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The rheological character of a polymer often appears as shear-thinning. Most polymers behaviour in a solution can be explained by the polymer chain or hard sphere theory. Other than that, shear-thickening polymer solution also exists. Its behavior can be explained by dilatant theory, which suggests that the shear-thickening of the solution is due to the swelling of the polymer particles. This phenomenon often occurs in suspension or emulsion. Solution exhibits a mixed behavior can also be found whose behavior is such that shear-thinning occurs under low shear force and shear-thickening occurs under high shear force. Under this circumstance, the viscosity versus shear force graph exhibits a spoon shaped curve. The rheological study can be applied to the dispersion of paint which can predict the dispersion effect of various polymer materials in solution.

中文摘要一般高分子聚合物溶液的流变行为多半呈现剪稀(shear-thinning)的现象，而大部分的高分子在溶液中的行为是以分子链或是硬球观点来解释，另外也有剪稠(shear-thickening)现象的高分子溶液，其流变行为则是以膨胀体观点来解释，即在高剪切力下，由於高分子团体积变大而使溶液黏度升高，这在悬伏液、乳液等常见；但也有在低剪切力下，溶液具有剪稀的行为，而在高剪切力下却成现剪稠的行为，在黏度对剪切力作图时，会呈现出一个勾形曲线的图形；流变行为的探讨可应用在涂布材料的分散技术上，以推测不同的高分子溶液对分散效果的影响。

It is included that 4-5 types of active sites exist in the catalytic system and the active site produced polymer with low molecular weight is easy to be activiated while TEA is used as the cocatalyst. While TIBA, the active site produced polymer with high molecular weight and seldom active site produced polymer with low one is prone to be activiated. MAO tends to activiate the active site produced polymer with middle-level molecular weight. In TEA-TIBA catalytic system, TEA and TIBA activiate the corresponding active site and the weight of every active site gradationally varied with the change of the ratio of the two cocatalysts. And the activity of the active site produced polymer with high molecular weight is proportion to the concentration of TIBA.

发现：TEA作为助催化剂时产生低分子量产物的活性中心易于活化，且体系中具有活性的活性中心有4～5种；TIBA易于活化产生高分子量的活性中心，基本上不能活化产生低分子量产物的活性中心；MAO对产生中等分子量产物的活性中心活化能力较强；在TEA-TIBA混合物体系中，TEA和TIBA各自对活性中心的作用表现为明显的互补现象，各活性中心的相对强度随着两种助催化剂之间的比例改变呈现渐次变化，其中产生高分子量产物的活性中心的相对活性(来源：c5AB3fC论文网www.abclunwen.com)与TIBA的浓度有明显的正相关性。

However, the thermal stability of metallic coordination polymer hardly enhanced in comparison with the polymer never coordinated transitional metallic ions. The reason might be that the energy of coordinate bond formed between metallic ion and polymer was trival in comparison with that of covalent bond in polymer. It started with coordinate bond when the coordinate polymer decomposed under high temperature, so it engendered little for the thermal stability at high temperature.

而金属配聚物较未配位金属的配体高温热稳定性提高不大，可能是由于金属离子与配体之间形成配位键的键能与配位体内的共价键键能相比要小得多，当金属配聚物受热裂解时，首先从配位键开始，因此对高温热稳定性的影响甚微。

Urushiol can be used as the basic raw material to develop economic and practical coating with good resistance to high temperature alkaline solution. Thus the polymer precursor was prepared using the polymerization of urushiol and formaldehyde. Then the urushiol-titanium chelate polymer (urushiol-Ti resin) was synthesized by way of the reaction of tetrabutyl titanate with the polymer precursor. The prospective target product was analyzed by means of high-performance liquid chromatography and Fourier transformation infrared spectroscopy.

为开发经济实用的耐高温碱水漆酚钛清漆，以漆酚为基本原料，先通过漆酚与甲醛缩聚，再将钛酸丁酯与前期合成产物反应，从而合成出了漆酚－钛螯合高聚物，并通过高效液相色谱和傅立叶红外技术检测了预期产物的合成情况。

The thesis mentioned that the conformation of lipase molecular can be induced by substrate to be an activated one in organic phase through constructing a water-in-oil micro-emulsion system. The activated conformation was recorded using high cross linking degree polymer. The effect of inducement on the activity of recorded lipase polymer was studied, the catalyzed property of recorded lipase polymer in water phase was investigated, and the fluorescence spectrum of lipase solution and recorded lipase polymer under different kinds of denaturalized circumstance were analyzed.

本文提出通过构建油包水型微乳体系，使酶分子能够在有机相中被反应底物诱导出活性构象，利用高交联度聚合物对该构象进行刻录，比较了底物诱导对刻录酶活性的影响，考察了刻录酶在水相中催化特性，并对脂肪酶溶液和刻录酶聚合物在各种变性条件下的荧光光谱进行分析。

Both the comb-shaped polymer KYPAM made by Beijing Hengju and polymer MO-4000 made in Japan are high performance polymer products which are high temperature-resistant and high salinity-resistant.

