查询词典 hemiacetal

Discussion of the solvent effect on oxidative free radical cyclization reaction of hemiacetal compounds 96 and 97

最后，研究半缩醛化合物96、97进行自由基反应之溶剂效应。

Any monosaccharide sugar that contains a ketone group or its hemiacetal.

任何一种含有酮基或其半缩醛的单糖。

Sugar that contains a ketone group or its hemiacetal.

任何一种含有酮基或其半缩醛的单糖。

A novel carbonyl transposition led by anilines'nucleophilic addition to methyl 2-keto α-D-glucopyranoside was discovered. And the mechanism of the reaction concerned to an enol rearrangment was provided through tracing the change of 〓H-NMR and 〓C-NMR of a hemiacetal intermediate which was obtained in the reaction of o-phenylene diamine with 2-keto glycoside. Both the intermediate and the converting product were identified by 〓H-NMR,〓C-NMR,〓H-〓H COSY and HMQC.

一、发现了2-位氧化α-甲基D-葡萄糖苷的芳胺亲核加成引起羰基转位的新方法，利用核磁共振氢谱及碳谱对邻苯二胺与2-位氧化α-甲基D-葡萄糖苷加成生成的稳定中间体半缩酮化合物在氘代丙酮中的变化进行跟踪，结合对转化产物的氢氢相关谱和HMQC结构确证，提出了该反应中2-位羰基通过烯醇化互变而转至3-位的机理并得到了验证。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。