查询词典 fluorination

Based on this model, the structures, dipole moments and the nuclear magnetic resonance parameters were calculated for a series of functionalized nanotubes, including nitrene and carbene modification, as well as 1,2- and 1,4-fluorination.

本文采用C80H20模型来表示(10，0)碳纳米管，基于此模型计算了一系列氮烯、卡宾和氟化的单壁纳米管的结构、偶极矩，以及核磁共振参数。

The paper discloses a process for diazotization fluorination of aromatic primary amines utilizing sodium nitrite and anhydrous hydrofluoride to produce the corresponding diazonium fluoride which is decomposed, usually by heat, to make the desired fluoroaromatics .

本文通过重氮化工艺路线的改进，在液态氟化氢中进行重氮化和重氮盐的热分解，提高了芳香族氟化物的收率，并且使重氮化反应工艺能应用于工业化生产。

In the complex system of MeSO4, the removal of Ca2+ and Mg2+ by fluorination precipitation and double salt precipitation deep purification process was studied by single factor method.

分别以浸出液和氟化沉淀液为原料，采用单因素法对复杂MeSO4体系氟化沉淀除钙镁和复盐沉淀深度净化进行了研究。

Results show that the best value of w is 7~10% and 5~7%, i is 0.08~0.2 A/cm^2 and 0.03~0.05 A/cm^2 respectively, during the electrolysis fluorination of pyridine and tributylamine; the addition of N-butyl mercaptan into the organic mixture can stabilize electrolysis process with its mass fraction 15~20% at best; impulse current polarization work status of low load is helpful to the electrolysis process and reduces corrosion rate of anode; electrolysis temperature is suitable at 0~20℃; electrobath can use electrolyte inner circulation structure, exterior circulation structure or blending structure.

结果表明：吡啶和N-三丁胺电解氟化的最佳值w分别为7%~10%和5%~7%，i分别为0.08~0.2A/平方公分和0.03~0.05A/平方公分；有机混合物中添加N-丁基硫醇可稳定电解过程，其质量分数最佳为15%~20%；采用低负荷的脉冲电流极化工况有利电解过程，降低阳极的腐蚀速度；电解温度0~20℃为宜；电解槽可采用电解液内循环、外循环结构，或其混合结构。

The influences of the original organic compound structure,content,active additive,anode current density,polarization work status,electrolyte circulation rate and temperature as well as electrobath structure during electrolysis fluorination are researched in the Center.

研究了电解氟化时原始有机化合物结构及其含量、活性添加剂、阳极电流密度、极化工况、电解液循环速度和温度以及电解槽结构等各种因素的影响。

The classification,synthesis and application of ionic liquids in fluorination were introduced in brief.

本文简要介绍了离子液体的分类、合成及其在氟化工艺中的应用。

Longer reaction time (48 h) and increase of hydrogen fluoride and catalyst are good for fluorination.

反应后的滤渣可再生为氧化汞循环使用，回收3次，反应的转化率和选择率均大于85%。

Reaction mechanism for 11,1,2-tetrafluoroethane preparation is carried out through gas phase fluorination by hydrogen fluoride over chromium-magnesium fluorination catalysts with trichloroethylene as main materials and dynamics models are set up.

研究了以三氯乙烯为主要原料，在铬镁氟化催化剂存在下，用氟化氢气相氟化制备1，1，1，2-四氟乙烷的反应机理，建立了动力学模型。

The application results from fluorination showed microwave heating could accelerate chemical reactions markedly. The reaction time could be shortened 50% at least than that of conventional heating. The relationship between fluorinating agents\' structure and their activity was studied systematically. In addition, an anhydrous KF with higher activity was prepared by using expansion effect of microwave heating. As we known, solvents were very important to reaction. The comprehensive study showed some less polar aromatic solvents could be used as dipolar solvents. In addition, they had better effect than dipolar solvents in some occasions, such as fluorination of chlorobenzaldehydes and chlorinated diphenyl ketones etc. The primary applications of ionic liquids were also studied which indicated reactions with ionic liquids as solvents were more efficient and simple.

研究表明，微波是一种节能高效的加热方式，在微波作用下的卤素交换氟化反应具有反应速度快、转化率高、选择性好的优点，其反应时间可较常规加热缩短50%以上；同时也系统地研究了氟化剂种类及制备方式对其反应活性的影响，并利用微波加热的膨化作用制备出了一种活性较高的KF，其活性与喷雾干燥KF相差不大；溶剂对反应具有重要的作用，在此系统地研究了强极性非质子溶剂和中等极性非质子溶剂的应用情况，发现一些中等极性的非质子溶剂如硝基芳烃和氯代芳烃类溶剂在氯代苯甲醛类化合物的氟化反应中具有比强极性非质子溶剂更好的使用效果。

This article describes the low pressure fluorination process for production of dichlorodifluoromethane , discusses the problems of prevailing in the process and proposes an improved process-high pressure fluorination reactor with external circulation.

介绍了二氟二氯甲烷低压氟化反应的生产过程，指出和剖析了生产技术中存在的问题，提出了采用外循环加压氟化反应器的改进措施。改进后的反应器具有生产能力大，反应气质量好，催化剂损耗低等特

It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发，分析对称连杆曲线上鲍尔点的产生条件，提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品，年生产总值3000万美元，产品价廉物美、选料上乘、质量保证，深受国内外客户的青睐