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New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene PolymerizationFacile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that:1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下:(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2,3-双(2,6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2,6-二[1-(2,4,6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上,研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响,研究表明:1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理,可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体;2、BET,XRD,IR,SEM,GPC和DSC研究表明,脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene Polymerization Facile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that: 1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下:(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2,3-双(2,6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2,6-二[1-(2,4,6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上,研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响,研究表明: 1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理,可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体; 2、BET,XRD,IR,SEM,GPC和DSC研究表明,脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

Computer carving molds categories: High Frequency copper mold, bronzing die, metal plastic mould, metal stamping die English letters, metal crafts sculpture, greeting cards embossed die, plastic gift-chapter, line unleaded Wave Soldering version of the rule of the furnace, three-dimensional relief Three-dimensional sculpture, and other computer processing…… stickers printed categories: all kinds of stickers printed labels, stickers, bar code standard, easy shredding, arrow superscript, clothing footwear subscript cloth, water standard, such as India Mark…… Rubber signs categories: Crystal Dijiao, micro-injection, drops of plastic, such as Chapter…… silicone raw materials series categories: Japan KE-1310ST, KE-1310S, JX-860, JX-850 and its color paste, auxiliary agents and dedicated Tools such as…… PVC raw materials Series: highly transparent material, PVC powder paste, DINP oil, light and heat stabilizers, hardware oil, PVC color paste…… hot-ink series: low-temperature heat-Ink (round, rectangular, smooth, Dumb noodles) and color color paste, and so on…… flocking Series: Flocking paper, flocking oar, flocking Transfer…… machines, and other series: automatic multi-color flocking machine, planting colorful three-dimensional plastic machine, silicone molding package Machines, high-frequency embossing machine, plastic plate pipeline equipment…---- since we have since opened in accordance with the philosophy, in order to meet customer needs and quality to achieve customer satisfaction.

电脑雕刻模具类:高周波铜模、烫金模、五金塑料模、五金冲压英文字母模、金属工艺品雕刻、贺卡压花模、礼品胶章模、线路版过波峰焊无铅过炉治具、立体浮雕等各种三维电脑雕刻加工……不干胶印刷类:印刷各种不干胶标签、贴纸、条码标、易碎纸、箭头标、服装鞋帽布标、水标、印唛等……橡塑标牌类:水晶滴胶,微量射出,滴塑胶章等……矽利康原料系列类:日本KE-1310ST、KE-1310S、JX-860、JX-850及其色浆、辅助剂和专用工具等……PVC原料系列:高度透明料、PVC糊脂粉、DINP油、光热稳定剂、硬油、PVC色浆……热固油墨系列:低温热固油墨(圆角、直角、光面、哑面)和彩色色浆等……植绒系列:植绒纸、植绒桨、植绒转印纸等……机器系列:自动多色植绒机、立体多彩植胶机、矽利康整套成型机、高频压花机、橡塑标牌流水线设备等…----自开张以来我们都依照经营理念,为了配合客户的需求以及在质量上能达到客户的满意。

Computer carving molds categories: high frequency mode, bronzing die, metal plastic mould, metal stamping letters die, metal crafts sculpture, greeting cards embossed die, plastic gift-chapter, line version of a wave soldering lead-free governance with a furnace, such as three-dimensional relief Three-dimensional sculpture of computer processing… stickers printed categories: all kinds of stickers printed labels, stickers, bar code standard, easy shredding, arrow superscript, subscript cloth clothing shoes and hats, water standard, such as India Mark… Rubber Tag Categories: Crystal Dijiao, micro-injection, drops Chapter plastic raw materials, etc… silicone series categories: Japan KE-1310ST, KE-1310S, JX-860, JX-850 and its color paste, auxiliary agents and special tools… PVC raw materials Series: highly transparent material, PVC powder paste, DINP oil, light and heat stabilizers, hardware oil, PVC heat-ink color paste… Series: low-temperature heat-ink (round, rectangular, smooth, dumb noodles) and color color paste , Etc… flocking Series: Flocking paper, flocking oar, flocking Transfer, etc… machines Series: automatic multi-color flocking machine, planting colorful three-dimensional plastic machine, silicone package molding machines, high-frequency embossing machine, rubber Plastic signs pipeline equipment…---- since we have since opened in accordance with the philosophy, in order to meet customer needs and quality to achieve customer satisfaction.

