查询词典 first-order reaction

Two steps were included in this reaction, first, sodium alkoxide was synthesized by th reaction between sodamide and cedrol, then cedrol methyl ether was synthesized by methylation reaction between sodium alkoxide and dimethyl sulfate.

反应分两步，首先氨基钠与柏木脑反应生成醇钠，然后醇钠与硫酸二甲酯进行甲基化反应生成甲基柏木醚。

Two SP1-like elements and half of binding motifs of RAR are found in the 119 bp region from -nt. 325 to -nt. 207 upstream of the first ATG. An AP1/cAMP like reaction element is found in the 113 bp region from -nt. 206 to -nt. 94 upstream of the first ATG of the CK13 gene 5' flanking region. We didn't know the reaction element CTGAATCA between -nt.

仔细分析CK13基因5'旁侧-nt.325~-nt.207之间119bp片段中，发现有两个类似的SP1反应元件及一个与半个维甲酸受体结合的模块，而CK13基因5'旁侧-nt.206~-nt.94之间113bp片段中-nt.199~-nt.192间的碱基CTGAATCA类似AP1/cAMP的反应元件。

A method of production of a reduction resistant dielectric ceramic composition having a superior low frequency dielectric characteristic and further improved in accelerated lifetime of insulation resistance, specifically a method of production of a dielectric ceramic composition containing a main component including a dielectric oxide of a specific composition, a first subcomponent including a V oxide, a second subcomponent containing an Al oxide, a third subcomponent containing an Mn oxide, and a fourth subcomponent containing a specific sintering aid in a specific ratio, including a step of mixing at least part of the materials of the subcomponents excluding one or both of at least the material of the third subcomponent and material of the fourth subcomponent with the starting materials prepared for obtaining the material of the main component to prepare the pre-reaction material, a step of causing the prepared pre-reaction material to react to obtain a reacted material, and a step of mixing the materials of the subcomponents excluded when preparing the pre-reaction material with the obtained reacted material to obtain a dielectric ceramic composition.

本发明提供一种介电陶瓷组合物的制造方法，其中介电陶瓷组合物以特定的比例含有如下成分：含有特定组成的介电体氧化物的主成分，该主成分可以提供具有优异的低频率介电特性的、绝缘电阻的加速寿命进一步提高的耐还原性介电陶瓷组合物的制造方法，含有V氧化物的第1副成分，含有Al氧化物的第2副成分，含有Mn氧化物的第3副成分，以及含有特定的烧结助剂的第4副成分；该方法包含如下工序：将至少除去第3副成分的原料和第4副成分的原料的一种或两种的其它副成分原料的至少一部分，与为了得到主成分原料而准备的起始原料混合，准备反应前原料的工序；使准备的反应前原料反应而得到反应后原料的工序；以及在所得的反应后原料中，混合在准备反应前原料时除去的副成分原料，得到介电陶瓷组合物原料的工序。

We studied trivalence chromium ion electrode reaction on three different surface state by cyclic voltammetry, discussed electrode activation influence on electrode reaction, and analysed the mechanism of electrode reaction. We discussed current efficiency during the first charge process and charge/discharge cycle performance by invariable current charge method.

应用循环伏安法考察了三价铬离子在三种不同表面状态石墨电极上的电极反应，探讨了电极表面活化处理对三价铬离子的电极反应的影响，并分析了电极反应的机理；采用恒电流充电的方法探讨铬液流电池初次充电过程的电流效率及恒电流充/放电循环的性能。

This paperindicated that it was good for condensation reaction when benzene-ring bearingelectron-attaching groups. It also showed that and the 6-hydroxyl group could bereacted with acyl halide, haloid ether and halo alkene, but not with halo alkane. It wasnot only the first time to find that the reaction product of D-mannitol and aromaticaldehyde is tri-condensation derivatives, but also the first time to obtain thep-phthaldehyde-sorbitol derivatives containing eight hydroxyl groups.

