查询词典 first-order reaction

Under the conditions of stir speeds 400 r·min~(-1) and distance between anode and cathode 1 mm, by using the orthogonal design, the optimum technological conditions were found that the current density was 0.3 A·cm~(-2), initial NaOH concentration in catholyte was 50 g·L~(-1), reaction times of two steps were all theoretical electrochemical reaction times. In the first electrosynthesis, initial Na_2CrO_4 concentration in anolyte was 650 g·L~(-1), and reaction temperature was 80℃. In the second electrosynthesis, initial Na_2Cr_2O_7 concentration in anolyte was 700 g·L~(-1), and reaction temperature was 85℃.

324全氟磺酸增强复合阳离子交换膜、阴阳极液中搅拌速度均为400r·min~(-1)条件下，通过正交实验得到优化工艺条件为：电流密度0.3A·cm~(-2)，阴极液氢氧化钠初始浓度50g·L~(-1)，两步反应时间均为理论电催化反应时间，第一步阳极液铬酸钠初始浓度650g·L~(-1)，反应温度80℃，第二步阳极液重铬酸钠初始浓度700g·L~(-1)，反应温度85℃。

First, a chlorinator was self-designed in this paper, and dichloride of 2-methyl-1-propene was synthesized by 2-methyl-1-propene reacted with chlorine fast in this reactor. By means of the Orthogonal Experiments design and single factor experiments, the influence of several reaction variables on the yield were examined and the optimum reaction conditions under the intervallic operation were obtained, the yield and selectivity of dichloride of 2-methyl-1-prop-ene were more than 65% and 80% respectively. Second, the preparation of 2-methylene-1, 3-propanediol, which dichloride of 2-methyl-1-propene reacted with alkali was investigated. By means of the Orthogonal Experiments design and single factor experiments, the influence of several reaction variables on the yield were examined and the optimum reaction conditions under the intervallic operation were obtained, the conversion of dichloride of 2-methyl-1-propene was 100%. Moreover the preparation of MPO, which 2-methylene-1, 3-propanediol reacted with hydrogen, in presence of Al_2O_3-Pd catalyst, was gotten, and the product was appraised.

本文在氯化反应过程中，自行设计制作出了氯化管式反应器，在该反应器中异丁烯和氯气迅速混合反应生成二氯异丁烯，根据该氯化反应特征利用正交试验和单因素试验考察了有关因素的影响并优化得到了最佳工艺条件，二氯异丁烯的总收率达65％以上，选择性达80％；接着，对二氯异丁烯进行水解反应制得了2-甲烯-1，3-丙二醇，讨论了相关因素对水解反应的影响，并通过正交试验和单因素试验得到了较佳工艺条件，二氯异丁烯的转化率达100％；同时还对制备的2-甲烯-1，3-丙二醇在常压下采用三氧化二铝负载钯催化剂催化加氢得目的产物MPO，并对产品进行了鉴定，从而打通了整个工艺路线。

Radioactive decay studies have found a kinds of elements can be α or β decay and the decay into another element, while the α-decay product of -α-rays became one of the deep structure of the material means of .1911, the Rutherford and others bombarded atoms with α-rays observed wide-angle deflection to determine the nuclear structure of atoms and nuclei was first proposed the term .1919 year, Rutherford and others have also found that with α-ray bombardment of nitrogen will release the nuclear protons, this is the first time Artificial realization of a nuclear reaction, after the bombardment of nuclei with the radiation caused by nuclear reaction method to become the primary means of research in nuclear.