电脑雕刻模具类:高周波模、烫金模、五金塑料模、五金冲压字母模、金属工艺品雕刻、贺卡压花模、礼品胶章模、线路版过波峰焊无铅过炉治具、立体浮雕等各种三维电脑雕刻加工…不干胶印刷类:印刷各种不干胶标签、贴纸、条码标、易碎纸、箭头标、服装鞋帽布标、水标、印唛等…橡塑标牌类:水晶滴胶,微量射出,滴塑胶章等…矽利康原料系列类:日本KE-1310ST、KE-1310S、JX-860、JX-850及其色浆、辅助剂和专用工具等…PVC原料系列:高度透明料、PVC糊脂粉、DINP油、光热稳定剂、硬油、PVC色浆…热固油墨系列:低温热固油墨(圆角、直角、光面、哑面)和彩色色浆等…植绒系列:植绒纸、植绒桨、植绒转印纸等…机器系列:自动多色植绒机、立体多彩植胶机、矽利康整套成型机、高频压花机、橡塑标牌流水线设备等

The macrocyclic polyamines are a kind of excellent ligands and have a substantially high binding affinity with transition metal ions. Macrocyclic polyamine metal complexes as enzyme models are widely used in chemical biology, medicine and gene therapy. 1, 4, 7, 10-tetrazacyclododecane is a representative macrocyclic polyamines compound and shows high binding affinity with transition metal ions, such as Zn, Cu and Co. Their metal complexes especially multinuclear complexes were widely used in DNA, RNA recognition.

大环多胺化合物是一类性质独特的优秀配体,具有良好的金属配位能力,其金属配合物作为人工酶模型广泛应用于核酸结构及功能研究、基因表达与调控、抗癌药物的研制等生物、化学和医学领域。1,4,7,10-四氮杂十二烷是典型的大环多胺化合物,对过渡金属离子Zn, Cu and Co有良好的配位能力,这些金属配合物特别是多核金属配合物被广泛应用于DNA识别中。

For the first time we synthesized nanoscale metal hydrides of lanthanum, neodymium, samarium, dysprosium, and ytterbium with high efficiency under mild condition by complexometric catalysis instead of traditional preparation at high temperature and high pressure. It is for the first time that we synthesized lanthanide organic compounds with catalysts or initiating agents at atmosphere and ambient temperature,and some of them are new compounds. Nanometric lanthanide metal powders are prepared by thermal decomposition of the compounds in vacuum. Differently from the traditional method, size of the products prepared by our method is less than 40nm, and the activity of the reaction is very high. They are pyrophoric at atmosphere. They can make some reactions without activity or low activity show extremely high activity .We investigated influent regulations of methods, conditions to scale and special surface.

我们首次成功地用络合催化等方法取代需在高温高压下进行的传统方法,在温和条件下高效率地合成出纳米尺寸镧、钕、钐、镝、镱的金属氢化物;首次在常压常温的条件下,通过催化、引发等方法合成镧系金属有机化合物,再将其真空热分解成功地制备了纳米尺寸的镧、钕、钐、镝、镱等金属粉末;与传统方法不同,这些方法得到的产品基本颗粒尺寸小于 40 nm,遇到空气燃烧,具有极高的化学反应活性,使原来活性很低甚至观察不到活性的反应大幅度提高反应速率和产率;考察了制备方法、制备条件等因素对晶粒尺寸、比表面积大小等的影响规律。

This welding wire not only has the inherent properties of metal powder-cored wire, such as with better welding quality, without slag, highly efficiency and conveniently adjusting the alloying elements etc., but also has the advantage of low hardness in as-welded (less than HRC45), good machinability, high hardness in as-aged (more than HRC55) and better wear resistance with customary working procedure on making or repairing equipments such as rollers when reasonable designing the alloys content. The author adequately makes use of the high-tempering in the required stress relieving working procedure. During this working procedure, which causes the hardness of overlaying metal increased by the reason of austenite changes into tempered martensite and more chiefly what is the precipitation of a lot of carbide by secondary hardening simultaneously. This wire can solve the hard rolled problems of some solid wires with higher alloys while it can get over the conflict of existing overlaying materials what are always possesed high hardness with poor machinability or low hardness, good machinability with poor wear resistance. Further, it also can overcome the intenerating phenomena between welding beads and make the external hardness of overlaying metal uniform. Be sure it could be found important meaning in the overlaying of wear-resistant equipments, such as the precise roller.

该焊丝除了具有金属粉型药芯焊丝焊接质量好、无渣、高效率和合金成分可方便调节等固有的优点外,合理的设计粉芯中的合金成分,按通常工序制造与修复轧辊等设备,充分利用必需的消除应力工序的高温回火,堆焊层金属在奥氏体转变为回火马氏体的同时更主要是通过二次硬化析出了大量碳化物导致硬度增加,使得该焊丝还具有焊态硬度低(小于HRC45)、机加工性能好和时效态硬度高(大于HRC55)、耐磨性能好等优点,解决了某些高合金实芯焊丝轧制困难的问题,同时克服了现行堆焊材料硬度高、加工性能差或者硬度低、加工性能好、耐磨性差的矛盾,并能克服焊道之间的软化现象,使堆焊表面硬度较为均匀,对耐磨件,譬如精轧辊的堆焊具有重要意义。