研究发现：苯环上有吸电子基团时对缩合反应有利；多元醇缩醛衍生物6-羟基除与酰氯反应外，也能和卤代酸酯、溴代烯反应，但不与卤代烷反应；首次发现D-甘露醇与醛反应主要得到三缩合物；首次合成了含有8个羟基的对苯二甲醛和山梨醇的缩合物。

The results showed high class PbSt2 could be synthesized by this new saponifying process.Compared with metathetical process,the reaction time shortened,liquid-solid ratio and moisture content of filter cake decreased.Powder product could be prepared by one-step process,and particle product by two-step process.For the optimum processing conditions,the reaction temperature and time for one-step process were 65℃ and 10min,the amount of alkali added in the first step was 50%;reaction temperture and time were 65℃ and 10min for the two-step process.

结果表明，用皂化法工艺可得到优等品PbSt2，较复分解工艺，反应时间缩短、液-固比降低、滤饼湿含量比减小，一步式工艺得到粉状产品，二步式工艺得到颗粒状产品；最佳工艺条件为：一步式工艺反应温度65℃，反应时间10min；二步式工艺第一步的加碱量比50%，反应温度65℃，反应时间10min。

The reaction has been drawing increased attention in that the reaction permit the use of organoboron compounds that are thermally stable and inert to water and oxygen.In this section microwave promoted Suzuki reaction of Sodium tetraphenylborate (NaBPh4) with carboxylic anhydrides catalyzed by Pd(PPh3)2Cl2 in THF was first reported.

第二章：微波辐射下Pd配合物催化NaBPh_4与羧酸酐的偶联反应研究本章中我们在微波辐射条件下，研究了PdCl_2(PPh_3)_2催化NaBPh_4与羧酸酐偶联反应，合成出了十种不对称芳酮，并分别考察了微波辐射功率、辐射时间、溶剂和原料配比等因素对反应的影响，优选出了较佳的反应条件，并根据文献及实验结果，讨论了可能的反应机理。

Meantime, we further studied this reaction under microwave irradiation conditions and first introduced the concept of the solvent-free and no-catalyst in this reaction, expanded the olefination of organozinc halides reagents with aldehydes, enlarged the application scopes of this reaction.

同时在微波辐射条件下进一步研究了该类反应，并在该类反应中初步引进无溶剂、非催化的概念，扩展和完善了有机卤化锌试剂与醛的烯基化反应，扩大了其应用范围。

Study the first phase of this experiment by kinetic method, it shows this reaction isfirst-degree reaction. At 32℃,34℃,36℃and 38℃, each constant of reaction rate is 0.0042,0.0052, 0.0098 and 0.0146, and the constant of dynamics is pyramided by the hoist oftemperature.

第一阶段化学反应为一级反应，在32℃、34℃、36℃和38℃的化学反应速度常数分别为0.0042、0.0052、0.0098、0.0146，随着温度的升高，化学动力学常数逐渐增大。

From the potential energy profile, it can be predicted that, the dominant channel of this reaction consists of three steps: the two reactants first form a three-membered ring intermediate (INT1) through a barrier-free exothermic reaction of 19.2 kJ/mol; three-membered ring intermediate (INT1) isomerizes to a four-membered ring silylene(P2) via the transition state (TS2) with an energy barrier of 22.8 kJ/mol; four-membered ring silylene(P2) further reacts with ethene(R2) to form a silicic bis-heterocyclic compound (P3), which is also a barrier-free exothermic reaction of 132.2 kJ/mol.

用CCSD//MP2/6-31G*方法研究了单重态二甲基亚烷基硅烯与乙烯生成硅杂双环化合物环加成反应的机理，根据该反应的势能面可以预言，该反应的主反应通道有三步组成：第一步是两反应物（R1， R2）首先生成了一三元环中间体（INT1），它是一无势垒的放热反应，放出的能量为19.2 kJ/mol；第二步是三元环中间体(INT1)经过渡态TS2异构化为了四元环硅烯（P2），其势垒为22.8 kJ/mol；第三步是四元环硅烯（P2）进一步与乙烯(R2)反应生成了硅杂双环化合物（P3），该反应也是一无势垒的放热反应，放出的能量为132.2 kJ/mol。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。