放射性衰变研究发现了一种元素可以通过α衰变或β衰变而变成另外一种元素，而α衰变的产物——α射线又成了人们探讨物质深层结构的手段。1911年，卢瑟福等人用α射线轰击原子、观察到大角度偏折，从而确定了原子的有核结构，并首次提出原子核这一名词。1919年，卢瑟福等人又发现用α射线轰击氮核会放出质子，这是首次用人工实现的核反应，以后用射线轰击原子核来引起核反应的方法逐渐成为研究原子核的主要手段。

Effects on the reaction of factors such as reactant ratio, reaction time, and reaction temperature were investigated, and optimum reaction conditions were determined as follows: mole ratio of cyanuric chloride to ethylamine to sodium hydroxide to sodium methyl mercaptide was 1:2.1:2.0:1.7, and the temperature and time of the first, second, and third substitution reactions were -2, 0, and 82℃ and 30, 60, and 180 min, respectively.

讨论了原料配比、反应时间和反应温度等因素对反应的影响，获得了较佳的反应条件。较佳反应条件为三聚氯氰：乙胺：氢氧化钠：甲硫醇钠＝l：2.1：2.0：1.7，第一、第二、第三取代反应的反应温度和反应时间分别为-2℃、0℃、82℃和30、60、180min。

The effects of different factors on the laser-induced graft polymerization on the PET surface were analyzed, and the mechanisms were discussed. The factors were: 1 Monomers with smaller molecules resulted in better modification than polymeric monomers. Acrylamide monomer was chosen as hydrophilic modifier finally; 2 Higher concentration of the monomer solution favored the graft reaction; 3 With the increasing laser fluence, the surface hydrophilicity of PET films increased at first, then decreased. More laser pulses led to a more hydrophilic surface; 4 Benzophenone as a photosensitizer hindered the graft polymerization; 5 The homopolymer retardant of ammonium iron sulfate hexahydrate in a proper concentration retarded the formation of homopolymers and promotes the graft copolymerization; 6 The solvent of monomer solution also affected the graft reaction. Different solvents functioned in different ways. Ethanol can promote the graft reaction because of the activity of hydrogen in its structure; 7 pH value of the monomer solution affects the polymerization rate, and a lower pH value was favorable to the graft reaction.

这些影响因素的作用分别为：1小分子单体的表面改性效果好，确定以丙烯酰胺为亲水性改性单体；2较高的单体溶液浓度有利于接枝反应；3激光能量密度增大，薄膜表面亲水性先显著增强，后又减弱；激光脉冲次数越多，改性后表面亲水性越强；4光敏剂BP对PET表面接枝聚合反应有阻碍作用；5适当浓度的均聚物抑制剂六水合硫酸铁铵能减少单体均聚物的生成，促进接枝聚合；6单体溶液的溶剂也影响接枝聚合的反应进程，不同溶剂的影响作用原理不同，含较活泼氢的乙醇能促进接枝反应；7溶液pH值影响单体聚合速率，pH值较低有利于接枝反应。

Therefore esterification crosslinked reactionbetween polyearboxylic acid and wood can be quantitatively determined.According toexperiment results of stereoscopic configuration choices by crosslinking agents,crosslinkingreaction between model of reaction intermediate and wood,and the intermediate characteristic incrosslinking reaction,crosslinking reaction intermediate was proofed.We can infercrosslinking reactions between polycarboxylicacid and wood want through a mechanism of twosteps reaction process,the first cyclic anhydrides were formed as intermediates by dehydratingbetween hydroxyls in polycarboxylic acids,second esters were occurred by substitution reactionbetween wood hydroxyls and cyclic anhydrides.

从而可全面定量表征木材与多元羧酸类化合物的酯化交联反应；依据交联剂立体构型选择性、反应中间体模型物与木材的交联反应和交联反应中间体的波谱特征实验结果，证实了交联反应中间体，因此可以推测：多元羧酸类化合物与木材化学组分的交联反应是经历两步反应的机理，首先多元羧酸中相邻羧基的羟基之间脱水形成五元环酸酐中间体，然后木材的羟基与酸酐发生亲核取代反应形成酯。

Synthesis of Antidote of N-Dichloroacetyl-2-methyl-1-oxa-4-aza-spiro-4.4-nonane BI Hong-mei, ZHANG Jin-yan, LIANG Ying, SHEN Yong (College of Arts and Sciences Heilongjiang August First Reclamation University, Daqing 163319, Heilongjiang, China) Abstract: N-Dichloroacetyl-2-methyl-1-oxa-4-aza-spiro-4.4-nonane was synthesized by one pot method with isopropanolamine, cyclopentanone and dichloroacetyl chloride. The optimum reaction conditions obtained are as follows:the proportion in moles of the above materials is 1∶1∶1.2, reaction solvent is toluene, reaction temperature is -15 to -10 ℃,reaction time is 3 h, under the optimum condition, the yield of the compound is 50.0%.

