,考察了突变株的遗传稳定性、耐酸性和产氢特性结果筛选到一株遗传性状稳定的高产氢突变株,具有良好的耐酸性,在pH值3.0 时仍能生长。

The adsorptions of SiH_2, SiH_2 with a hydrogen adatom (SiH_2+H) and SiH_2 with two hydrogen adatoms (SiH_2+2H) on the Si (100) surface near SDV structure have been calculated. Three possible sites are found in each case, and the presenting of hydrogen may reverse the relative stability of these sites.

本文首先计算分析了SiH_2、SiH_2+H和SiH_2+2H等硅烷分解后的产物在硅表面的吸附特性,我们发现每种情况都有三个可能吸附的位置,并且表面附着氢原子的出现可以造成这些吸附位置相对稳定性的逆转。

The Mo center of [Mo8](superscript 4)-shows a slight distorted square antiprism coordination environment. The N atoms of cyano groups, acting as acceptors of hydrogen bonds, together with protonate N atoms from organocations and the lattice water, serving as donors of hydrogen bonds, form intricate hydrogen bond interactions, thus generating three-dimensional supramolecular network with the help of π-π interactions of some organocations.

Mo8(上标 4-)离子中,Mo中心处于扭曲的反四棱柱配位环境。8个未配位的氰基氮原子作为氢键的受体,有机阳离子上质子化的氮原子和结晶水作为氢键的给体,形成了丰富的氢键作用,这些氢键作用连同部分有机阳离子间的π-π堆积、阴阳离子间的静电力和Van Der Waals力构筑成三维超分子网络。

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