查询词典 formylation

With the occurrence of H2/Pd-C and ethyl formic ester,the reduction of the nitro group and the formylation of the amino group could be finished in one step.

但是在甲酸乙酯存在下，用H2/Pd-C对Ⅶ的硝基进行还原，得到的Ⅷ中的氨基可当即被甲酰化，使由Ⅶ到Ⅳ的两步反应一步完成。

Starting from 3, 5-dihydroxybenzoic acid, a total of 16 kinds of salicylicaldehyde derivatives have been synthesized by the esterification, substitution, reduction, formylation, condensation, brominate, functional group protection and deprotection reactions, of which 11 have not been reported yet. Enatiomerically pure 2-amino-2'-hydroxy-1, 1'-binaphthyl has been easily obtained from its racemic mixture by the eantioselective formation of inclusion crystals with N-benzylcinchoninium chloride.

树枝状大分子希夫碱三齿手性配体的设计与合成从3，5-二羟基苯甲酸出发，通过酯化、取代、还原、甲酰化、缩合、官能团的保护与去保护等反应合成了四个系列16种水杨醛衍生物，其中11中是未见文献报道的新化合物。

The formyl-2.2-bisferrocenyl-propane was synthesized by formylation reaction of 2.2-bisferrocenyl-propane with DMF in the presence of POCl3 in CHCl3 at (55±2)℃ in high yield and conversion, the diformyl-bisferrocenyl-propane was also obtained simultaneously in low yield.

随着二茂铁化学基础理论的发展及二茂铁衍生物的大量合成，人们也逐步发现了它们在许多领域的应用前景[1]，尤其是作为燃速催化剂，具有比金属氧化物更高的燃速催化效果。

The formyl-2.2-bisferrocenyl-propane was synthesized by formylation reaction of 2.2-bisferrocenyl-propane with DMF in the presence of POCl3 in CHCl3 at (55±2)℃ in high yield and conversion, the diformyl-bisferrocenyl-propane was also obtained simultaneously in low yield.

随著二茂铁化学基础理论的发展及二茂铁衍生物的大量合成，人们也逐步发现了它们在许多领域的应用前景[1]，尤其是作为燃速催化剂，具有比金属氧化物更高的燃速催化效果。

The influence of the Vilsmeier formylation reaction, the immediate Grignard reaction, the mediate Grignard reaction and the solvents on the synthesis of 2,8-diformyldibenzhothiophene was also investigated.

探索了Vilsmeier甲酰化、直接格氏试剂法、间接格氏试剂法以及溶剂对合成2，8-二甲酰基二苯并噻吩的影响。

As expected from the reaction mechanism, the carboxyl groups of aspartic and glutamic acid residues were not modified, while the amino group s that could react with the activated peptides were concomitantly protected by formylation.

如反应机理所预测的那样，天门冬氨酸和谷氨酸残基未被修饰，而能与活性肽反应的氨基则同时被甲酰化保护起来。

As expected from the reaction mechanism, the carboxyl groups of aspartic and glutamic acid residues were not modified, while the amino groups that could react with the activated peptides were concomitantly protected by formylation.

如反应机理所预测的那样，天门冬氨酸和谷氨酸残基未被修饰，而能与活性肽反应的氨基则同时被甲酰化保护起来。

Formylation and diformylation of dithieno [2,3-b:3',2'-d] thiophene were prepared by two methods. Firstly, aromatic carbanions were prepared by 1 Br/Li exchange of bromo dithieno[2,3-b:3',2'-d]thiophene with n-BuLi in THF at low temperature; 2 deprotonation of dithieno[2,3-b:3',2'-d]thiophene with LDA.

二噻吩并[2，3-b：3'，2'-d]噻吩单醛与双醛的制备首先通过两种方法产生芳基负离子：1溴代并三噻吩在四氢呋喃中与正丁基锂发生的溴锂交换；2用LDA对二噻吩并[2，3-b：3'，2'-d]噻吩去质子化作用。

The key intermediate 3-methylaminopiperidine was synthesized from 3-methylaminopyridine by two methods,formylation and lithium aluminium hydride reduction or condensation with triethyl orthoformate and sodium borohydride reduction,and then hydr...

以3-氨基吡啶为原料，分别通过甲酰化反应、氢化铝锂还原和原甲酸三乙酯缩合、硼氢化钠还原两种方法得到3-甲胺基吡啶，最后经催化氢化得到中间体3-甲胺基哌啶。

The key intermediate 3- methylaminopiperidine was synthesized from 3-methylaminopyridine by two methods, formylation and lithium aluminium hydride reduction or condensation with triethyl orthoformate and sodium borohydride reduction, and then hydrolysis.

以3-氨基吡啶为原料，分别通过甲酰化反应、氢化铝锂还原和原甲酸三乙酯缩合、硼氢化钠还原两种方法得到3-甲胺基吡啶，最后经催化氢化得到中间体3-甲胺基哌啶。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。