查询词典 first-order reaction

The first ethynyl group is reacted with the first reactive group in a first carbon-carbon bond formation reaction and the second ethynyl group is reacted with the second reactive group in a second carbon-carbon bond formation reaction to crosslink the first backbone with the second backbone, thereby forming the packaging substrate.

在第一个碳－碳键生成反应中，使第一个乙炔基与第一个反应性基反应，在第二个碳－碳键生成反应中，使第二个乙炔基与第二个反应性基反应，将第一种主链与第二种主链交联，从而制成组装基片。

The whole sintering process of SHS converter fettling materials can be divided into three steps. The first step is the decomposition reaction of carbonates and sodium nitrate, which is an endothermic reaction. The second step is the SHS reaction, i. e. thermite reaction, the metal of Al reacts with CO〓, O〓, NO〓, Fe〓O〓 to form Al〓O〓. The speed of thermite reaction is very quick, and accompanied with large amount of heat emission and temperature rise. The third step is the reaction of spinels formation. The Al〓O〓 produced by SHS reacts with MgO to form spinels.

整个SHS补炉料的烧结过程分三步进行：第一步为碳酸盐、硝酸钠的分解反应，属于吸热反应；第二步为SHS反应即铝热反应，金属铝粉与CO〓、O〓、NO〓、Fe〓O〓等反应生成Al〓O〓，反应速度很快，并伴随有巨大的放热和温度升高；第三步为合成尖晶石的反应，SHS反应产物Al〓O〓与MgO反应生成尖晶石。

The suitable synthesis conditions were defined as follows: the molar ratio of DCPP and resorcin was 2.1:1;the dosage of catalyst made by myself was 1.5% of the amount of the resorcinol;the first reaction temperature was 120～130℃,the reaction time was about 60min,the second reaction temperature was160～170℃,the reaction time was 60min,the third reaction temperature reaches to 210～220℃ for removing the unreacted phenol and superfluous DCPP.

确定了反应的最佳工艺条件：DCPP和间苯二酚的物质的量之比为2.1：1；使用自制的催化剂，用量为间苯二酚质量的1.5％；起始反应温度为120～130℃，反应时间约为1h；第二步反应温度为160～170℃，反应时间约为1h，最后把温度升到210～220℃除去残留在产品中的苯酚和过量的DCPP，产品收率约为92.0％。

The results showed that the population administered with free adjuvant cholera vaccines,both low dose group and common dose group,occurred the weak adverse reaction with 10￣25% rate.The reaction rates between two dose groups of the same vaccine have not significant difference;The reaction rate of the first inoculation(19￣25%) is higher than those of the second inoculation(10￣15%)(P 05);The inoculating local reaction is very light ,only the very few subject occurred the scleroma with 15 mm of diameter.The reaction of aluminum absorbed cholera vaccine is slightly stronger than those of other groups.

结果表明，不加铝佐剂的O139型霍乱菌苗及O1群霍乱菌苗，不论是低剂量组（两剂全程接种45亿菌体）抑或常剂量组（全程接种90亿）接种人群均可产生10～25％的体温呈轻度升高的弱反应，并且同种菌苗的两剂量组的反应率无显著差异；第一剂接种的反应率（19～25％）较第二剂接种的（10～15％）高，P＜0.05；接种局部反应轻微，只有个别受试者出现直径小于15mm的硬结；加佐剂的O1群吸附霍乱菌苗的反应较其它组强。

The first step reaction of methanol hydrochlorinate is methanol react with hedrogen chloride to produce monochloro methane and water, if the methanol can meet the request, the high pure monochloro methane can be refined.

甲醇法第一步反应为甲醇与氯化氢反应生成氯甲烷和水，如果所用原料甲醇满足要求，反应产物经过简单的精制即可得到高纯度的一氯甲烷。

The Suzuki reaction, the coupling of organoborate compounds with organic electrophiles catalyzed by Palladium complexes, is a valuable Csp2-Csp bond forming reaction. The reaction has been drawing increased attention in that the reaction permit the use of organoboron compounds that are thermally stable and inert to water and oxygen.In this section microwave promoted Suzuki reaction of phenylboronic acid with benzyl halides catalyzed by Pd(PPh3)2Cl2 DMF/H2O(v/v=10 : 2) was first reported.

