查询词典 fullerene

Fourthly, based onour experiments and the literatures', the necessities of endohedralmetallofullerenes' formation are the existence of well graphitized of carbonand metal acetylide.

四在实验和文献报导的基础上，提出原料中完好石墨化的碳和电石型金属碳化物的存在是形成Fullerene笼内金属包合物的必要条件。

Fullerene, the third carbon allotrope besides graphite and diamond, was discovered by Kroto et al. in 1985. Since then, the studies of fullerenes has become the worldwide hot topic and significant progresses in many fields have been achieved.

富勒烯为除金刚石和石墨外碳元素的第三种同素异形体，自Kroto等1985年发现以来，对富勒烯的研究一直是世界性的热点话题，并在多个方面取得重要进展。

There is no electron transfer from tetrakis(2-thienyl)tetrathiafulvalene to [60]fullerene containing piperidinoxanthate dyad in benzonitrile in steady-state.

四硫富瓦烯及其衍生物是良好的有机导体及电子给体，噻吩基取代的四硫富瓦烯可作为合成含噻吩及四硫富瓦烯两种电子给体的聚合物的单体。

A compound 2-(3-hydroxyphenyl)[60] fullerene pyrrolidine was synthesized by the 1,3-dipolar cycloaddition reaction of the fullerene(C60) and azomethine ylide (prepared from glycine and 3-hydroxybenzaldehyde). The product was characterized by UV-Vis,1H-NMR ,FT-IR and MS. The reaction conditions affecting the yields of product were investigated and the optimum reaction conditions with product yield 75%(based on consumed C60) were:molar ratio of C60∶3-hydroxybenzaldehyde:glycine 1∶3∶6,reaction temperature 95℃,reaction time 18h.

利用甘氨酸和3-羟基苯甲醛与C60发生1， 3-偶极环加成反应，合成分离得到了2-(3-羟基苯基)[60]富勒烯吡咯烷，用UV-Vis、1H-NMR、FT-IR、MS等测试手段表征了产物的结构，并通过单因素方法，探讨了反应条件对产物产率的影响，得到最佳工艺条件：反应物摩尔比1∶3∶6，温度95 ℃，反应时间18 h，产物的产率可达75%（以消耗的C60计）。

The absorption peaks of cyanine dye part in two compounds were bathochromic shiftsin some content because they were infected by [60]fullerene, this indicated that therewas interaction between [60]fullerene part and cyanine dye part in the compounds.

但染料部分的吸收由于受〓富勒烯的影响，在不同程度上发生了红移，这初步说明了：〓富勒烯和染料之间有分子内的作用。

Results In Vero cell system,in direct virucidal and infection block experiments,fullerene C60 liposomes have induction effect on the expression of HSV-1F strain glycoprotein gC,whether it is under illumination or in lucifugal conditions,but in multiplication inhibition experiments,fullerene C60 liposomes have no effect to the expression of HSV-1F strain gC.

结果 在Vero细胞系统中，C60脂质体在直接杀灭和感染阻断的实验中，不论在光照还是在避光条件下，对HSV-1F株gC的表达均有诱导作用；但是在增殖抑制实验中，对HSV-1F株gC的表达没有影响。

The reaction of [60] fullerene with dimethyl malonate and diethyl malonate in the presence of manganese acetate dihydrate for 20 min afforded singly bonded [60] fullerene dimers in a 1, 4-addition pattern.

Mn作为一类良好的自由基引发剂，能有效地催化C〓与丙二酸二甲酯和丙二酸二乙酯的自由基加成反应，生成C〓的二聚体。在回流的氯苯中随着时间的的延长，二聚体分解成1，4-双加成的C〓衍生物。

The C_(60)-fused tetrahydrofuran derivatives are excellent synthons for further functionalization.While treated with different equiv,of BF_3·OEt_2 at various temperature,several novel functionized fullerene derivatives have been successfully synthesized.2.1,4-Fullerenols C_(60)ArOH were synthesized via the reaction of[60]fullerene with 4-substituted phenylhydrazine hydrochlorides and sodium nitrite under moisture and aerobic conditions.

这种四氢呋喃环合富勒烯衍生物作为一个合成中间体又可发生进一步的衍生化反应，其与不同当量BF_3·OEt_2在不同温度条件下可以得到二氢呋喃环合富勒烯衍生物、三元环合富勒烯衍生物等。2。

Three fullerene derivatives including a bisadduct of tetraethyl methano[60] fullerenediphosphona- te、a dimalonic acid[60]fullerene (DMA C60and fullerol were used to study the relationship between their photo-induced GSH depletion and structures.

采用二加成亚甲基富勒烯[60]二膦酸四乙酯、二加成富勒烯[60]丙二酸(DMA C60)和富勒醇 3种富勒烯衍生物研究富勒烯衍生物的结构与光诱导细胞内GSH耗竭的关系。

In the second part, the preparation and the properties of self-assembled films of Fullerene and Fullerene derivatives have been studied.

第二部分，主要进行了几例富勒烯与富勒烯衍生物的自组装薄膜的研究。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。