查询词典 gas-forming reaction

The optimized structures and energies of the reactants, intermediates, transition states and products of two reaction channels (corresponding to syn-acraldehyde and anti-acraldehyde) in gas or in methanol solvent were obtained. The potential energy profiles reveal the processes of the trimethylamine-catalyzed Baylis-Hillman reaction between acraldehyde and formaldehyde in gas or in methanol solvent at the microscope level.

通过研究，获得了三种情况下两种反应通道(分别对应于顺式-和反式-丙烯醛)中涉及的反应物、产物、中间体、过渡态的优化结构及其能量，并由此得到了反应的势能面图，在电子微观层次上揭示了三甲胺催化的丙烯醛和甲醛的Baylis-Hillman反应的微观过程。

For water gas, the inspection of the amount of H〓 and CO is the basis. In the gasification reaction zone, deoxidize zone is the main reaction zone for generating flammable gas and it is also the core zone to control the gasification stability.

在空气煤气中主要检测CO〓含量，做为是否调控的依据，在水煤气中，而是检测H〓及CO的含量，做为是否调控的依据。

The invention uses benzene carbonic acid as raw material, uses hydrogen gas as reducing agent, and uses ZnO and CeO2 as main accelerating agent. In solid-bed reactor the invention carries out hydrogenation reduction reaction. The reaction temperature is 340-440Deg.C, gas hourly space velocity is 600-4800h-1, hydracid mole rate is 20:1-160:1, the selectivity ratio of benzaldehyde is 99%, and the productivity is above 95%.

该方法以苯甲酸为反应原料，以氢气为还原剂，以ZnO和CeO 2 的复合氧化物为主催化剂，在固定床反应器中，进行气相加氢还原反应，反应温度为340℃～440℃，气时空速为600h -1 ～4800h -1 ，氢酸摩尔比为20∶1～160∶1，采用本发明制备苯甲醛的选择性可达99％，收率可达95％以上。

The invention uses benzene carbonic acid as raw material, uses hydrogen gas as reducing agent, and uses ZrO2, TiO2 and Y2O3 as main accelerating agent. In solid-bed reactor the invention carries out hydrogenation reduction reaction. The reaction temperature is 340-450Deg.C, gas hourly space velocity is 600-4800h-1, hydracid mole rate is 20:1-160:1, the selectivity ratio of benzaldehyde is 96%, and the productivity is above 90%.

该方法以苯甲酸为反应原料，以氢气为还原剂，以复合氧化物ZrO 2 、TiO 2 和Y 2 O 3 为主催化剂，在固定床反应器中，进行气相加氢还原反应，反应温度为340℃～450℃，气时空速为600h -1 ～4800h -1 ，氢酸摩尔比为20∶1～160∶1，采用本发明制备苯甲醛的选择性可达96％以上，收率可达90％。

In this paper, the studies on the preparation of high pure mesitylene usingMTBE tail gas are made in both experimental and theoretical, different factorsaffecting the alkylation reaction to produce mesitylene by MTBE tail gas areinvestigated, the optimal condition of reaction is defined and the alkylationreaction kinetics of different components are studied, moreover, the comparisonbetween C4 raffinate oil and isobutene used for alkylation agent is made too.

本文对MTBE尾气烷基化法制备高纯度均三甲苯过程进行了实验研究和理论分析，确定了不同因素对烷基化反应的影响，得到了MTBE尾气制备均三甲苯的最佳反应条件，并对不同组分的烷基化反应动力学进行了研究。此外，对乙烯C4抽余油和异丁烯做为烷化剂的实验结果进行了分析和比较。

The invention relates to a method for treating gaseous VOCs by a solid extraction-electro-catalytic oxidation method and a device thereof. The method has the steps that: firstly, an electromagnetic type air compressor is used for controlling the gas flowing velocity by a glass rotameter so as to ensure contaminations in the contamination solution in a gas washing bottle to be stripped into an electrochemical reactor; secondly, microporous aeration heads are distributed in the electrochemical reactor, after being stripped into the electrochemical reactor, the gas is distributed in the electrochemical reactor by the microporous aeration heads, takes parts in the electrochemical reaction and passes through the cathode of absorptive and conductive porous material and the anode of iron sheet in sequence; thirdly, the treated gas finally flows out from the top end of the electrochemical reactor and enters into the gas absorption solution.

