查询词典 ethylenediamine

PETEDA was synthesized through pentaerythrityl tetrabromide and ethylenediamine's reacting by the aminolyzing reaction of alkyl halide. It was proved that the product contains a lot of amino groups analyzed by FTIR (Fourier Transform Infrared Spectroscopy) and ETA.

以四溴代季戊烷和乙二胺为原料，通过卤代烷胺解反应，合成了树枝状分子季戊四乙二胺，采用傅立叶变换红外光谱和元素分析对其进行了表征。

Bis (P—bromobenzylamino) ethane and 1,2—bis (m—Iodobenzylamino) ethane may be prepared by condensation of the corresponding halo benzaldehyde with ethylenediamine and followed by catalytic hydrogenation of the Schiff's bases over Pto_2 in glacial acetic acid solutions: Both Ⅱa and Ⅱb may react in neutral mediam with aldehydes to form well—defined crystalline tetrahydro—imidazole, which may be served as derivatives of identification for aldehydes: Under the same condition, however,Ⅱb may ...

用1，2-二乙烷与二十余种醛类作用，得到有固定熔点的晶体衍生物，它们的熔点分布在85—210℃之间，产率为40—96％，这试剂与甲基酮类在相同条件下无反应，因此，它可作为鉴定醛类的专属试剂。 2。上述衍生物用稀盐酸在室溫处理，能发生水解，可以定量地收回原来的醛，因此这试剂又可作为分离醛类的试剂。 3。上述衍生物可以用非水滴定法半微量地测定其分子量可作为鉴定醛类的另一项参考数据。 4.1，2-二乙烷与醛类能生成晶体衍生物，但这试剂也与甲基酮在同样条件下发生反应，所以不适合作为鉴定醛类的专属试剂。

Mercaptopropyl methyldimethoxysilane was synthesized by thiourea in the presence of tetramethylammonium iodine as a catalyst and mixed liquid containing ethylenediamine and trichloroethylene as a neutralizer, without solvent, in which the reaction temperature, catalysts ,neutralizer and their amounts were optimized.

以四甲基碘化铵为催化剂，乙二胺和三氯乙烯的复合液为中和剂，在无溶剂体系中，用硫脲法合成了甲基巯丙基二甲氧基硅烷。

The main synthetic methods and application prospect of organic energetic dinitrate salt s,ethylenediamine dinitrate,azobisformamidine dinitrate,carbohydrazinium dinitrate,polyaminoguanidine dinitrate and tetrazine dinitrate,were reviewd with 26 references.

综述了乙二胺二硝酸盐、偶氮二甲醚二硝酸盐、碳酰肼二硝酸盐、氨基胍类二硝酸盐和四嗪类二硝酸盐等有机含能二硝酸盐的主要合成方法及应用前景。

Although CdS and NiSe belonged to the same crystal system, they had a great difference in the morphology of products produced in ethylenediamine by a solvothermal process. By making a crytallographic comparison between CdS and NiSe, I thought that fourcoordinated crystals were more prone to grow one-dimensionally in the stacking direction of tetrahedrons. This hypothesis could also be embodied in many examples.

硫化镉和硒化镍的晶体结构都为六方晶系，但在以乙二胺为溶剂的溶剂热条件下合成出的产物形貌有很大的差别，我们通过对两类晶体结构的结晶学比较，我们认为4配位的晶体更趋向于生成一维纳米材料，并提出生长方向即为四面体堆积方向，这一假设也能得到许多例子的证实。

The reaction mechanism of tetrakis hydroxymethyl phosphonium chloride and raw collagen were researched by the simulated materials of collagen including glycin,ethylenediamine and hide powder.

通过研究四羟甲基氯化鏻与皮胶原模拟物反应，间接证明THPC主要与胶原蛋白的氨基结合，可与氨基以n∶n=1∶2.2形成交联，THPC与羟基和酰胺基均有少量结合，并在pH=8.0时结合量最高。

These catalysts were found to have good activity and reusability in the Heck vinylation of aryl iodides and acrylate, among which the ethylenediamine modified resin supported Pd(0) catalyst kept a high activity at the 17th run at 90℃.

结果表明，该类催化剂具有良好的催化活性和重复使用性能，其中用乙二胺功能化树脂负载的Pd(0)催化剂在90℃重复使用17次时能保持良好的催化活性。

Using tellurium power and corresponding simple metal salts as reactants, we have prepared a series of nanocrystalline metal tellurides (Cu〓Te〓, CoTe〓, NiTe〓, SnTe, Ag〓Te, CdTe, PbTe) in ethylenediamine system at low temperature (140-180℃).

通过乙二胺体系的溶剂热过程，以碲粉为碲源，从简单金属盐出发，在较低的温度下（140-180℃）成功地制备了一系列纳米金属碲化物(Cu〓Te〓、CoTe〓、NiTe〓、SnTe、Ag〓Te、CdTe、PbTe)。

The millimetersized tubular crystal selenium was first prepared. By studying the process of treating selenium in ethylenediamine, we proposed the mechanism of the preparation of selenides under solvothermal condition. The selenides came into being from the reaction of metal ions with Se〓, which was obtained by the amine attacking selenium. Moreover, a new precursor to prepare nanocrystalline selenides at room temperature was obtained. From this precursor, we have prepared nanocrystalline silver selenides, copper selenides, lead selenides and cadmium selenides nanorods.

首次报道了采用溶剂热处理的方法制备出厘米尺度的管状结构硒晶体；通过对硒粉在乙二胺中的溶剂热研究，初步探讨了以单质硒为硒源的溶剂热合成硒化物的反应机理应是硒受胺类的亲核进攻变成Se〓而进一步形成相应的硒化物；获得了合成硒化物纳米晶的前驱物，并在室温条件下合成了硒化银、硒化铜、硒化铅纳米晶和硒化镉纳米棒等。

In this thesis, nano-scale particles of metals, metal sulfides, selenides, oxides and nano-composites of metals/polymer, semiconductor sulfides/polymer have been successfully prepared by γ-ray irradiation technique in sorts of systems including water system, alcohol system, ethylenediamine system, microemulsion and emulsion system at room temperature and under ambient pressure. The possible formation mechanisms of nano-scale materials were suggested, and some factors of affecting the formation of nano-materials were studied.

本论文使用〓Co-γ射线辐射技术，在常温常压下分别于水体系、乙醇体系、乙二胺体系、微乳液和乳液体系中，成功地制备了纳米金属、硫化物、硒化物、氧化物以及金属／聚合物、半导体硫化物／聚合物纳米复合材料，并初步探讨了纳米材料形成的可能机理和影响因素。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。