查询词典 first-order reaction

By means of GC, GC-MS, GC-IR, the reaction products were investigated and the results showed that there are triylene, camphene, limonene, p-cymene, terpinolene -terpinene,-terpinene,-fenchyl formate, linalyl formate, terpinyl formate, bornyl formate and isobornyl formate containing in the products,and linalyl formate was first discovered in addition reaction of a -pinene and formic acid .The content of the main product terpinyl formate is up to 60.4%,the selectivity is 64.5%.

采用GC、GC-IR、GC-MS等对反应产物进行定量和定性分析，结果表明：微波辐射下α-蒎烯与甲酸的反应产物含有三环烯、莰烯、对-伞花烃、α-松油烯、γ-松油烯、柠檬烯、异松油烯、甲酸葑醇酯、甲酸异龙脑酯、甲酸龙脑酯、甲酸芳樟酯、甲酸松油酯。

First, the preparation of l,2-dichloro-4-nitrobenzene, which l-chloro-4-nitrobenzene reacted with chlorine in a self-designed chlorinator, in presence of Lewis acid catalyst,.was investigated. By means of the Orthogonal Experiments design and single factor experiments, the influence of several reaction variables on the yield were examined and the optimum reaction conditions under the intervallic operation were obtained, the yield of l,2-diehloro-4-nitrobenzene was 83.26%.

为此，本文首先在自行设计的塔式氯化器中，以对硝基氯苯为原料，路易氏酸作催化剂，分子氯氯化合成3，4-二氯硝基苯(合成3-氯-4-氟-硝基苯的原料)，根据该氯化过程特征，利用正交试验设计方法结合单因素实验考察了有关因素对氯化过程的影响，优化得到了最佳的氯化工艺条件，3，4—二氯硝基苯的收率可达83.26％。

Content The basic concepts of atomic, molecular and crystal structure and coordination compound structure; Macroscopic rule of chemical changes: the first law of thermodynamics, the second law of thermodynamics, the third law of thermodynamics, chemical equilibrium and the rate of chemical reaction; redox reaction

课程目标：无机化学是化工、材料、生物工程等专业学生入校后的第一门化学基础课。通过本课程的学习，使学生掌握无机化学的基本原理和重要元素及其化合物的性质、典型反应等基本知识，并为本专业的其它后继课程提供必要的理论和知识。

2Nd, thorough analysis: The Earth may say is an extremely marvelous thermonuclear reactor, when the earth interior pressure achieved certain critical, in the Earth material may decay the nuclear matter is called as the thermonuclear material, can have the thermonuclear reaction, thus has the huge energy, then the melted partial materials, form the rock magma are the liquid state materials, this response stratification plane is possibly many stratification planes, first possibly is located between the earth's crust and the mantle, upward next two transfers, displays for the light density material diastrophism as well as density upper mantle material phenomena and so on solidification; Under second possibly is located between the mantle and the core, the pressure is more formidable, causes not not easily to have the thermonuclear reaction thermonuclear material to have the response, forms the relative quite stable liquefied material level, simultaneously is upward next two transfers, forms the counter-flow phenomenon which the high density under mantle as well as the high density core material contact liquefies and is far away cools; These material periodicity regular movements and so on convection as well as Earth polar axis rotation are possibly the basic source powers which the terrestrial magnetic field produces.

深入剖析：地球可以说是一个非常奇妙的热核反应堆，当地球内部的压力达到一定的临界，地球物质中可衰变的核物质统称为热核物质，就会发生热核反应，从而产生巨大的能量，进而融化部分物质，形成岩浆即液态物质，这个反应层面可能是多个层面，第一层可能位于地壳与地幔之间，向上下两边对流，表现为轻密度物质的地壳运动以及中密度上地幔物质的固化等现象；第二层可能位于下地幔与地核之间，压力更为强大，引起不易发生热核反应的热核物质发生反应，形成相对比较稳定的液化物质层，同时向上下两边对流，形成中高密度的下地幔以及高密度地核物质的接触液化和远离冷却的对流现象；这些对流以及地球极轴自转等物质周期性规律性运动可能是地球磁场产生的根本源动力。

First, the precursor polymer with azobenzene groups on main-chain was obtained by condensation polymerization between 4,4'-dihydroxyazobenzene and N,N-(2-bromoethyl)aniline through Williamson reaction. Then the azo polymer containing azobenzene groups both on main-chain and side-chain was prepared through an azo-coupling reaction between the precursor polymer and the diazonium salt of 4-nitroaniline.