第四章：微波辐射下Pd配合物催化端烯与芳卤偶联反应研究本章中我们在微波辐射条件下，研究了PdclZ(P Ph3)：催化端烯与芳卤的偶联反应，合成出了七种乙烯基化合物；并分别考察了微波辐射功率、辐射时间、原料配比、和PTc等因素对反应的影响，优选出了较佳的反应条件，并根据文献及实验结果，讨论了可能的反应机理。

Four phenylalanine derivatives were synthesized with this approach. The condition of the condensation reaction was optimized. The side reaction of the Curtius reaction was studied and a urine by-product was isolated and characterized.b. Through the detailed study of the behavior of various N-acetyl phenylalanine methyl esters under the condition of the Bischler-Napieralski reaction, it was found for the first time that the formation of benzyl oxazole derivatives was a competitive approach with the normal B-N reaction.

一、基于Bischler-Napieralski反应设计了以苯丙氨酸衍生物为原料的路线，在这条路线的研究中，主要取得了以下结果：、建立了一条以芳香醛和丙二酸单甲酯为原料，通过缩合、氢化、Curtius等反应制备苯丙氨酸甲酯的通用合成路线，对其中的缩合反应条件及Curtius反应中的副反应进行了深入的研究，利用这条路线合成了四个芳环取代的苯丙氨酸单甲酯衍生物。

The results show that:First, concentration of hydrogen peroxide have the most obvious influence to oil yield and carbon black yield,with the increase of concentration of hydrogen peroxide the oil yield first increase then decrease,when concentration of hydrogen peroxide is 8.19% or so,the oil yield reach to the biggest value, and with the increase of concentration of hydrogen peroxide carbon black yield decrese;Then,reaction time have more obvious influence to oil yield and carbon black yield,oil yield increase but carbon black yield decrease with the increase of reaction time;Thirdly,reaction tempreture have some influence to oil yield and carbon black yield,samely,oil yield increase but carbon black yield decrease with the increase of reaction tempreture;Finally,reaction pressure does almost no influence on oil yield and carbon black yield.

研究结果表明：过氧化氢质量浓度对产油率和炭黑产率的影响最为显著，产油率随过氧化氢质量浓度的提高先提高后降低，在过氧化氢质量浓度为8.19%左右时达到最大值，炭黑产率随过氧化氢质量浓度的提高而降低；反应时间对产油率和炭黑产率的影响也比较显著，产油率随反应时间的增加而提高，炭黑产率随反应时间的增加而降低；反应温度对产油率和炭黑产率也有一定的影响，产油率随反应温度的提高而相应地提高，炭黑产率随反应温度的提高而降低；在本文实验范围内，反应压力对产油率和炭黑产率基本上没有影响。

According to depositions of nanostructured silica in plants and chemically synthesized nanostructured silica sprayed into leaves and physical properties of leaf conferred by silica depositions as well, the first step reaction of high-specific supramolecular recognition process of fungi spores and host surfaces is discussed. Nanostructured silica can alter leaf physical properties including topography and hydrophobicity and affect extracellular matrix release and formations of germ tube, appressorium and penetration peg.

初步揭示了纳米结构SiO〓与植物真菌病害发生的关系：从化学合成的纳米结构SiO〓在叶表的沉积以及沉积之后赋予植物叶片独特的物理学特性入手，详细研究了纳米结构SiO〓抑止真菌孢子和寄主表面的高度专一性的超分子识别过程的第一步反应，从而提出纳米结构SiO〓可能改变植物叶表面原有的拓扑结构和疏水等物理学特性，即形成特殊的双亲性表面，影响真菌胞外物质的释放和芽管、附着胞及侵染钉的形成，阻断真菌孢子早期的侵染过程，从而确定靶向的真菌病害的控制措施。

In this report, half-esterification between these pendent hydroxyl groups of hydroxyl-PU and maleic anhydride could lead to new pendent groups, carboxylic groups. These highly polar carboxylic groups in the side chain of PU could play the role of internal emulsifier. They had self-dissociation ability in the water or were neutralized first by appropriate amount of base. Then, PU bearing carboxylic group could dispersed steadily in the water, named aqueous-based polyurethane dispersion.

在本论文中，利用原来亲油性Hydroxyl PU主链段上悬挂的羟基经由与琥珀酸酐的半酯化(Half-esterification Reaction)反应后，使PU在侧链上悬挂具有强极性的羧酸基，其可作为聚胺酯分子中的内乳化剂，羧酸基能在水相中自身解离产生离子或加入适量碱使之中合，使聚氨酯高分子能够稳定分散於水中，即所谓水性PU分散液(Aqueous-based Polyurethane Dispersion)。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。