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Methods 4-Hydroxy- benzonitrile was treated with sodium hydrogen sulfide and anhydrous magnesium chloride in dimethyl formamide to give thioamide, which was then directly cyclized with ethyl 2-chloroacetoacetate without separation to give ethyl 2-(4-hydroxyphenyl)-4-methylthiazole-5-carboxylate(2) in one-pot; then 2 was formylated with Duff reaction adopting hexamethylenetetramine in trifluoroacetic acid to give ethyl 2-(3-formyl-4-hydroxyphenyl)-4-methylthiazole-5-carboxylate(3); finally, the target compound was obtained by the treatment of 3 with hydroxylamine hydrochloride and sodium formate in formic acid.

采用"一勺烩"方法,以4-羟基苯甲腈为起始原料,首先与硫氢化钠和无水氯化镁在N,N-二甲基甲酰胺中反应,所得中间体不经分离,直接加入2-氯乙酰乙酸乙酯进行环合反应,得到2-(4-羟基)苯基-4-甲基-5-噻唑甲酸乙酯(2);然后通过六亚甲基四胺/三氟乙酸进行Duff反应,得到2-(3-甲酰基-4-羟基)苯基-4-甲基-5-噻唑甲酸乙酯(3);再经盐酸羟胺/甲酸/甲酸钠体系脱水得到目标化合物。

The components of higher relative content in wines were ethyl acetate, butanoic acid methylester, acetic acid isobutylester, butyric acid ethylester, isobutylalcohol, isopentylacohol acetate, isopentylalcohol, acetic acid hexylester, hexylalcohol, ethyl caprylate, decanoic acid ethylester, acetic acid phenethylester, lauric acid ethylester, benzeneethanol, octanoic acid,decanoic acid and hexanoic acid ethyl ester.

猕猴桃酒样中乙酸乙酯,丁酸甲酯,丁酸异丁酯,丁酸乙酯,异丁醇,乙酸异戊酯,异戊醇,乙酸己酯,己醇,辛酸乙酯,癸酸乙酯,乙酸苯乙酯,月桂酸乙酯,苯乙醇,辛酸,癸酸,己酸乙酯等相对含量较高。

Methoxy sec-ethyl acetate, Ethyl acetate, Ethyl forate,α-Pinene,β-Pinene, Camphene, Junipene, Limonene, P-Cymene, Linalool and Terpinole are regarded as the key flavorous components, which result in the peculiar smell and taste in fruits of Rubus L..

综合分析表明,甲氧基次乙基乙酸酯、乙酸乙酯、甲酸乙酯、α-蒎烯、β-蒎烯、莰烯及桧烯、柠檬烯、对伞花烃、芳樟醇、萜品醇类等化合物是四种悬钩子类果实的主要香味成分。

The results indicated that the use of such membrane could achieve satisfactory separation effects (condensate of high alcoholicity and rich flavoring substances was obtained, membrane-flowing rate: ethanol>esters except ethyl lactate>aldehyde>other alcohol>water), the membrane had good selectivity to ethanol and ethyl caproate had good membrane-flowing rate and membrane-passing percentage, however, ethyl lactate, aldehyde and methanol had poor mambrane-passing percentage with heavy loss during membrane-passing.

结果表明,渗透汽化膜有良好的分离性能,可得到高酒精度、香味物质富集的冷凝液;过膜速率:乙醇>酯类>醛类>其他醇类>水;膜对乙醇选择性好,己酸乙酯的过膜率及过膜速率高;乳酸乙酯、醛类及甲醇过膜率较小、损失量较大;渗透汽化膜用于白酒的香气成分分离有良好的工业应用前景。

The main chemical components of Bulgaria are Citronellol、Trans-Geraniol、Nerol、Methyl eugenol、Linalool、β-Phenyl ethyl alcohol. The main chemical components of Xinjiang Province areβ-citronellol、trans-geraniol,β-phenyl ethyl alcoho, farnesol, geranellyl acetete, 7-octamoic acid ethyl ester.

保加利亚玫瑰油的主要成分为β-香茅醇、反式-香叶醇、橙花醇、芳樟醇、β-苯乙醇、甲基丁子香酚;新疆玫瑰油的主要成分为β-香茅醇、反式-香叶醇、β-苯乙醇、7-辛烯酸乙酯、乙酸香叶酯、金合欢醇。

At the same concentration, extracts show the highest scavenging rate on the four different free radicals extracted by ethyl ether, acetone, ethyl ether and ethyl acetate, respectively.

在相同的浓度下,对自由基的清除作用最大的分别为乙醚、丙酮、乙醚和乙酸乙酯提取物。

Said preparation method includes: dissolving curcumin and polyvinyl pyrrolidone according to mass ratio of 1:4-1:15 in organic solvent (for example absolute ethyl alcohol, propyl alcohol, isopropyl alcohol and ethyl acetate), making reduced pressure distillation at 55-95deg.C to remove most of ethyl alcohol to obtain paste material, quickly pouring the paste material into a stainless steel disk, vacuum drying at 60-90deg.C in drying oven and pulverizing.

本发明将姜黄素和聚乙烯吡咯烷酮按质量比1∶4~1∶15溶于有机溶剂(如无水乙醇、丙醇、异丙醇、乙酸乙酯等),于减压蒸馏55-95℃下除去大部分乙醇至成糊状,迅速倒入不锈钢盘中,在60-90℃下真空烘箱烘干,用粉碎机粉碎,得到姜黄素固体分散体。

For the α-arylation of ethyl acetoacetate, the product was α-aryl ethyl acetoacetates, rather than ethyl a-arylacetates which are the major products in other catalytic systems.

较为惰性的氯代芳烃在Pd2/L1的催化下,也能够跟1,3-二羰基化合物发生α-芳基化反应。

Methods Used the salvia miltiorrhiza original medicine cribble, the control temperature (80±2)℃ carried on 95% ethyl alcohol, 50% ethyl alcohol and the water withdraws in turn 3 times, the ethyl alcohol withdraws each 0.5h to circulate 10min, the filtrate reduced pressure concentration.

方法采用丹参原药粗粉,控制温度(80±2)℃进行95%乙醇、50%乙醇和水依次提取3次(乙醇提取每0.5h 循环10min ,滤液减压浓缩)。

To evaluate the potential of several biodiesels, which had different content of fatty acid methyl ester, as substitute solvent for quizalofop-p-ethyl emulsifiable concentrate, the type and content of fatty acid methyl esters in tested biodiesels were analyzed by gas chromatography, and 5% quizalofop-p-ethyl ECs were prepared with different biodiesels, respectively. The control test against gramineous weeds by the 5% quizalofop-p-ethyl ECs were carried out in greenhouse.

为评价不同来源生物柴油作为溶剂配制精喹禾灵乳油的效果,采用气相色谱法测定了几种生物柴油中脂肪酸甲酯的种类及含量,利用相应制备的5%精喹禾灵乳油进行了防治禾本科杂草的盆栽试验,同时比较了不同生物柴油对药剂稀释液表面张力、干燥时间和在叶片表面沉积量等药液物理性状的影响。

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