设计并合成了一种新型的主侧链均含偶氮生色团的聚合物，首先通过4，4'-二羟基偶氮苯与N，N-二溴乙基苯胺之间的Williamson反应缩聚得到主链含偶氮苯基团的先驱聚合物，再通过重氮偶合反应得到目标产物，并利用核磁共振、红外光谱、紫外可见光谱、热分析等手段确认了所制备聚合物的结构。

Since the dismutation of superoxide radicals by SOD is a reaction that is rate-limited by diffusion and enhanced by electrostatic guidance, all these structural features may be related to GP-MnSOD's high catalytic activity: first, Lys38 may increase the effective enzyme-substrate association rate by enhancing the electrostatic gradient at its substrate channel; second, an excess of acidic over basic residues makes the negative surface potential of GP-MnSOD more larger than those of other known MnSODs. This may enhance the reaction rate by reducing futile collisions of superoxide radicals with GP-MnSOD's surface.

因此，GP-MnSOD的上述结构特征可能与GP-MnSOD的较高酶活有关：首先，Lys38增加了底物通道口的正静电势梯度，从而可能促进了GP-MnSOD的活性中心与底物的有效结合速率；其次，GP-MnSOD表面覆盖的过量酸性残基使得它比其它MnSOD在底物通道以外的蛋白表面更多地被负静电势所覆盖，这可能有效地减少了超氧阴离子与GP-MnSOD表面的无效碰撞，从而提高了反应速率。

The first stage is an endothermic reaction, and the second one is an exothermic reaction.

采用双组分分阶段一级反应模型求出了四个污泥样品的表观活化能和指前因子，给出了样品热解的动力学方程，通过理论计算，双组分分阶段一级反应模型的理论数据与实验数据吻合良好。

In chapter 4 an abnormal reaction that the nitro group of 1-aryl-2-nitroethenescan be easily replaced by the organic moity of FG-RZnI using Ni〓 and tertiaryamine as catalyst was first given. The experimental results show that in the presenceof catalytic amount of Ni〓 and tertiary amines, the reaction of FG-RZnI andl-aryl-2-nitroethenes give the substitution products l-aryl-l-alkene, instead ofMichael addition products.

通过实验发现，在催化量的Ni〓及叔胺催化下， l-硝基-2-芳基乙烯与烷基碘化锌并不进行Michael加成反应，而是发生1-硝基-2-芳基乙烯中硝基被取代的反应，生成了高产率的1-芳基-l-烯烃，由于此反应的原料易得、反应条件温和、产物的产率高，因而是合成l-芳基-1-烯烃的有效方法。

A reaction mechanism is proposed to involve one pre-equilibria. First we select a Pt model drugs Na_2PtCl_6 to oxidate L- cysteine and L- cysteine hydrochloride, and study the kinetics of the reaction.

对L-半胱氨酸及其盐酸盐是一级反应的实验结果，建立了半光氨酸一个前期平衡的化学动力学机理，根据该机理圆满解释了实验现象和结果。

The preparation process of self-holing polyimide with organosilicon block includes the following steps: 1 the first reaction of polyacid anhydride in functionality not lower than 2, silicon oil with 2 or more amino or imino groups and polyamine with 2 or more amino groups, and the second reaction with one or several kinds of added isocyanate with 2 or more isocyanate radicals to produce sol of polyamido acid containing organosilicon block; 2 solidifying the sol to obtain solid polyamido acid containing organosilicon block; and 3 imidonating the solid to obtain self-holing polyimide with organosilicon block.

本发明公开了一种有机硅嵌段自发孔聚酰亚胺的制备方法，该方法包括以下步骤：(1)有机溶剂中具有大于或者等于2的酸酐官能团度的多酸酐与具有大于或者等于2的胺基或亚胺基的硅油以及具有大于或者等于2的胺基的多胺反应，随后添加一种或多种具有含有等于或者大于2个异氰酸酯基的异氰酸酯反应，生成含有机硅嵌段聚酰胺酸的溶胶。(2)溶胶固化制成有机硅嵌段聚酰胺酸固体。(3)固体亚胺化，即得有机硅嵌段自发孔聚酰亚胺。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。