除草剂解毒剂N-二氯乙酰基-2-甲基-1-氧杂-4-氮杂-螺[4.4]壬烷的合成毕洪梅，张金艳，梁英，沈勇(黑龙江八一农垦大学文理学院，黑龙江大庆 163319)摘要：以33%的氢氧化钠水溶液为缚酸剂，异丙醇胺、环戊酮和二氯乙酰氯为原料，采用&一锅法&合成了N-二氯乙酰基-2-甲基-1-氧杂-4-氮杂-螺[4.4]壬烷，采用正交实验法得到最佳反应条件：反应原料摩尔比为1∶1∶1.2，苯作溶剂，反应的温度为-15 ℃~-10 ℃，搅拌时间为3 h，产率达到50.0%。

The results showed that the synthesis reaction was biphasic, because of the presence of the intermediate product dicalcium phosphate dehydrate. The second step reaction occurred just at the end of the first one and ended rapidly in less than 30s, which was called as explosive reaction. The pseudo-Avrami equation was used to describe the reaction processes.

结果表明，合成过程为生成中间产物二水磷酸氢钙的两步式反应，其中第二步反应在第一步反应结束后才开始，并且在很短的时间内(0s)迅速完成，即发生了&爆炸式&反应，反应过程可用类Avrami方程进行表征。

The side reaction of the Curtius reaction was studied and a urine by-product was isolated and characterized.b. Through the detailed study of the behavior of various N-acetyl phenylalanine methyl esters under the condition of the Bischler-Napieralski reaction, it was found for the first time that the formation of benzyl oxazole derivatives was a competitive approach with the normal B-N reaction. A convincing mechanism was suggested and a rule governing the reaction was summarized.c.

一、基于Bischler-Napieralski反应设计了以苯丙氨酸衍生物为原料的路线，在这条路线的研究中，主要取得了以下结果：、建立了一条以芳香醛和丙二酸单甲酯为原料，通过缩合、氢化、Curtius等反应制备苯丙氨酸甲酯的通用合成路线，对其中的缩合反应条件及Curtius反应中的副反应进行了深入的研究，利用这条路线合成了四个芳环取代的苯丙氨酸单甲酯衍生物。

The phase equilibrium data of SBO-FAME-Methanol, SBO-FAEE-Ethanol and Glycerol-FAEE-Ethanol systems were measured. The results indicated that it involved two different stages: liquid-liquid-solid reaction stage and liquid-solid reaction stage. When the molar ratio of methanol to oil is 12:1 at 65℃, the turning point is at a 55% biodiesel yield. The liquid-liquid-solid reaction model was proposed based on the double-membranes theory. It indicated that the process is reaction and mass transfer controlled together at the first stage, and the second stage is reaction controlled. The predictions of the model are matched with the experimental results.In the end, the acid was extracted using methanol and ethanol from jatropha curcas l oil.

测定了生物柴油制备过程中的SBO-FAME-Methanol、SBO-FAEE-Ethanol、Glycerol-FAEE-Ethanol三组分相平衡数据，表明固体碱催化过程分为液-液-固和液-固两个反应阶段，在醇油摩尔比为12：1、65℃的初始反应条件下，转化率达到55%时，为第一阶段向第二阶段的转折点；基于双膜理论建立了固体碱催化制备生物柴油的非均相液-液-固反应模型，表明两个反应阶段分别为传质、反应共同控制和反应控制，模型计算值与实验值吻合较好。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。