北京恒聚生产的KYPAM梳形聚合物和日本生产的MO-4000聚合物都是耐高温、杭高盐的高性能聚合物产品。

As a special form of polymer, the perdeuterated polymer foams not only have the microporours structure and good capabilities as same as nondeuterated polymer foams, but have some particular characters, such as isotope effect, nonradioactivity, and high deuterated ratio. For those reasons, the perdeuterated polymer foams will be used in many fields, especially in inertial confinement fusion and low wastage plastic.

全氘代聚合物泡沫作为一类特种聚合物材料，不仅具有常规聚合物泡沫材料所具有的微孔形貌和良好的物理化学、机械力学等性能，而且还具有独特的同位素效应，以及非常高的氘代率等特征，且无放射性，因而在激光惯性约束聚变(Initial Confinement Fusion，ICF)热核靶材料，以及低损耗塑料光纤材料等研究领域中具有十分广泛的应用前景。

In the dissertation, a new stabilization method, equal-density method was adopted to prepare modified asphalts with storage stability at high temperature. In this method, a compound was prepared by premixing polymer and filler, and the compound was mixed with asphalt to prepare Polymer-Modified Asphalt by changing the ratio of polymer and filler. The asphalts with good storage stability were formed with the addition of filler, by regulating the density difference between polymer and asphalt. With identifying the effect of composition factor and the technique conditions on mechanical properties of polymer/filler compound and the molecular distribution of the polymer, identifying the effect of composition factor and the technique conditions on the properties and structure of polymer/filler modified asphalt, Styrene-Butadiene-Styrene copolymer, Low Density PolyEthylene, Styrene-Ethylene-Butadiene-Styrene block copolymer modified asphalts with good storage stability and performance were prepared. Rheological method, gel content analysis and swelling measurement were adopted to elucidate the interaction between the polymer and filler. Filler reduced the difference between the polymer and asphalt with the premixing technique, which led to the improvement of the storage stability of the modified asphalts. The thermo-oxidative aging process of base asphalt and PMA were studied and the effect of antioxidant additives on the base asphalt and PMA were analyzed.

本论文采用等密度方法，即预先混合聚合物与填料制备复合物，复合物在沥青中会吸收油份而溶胀，改变填料的用量从而调节聚合物与沥青的密度差异的方法，制备出高温贮存稳定的改性沥青，并研究了工艺条件和配方因素对聚合物/填料复合物力学和聚合物分子量分布的影响，系统考察了工艺条件和配方因素对聚合物/填料改性沥青性能与形态结构的影响，研制出性能优良、高温贮存稳定的苯乙烯-丁二烯-苯乙烯三嵌段共聚物、氢化SBS、低密度聚乙烯改性沥青，并通过流变学分析方法及凝胶和溶胀测试探讨了聚合物与填料的相互作用，指出经过预混工艺填料改变了聚合物与沥青的密度差异，以此说明聚合物/填料改性沥青高温贮存稳定的原因；研究了基质沥青和聚合物改性沥青热氧老化过程，并分析了抗氧剂对基质沥青及聚合物改性沥青的影响，探讨了抗氧剂提高沥青耐老化性能的原因。

This paper studied the modification effects of granulated polymer-PR PLAST on asphalt mixtures by a large number of laboratory tests using different contents of the polymer. It is pointed that the rutting-resistance of mixture under high temperature is enhanced with the polymer contents and the Dynamic Stability is increased by 3 times on 0.5% polymer contents.

通过大量的室内试验分析，研究了粒化聚合物PR PLAST对沥青混合料性能的改善作用，通过对不同掺量的粒化聚合物沥青混合料的性能试验，发现掺量增加时，沥青混合料的高温抗车辙能力也随之提高，在掺量为0.5%时动稳定度提高约3倍；沥青混合料的水稳性也有一定程度的提高，低温抗裂性有少量改善。

Polymer processing is a high-energy process operation, and screw machinery is widespread applied to the polymer processing, such as screw extruders, screw injection molding machine and so on. The screw plasticating and conveying equipments based on shear rheology are generally adopted in polymer processing, in which materiels are dominated by shear stress. Therefore, there are some ubiquity disadvantages of the current methods of polymer materials processing, such as long thermo-mechanical, high energy consumption, too big equipment structure, and dependence on material properties.

加热管高分子材料成型加工是高能耗过程作业，目前普遍采用螺杆机械，如螺杆挤出机、螺杆注射机等，在螺杆机械中物料塑化输运主要是靠螺杆旋转时对物料的拖曳作用，固体输送为摩擦拖曳，熔体输送为粘性拖曳，物料的速度梯度与其流动和变形方向垂直，这种流动与变形受剪切应力支配，所以当前的高分子材料加工方法普遍存在物料塑化输运所经历的热机械历程长、能耗高、设备结构大、对物料特性依赖性强等缺陷。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。