Common transparent quartz tube SiO2 more than 99.9% purity, geometry, chemical stability, thermal stability, resistance to thermal denaturation and anti-crystallization properties of the fine, optical transmittance above 93%; from hydroxyl in hydroxyl tube below 10ppm, after vacuum from hydroxyl, hydroxy-up to 5ppm below apply to high-pressure mercury lamp, sodium lamp, metal halide lamp, such as low-hydroxy products; white pipe, used mainly for heating tube, heating tube, far infrared control the manufacture, milky quartz pearl quartz tube possession of new technology, the management side as if the surface of pearls, all aspects of performance than ordinary white tube better; filter tube to filter out ultraviolet UV band in the harmful wavelengths of 190-320nm ultraviolet light source applied to environmental protection manufacturing; no ozone UV filter tube and pipe the contrary, through the ultraviolet wavelength around 253.7nm, there is no ozone UV lamp main material, widely used in medical equipment, water treatment, food hygiene, such as sterilization; quartz casing diameter 8-120mm in between, has a single opening, double opening round, flat-top shape and widen the mouth of necking, flanging, sanding and other processing, high temperature resistance, corrosion resistance, good light transmission and moisture-proof, explosion-proof characteristics such as widely used in aquarium thermostat, disinfection equipment, heating pipes, water treatment, metal halide lamp, such as product manufacturing and environmental protection, health, chemical and other fields; quartz Clamshell specifications 8-180mm, the shape according to the customer requirements, the bubble shell can take capillary has to carry out the exhaust, high temperature, light transmission is good, mainly for JC, JD, H1-H7, the stage lights and high-pressure mercury lamp, sodium lamp, metal halide lamp, such as product manufacturing; quartz water jacket mainly used in printing and packaging processing industry ---- UV light-curing, UV light curing is a very reliable and can be used to replace hot air dryers and other drying technique of curing technology, which in the printing and packaging of the processing industry has been widely.

普通透明石英管SiO2纯度达99.9%以上,几何尺寸、化学稳定性、热稳定性、抗热变性和抗析晶性能优良,光学透过率达93%以上;脱羟管羟基在10ppm以下,经过真空脱羟,羟基可达5ppm以下,适用于高压汞灯、钠灯、金卤灯等低羟基产品;乳白管,主要用于发热管、加热管、远红外管的制造,珠光石英管乳白石英管之新工艺,管面好象珍珠的表面,各方面性能比普通乳白管更优;滤紫外线管能够滤除紫外光谱波段中对人体有害的190-320nm波长的紫外线,适用于环保光源的制造;无臭氧管与滤紫外线管相反,可透过253.7nm左右波长的紫外线,是无臭氧紫外线杀菌灯的主要材料,广泛用于医疗器械、水处理、食品卫生等杀菌;石英套管直径范围在8-120mm之间,有单开口、双开口、圆头、平头等外形和扩口、缩口、翻边、磨砂等加工,具有耐高温、耐腐蚀、透光性好及防潮、防爆等特点,广泛使用于水族恒温器、消毒设备、加热管、水处理、金卤灯等产品的制造和环保、卫生、化工等领域;石英泡壳规格Φ8-180mm,形状根据客户要求,泡壳上可以接有毛细管,可进行排气,耐高温,透光性好,主要用于JC、JD、H1-H7、舞台灯和高压汞灯、钠灯、金卤灯等产品的制造;石英水套主要用于印刷和包装加工工业---- UV光固化, UV光固化是一种十分可靠的、可取代热空气干燥机和其他干燥技术的固化技术,它在印刷和包装加工工业已经得到广泛应用。

In boiler field, proper atomization of high viscosity liquid fuel is the essential assurance to safe .stable and high efficient combustion for boiler; in the propulsion equipment of rockers and turbo jet-propelled engine, the atomization quality of liquid fuel is the precondition to improve combustion efficiency and supply sufficient propulsion; in the field of industrial manufacture, metal powder is made by liquid metal which is impacted by high velocity gas; in the field of agricultural irrigation, the water with certain velocity is used to strike metal disk to make insufflations proportionally to the irrigation field; in the technique of desulphurization and coal gasification, proper design of nozzle is the essential factor to advance the efficiency of desulphurization and coal transformation.

在锅炉领域,高粘度液体燃料的良好雾化是锅炉安全稳定高效燃烧的重要保证;在火箭推进装置、涡轮喷气式发动机中,液体燃料的雾化质量是提高燃烧效率并产生足够推力的前提;在工业生产领域,用高速气流冲击液态金属来制备金属粉末:在农业灌溉中,用一定速度的水流冲击金属圆盘破碎并改变方向实现对灌溉区域的均匀喷洒:在烟气脱硫、煤气化等工艺中,良好的喷嘴设计是提高烟气脱硫效率和碳转化率的重要因素。

The invention relates to a method for preventing a top metal layer of packaging chips from fracturing under high temperature, which avoids the fracture of the top metal layer caused by the inter-diffusion of a gold ball, an aluminum welding pad and a top layer metal by introducing a lower metal layer to the joint between the top layer wire and the aluminum welding pad and driving a metal plug to the joint between the top metal layer and the lower metal layer and a metal plug to the joint between the lower metal layer and the aluminum welding pad.

一种防止封装芯片上的顶层金属层在高温下断裂的方法,通过在顶层金属线和铝焊垫之间连接处引入下层金属层,并在顶层金属层和下层金属层之间的连接处以及下层金属层和铝焊垫之间的连接处打金属插塞,避免了因金球、铝焊垫以及顶层金属相互扩散造成的顶层金属层断裂。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。