查询词典 hillman

B3LYP/6-311++G** calculations were carried out to study the trimethylamine catalyzed Baylis-Hillman reaction between acraldehyde and formaldehyde.

采用密度泛函DFT-B3LYP方法在6-311++G**基组下计算研究了三甲胺催化的丙烯醛和甲醛的Baylis-Hillman反应的微观过程，获得了两种反应通道(分别对应于顺式-丙烯醛和反式-丙烯醛)的势能面。

The optimized structures and energies of the reactants, intermediates, transition states and products of two reaction channels (corresponding to syn-acraldehyde and anti-acraldehyde) in gas or in methanol solvent were obtained. The potential energy profiles reveal the processes of the trimethylamine-catalyzed Baylis-Hillman reaction between acraldehyde and formaldehyde in gas or in methanol solvent at the microscope level.

通过研究，获得了三种情况下两种反应通道(分别对应于顺式-和反式-丙烯醛)中涉及的反应物、产物、中间体、过渡态的优化结构及其能量，并由此得到了反应的势能面图，在电子微观层次上揭示了三甲胺催化的丙烯醛和甲醛的Baylis-Hillman反应的微观过程。

Chapter three focuses on the application of the Baylis-Hillman adduct in organic synthesis and some new exploration was made.

第一章对钐试剂促进的有机反应和Baylis-Hillman反应在有机合成中的应用作了简要介绍；第二章研究了二碘化钐促进的还原消除反应；第三章研究了Baylis-Hillman加成物参与的立体选择性的转化反应。

The Yankees were interested in speaking to Trey Hillman, but by the time they had a vacancy, he had agreed to terms with the Royals.

球团本来也将Trey Hillman纳入考量，但慢了一步---他已经同意接任皇家队的总教练了。

Charles Hillman, associate professor of kinesiology at the University of Illinois, was able to duplicate these findings with 259 third and fifth-grade Illinois students.

伊力诺依大学运动机能学副教授Charles Hillman对该州259名3、4年级的学生进行的调查中，也印证了上述结果。

Three generic political strategies (information, financial incentive and constituency building) proposed by Hillman and Hitt are believed to be effective strategies among foreign firms.

Hillman和Hitt提出的"提供信息、财务激励和提供支持"三类政治战略，都被外企认为是有效的政治战略方式。

In chapter three,we investigated a new Baylis-Hillman-type reaction,organozinc speciesCF_3COOZnEt can react withα,β-acetylenic ketones and N-tosylated imines providing Baylis-Hillman adducts in good yield in the absence of any catalysts.

有机锌试剂CF_3COOZnEt可以与各种类型的α，β-炔酮及亚胺发生偶联反应，高产率的得到β-取代的Morita-Baylis-Hillman反应加合物，这类反应不需要任何的催化剂，产物具有立体单一型，完全是Z式结构。

The normally brominated Baylis-Hillman adducts were formed as the major product at low temperature. While at room temperature or heating, the α,γand β,β-dibrominated compounds were formed as the major products using 3-butyn-2-one and methyl propiolate or propynenitrile as substrate, respectively.

贫电子炔类化合物的Baylis-Hillman反应的研究在这部分工作中我们发现在用TiBr〓或BBr〓为Lewis酸催化贫电子炔类化合物和芳香醛的Baylis-Hillman反应时，温度对反应的影响很大：当反应在低温下进行时，通常生成的是正常的β-溴代的Baylis-Hillman反应产物；而在室温或加热条件下反应，以丁炔酮为底物时，主要生成的是α，γ-二溴化合物，而以丙炔酸甲酯及丙炔腈为底物时，主要生成的是β，β-二溴化合物。

However, using tributylphosphine as a Lewis base and -1, 1'-bi-2-naphthol as a cocatalyst, the Baylis-Hillman reaction of arylaldehydes with cyclopent-1-en-one proceeded smoothly.

在本论文主要对磺酰亚胺和各种活化烯的aza-Baylis-Hillman反应以及它们的不对称aza-Baylis-Hillman反应进行了研究。

After the failure of achieving good enatioselectivity in asymmetric Baylis-Hillman reaction, we turned our attention to traditional chiral Lewis base catalyzed asymmetric Baylis-Hillman reaction.

我们还发现，用咪唑与-脯氨酸共催化醛和丁烯酮的Baylis-Hillman反应，但产物的e.e值还是很低，因此又回到了传统的用手性Lewis碱催化不对称Baylis-Hillman反应研究中。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。