本发明涉及一种固态萃取-电催化氧化法处理气态VOCs的方法及装置，方法步骤：第一步，电磁式空压机通过玻璃转子流量计控制气体流速，将气体洗瓶中的污染物溶液中的污染物吹脱进电化学反应器；第二步：电化学反应器中布有微孔曝气头，气体吹脱进入电化学反应器后，通过微孔曝气头分布于电化学反应器内，参加电化学反应，依次经过通过吸附性导电多孔材料阴极和Fe片阳极；第三步，经处理后的气体最后从电化学反应器顶端流出进入气体吸收溶液。

In the research of advanced key techniques, the technique of nano-catalyst is developed and tested according to the requirement for the catalytic flame stablizer gas turbine and the related reaction model wil be fully construced. In the aspect of hydrogen shift and separation process, we are going to probe into various operating parameters for the water shift reaction and the membrane reactor alread constructed. Also, the high efficiency DPMS-based hydrogen shift and separation system that carry out both water gas shift and pressure swing absorption will be tested. The main task this year is to construct the proto-type clean hybrid power generation system.

前瞻关键技术研究方面，奈米触媒制备技术将依触媒驻焰气涡轮引擎之需求进行开发与测试，并建立相关反应模式；气化合成气转化与分离技术部分，将进行已建立水气转移反应与薄膜反应器之各项操作参数探讨，并进行以双孔径分子筛为担体，附加水气转移反应与变压吸附分离所建立之高效率分离富集H2方法之系统实测。

Using ethyne as source gas, CNTs were successfully synthesized by CVD method. By comparing different synthesis technics, the influences of parameter to the grow of CNTs, such as catalysts, growth time, reaction temperature and ratio of all kinds of carrier gases were investigated. The results showed that the influence of carrier gas, reaction temperature, and the growth time on synthesis of CNTs was significant. In conclusion, a better condition for carbon nanotube growth was obtained. Through analyzing Raman Spectrum of samples, GM and SWNTs' characteristic peak-RBM was indicated.

采用乙炔为碳源、氢气和氩气为载气，利用气相催化热解法在AAO模板上成功的制备出了纳米碳管，用TEM，SEM，EDS，Raman等表征方法研究了生长温度、裂解时间、载气含量和不同催化剂对碳纳米管的石墨化程度、产物形态的影响，指出了单壁碳纳米管的特征振动模式—径向呼吸振动模以及拉伸振动模式G模，缺陷导致的D模，并采用蒸金后的样品进行了场发射的测试，得到了F-N曲线，与理论符合较好。

As the concentration of FeO increasing, the rate of decarburizing and reaction-dissolving of refractory rises sharply. Meanwhile gas production rate of reduction reaction is increased and motion and foaming of molten slag are also speeded up. The corrosion feature of refractory containing graphite carbon is that the most severity area is slag level (interface of slag-gas phas -refractory) and slag-metal interface comes second, and the lowest corrosion rate is the area of iron-bath.

熔体的组成、温度及熔体与耐火材料间的相对运动对耐火材料的侵蚀产生着很大影响，而熔渣中FeO浓度是最主要的因素，FeO浓度提高，使耐火材料脱碳和反应熔蚀速度呈直线上升，熔体中还原产生气体量增加，熔体涨泡及运动速度提高，这些作用都加快了熔体对耐火材料的侵蚀。

The computational results indicate that surface catalytic combustion restrains gas phase combustion. Inlet velocity and tube diameters have important influence on catalytic combustion of hydrogen. For smaller inlet velocities,reaction is dominated by gas phase combustion. As the inlet velocity increases,there exist both surface catalytic combustion and gas phase combustion. For bigger inlet velocities,reaction is dominated by surface catalytic combustion. The temperature of flame core decreases with the decrease of tube diameter.

计算结果表明，表面催化反应对空间气相反应有抑制作用；入口速度和管径对氢气的催化燃烧过程有重要的影响，在入口速度较小时，燃烧主要是空间气相化学反应，随着入口速度的增大，燃烧过程同时存在着表面催化反应和空间气相反应两种控制因素，在入口速度较大时，燃烧主要是表面催化燃烧过程；随着管径的减小，微型管道内反应的最高温度降低。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。