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We investigated constituent of triterpenoid saponins ofAlbizzia, two new compounds together with two known compounds were isolated from Albizzia julibrissin Durazz. by using column chromatography (macroreticular resin, silica gel, Sephadex gel, reverse phase silica gel),preparative HPLC methods et al.On the basis of spectroscopic analysis, including IR,ESI-MS,~1H-NMR,~(13)C-NMR,HMBC,HMQC,~1H-~1HCOSY and chemical methods, the structure of two new compounds were identified as 3 - O -[β-D-xylopyranosyl(1→2)-β-D-fucopyranosyl (1→6)-β- D -2- deoxy - 2 - acetoamidoglucopyranosyl] -21-O-[(6S)-2- trans- 2,6-dimethyl - 6 - O-β- D - quinovopyranosyl -2,7- octadienoyl] - acacic acid- 28 - O-β-D-glucopyranosyl(1→3)[α-L-arabinofuranosyl(1→4)]-α-L-rhamnopyranosyl(1→2)-β-D-glucopyranoside acacic acid 3- O -β- D- glucopyranosy(1→3)-β- D- fucopyranosl(1→6) [β-D- xylopyranosyl (1→2)]-β-D-glucopyranoside ;two known compounds were acacic acid lactone 3- O -β-D- xylopyranosyl-(1→2)-β-D-fucopyranosl (1→6)- 2-deoxy -2 -acetoamido -β-D- glucopyranoside ; acacic acid lactone 3- O-β-D-xylopyranosyl(1→2)-α-L- arabinopyranosl (1→6)- 2- deoxy - 2- acetoamido -β-D-glucopyranoside . The study lays chemical foundation and chemical reference substance for enhancing quality standard of Albizzia julibrissin Durazz.
本研究论文在综述国内外对合欢属Albizzia三萜皂苷化学成分和药理作用研究进展的基础上,利用传统植化分离手段和现代分离技术,包括大孔树脂、硅胶、葡聚糖凝胶、反相硅胶等柱色谱,制备高效液相色谱法等技术从中药合欢皮中分离得到了4个化合物,其中,2个新化合物和2个己知化合物,并进一步通过现代分析技术IR,ESI-MS,~1H-NMR,~(13C-NMR,HMBC,HMQC,~1H-~1HCOSY等和化学方法鉴定了2个新化合物的结构分别是:3-O-[β-D-吡喃木糖基(1→2)-β-D-吡喃夫糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖基]-21-O-[(6S)-2-反式-2,6-二甲基-6-O-β-D-吡喃鸡纳糖基-2,7-辛二烯酸基]-金合欢酸-28-O-α-L-呋喃阿拉伯糖基(1→4)[β-D-吡喃葡萄糖基(1→3)]-α-L-吡喃鼠李糖基(1→2)-β-D-吡喃葡萄糖苷,金合欢酸3-O-β-D-吡喃葡萄糖基(1→3)-β-D-吡喃夫糖基(1→6)[β-D-吡喃木糖基(1→2)]-β-D-吡喃葡萄糖苷;2个已知化合物结构分别是:金和欢酸内酯3-O-β-D-吡喃木糖基(1→2)-β-D-吡喃夫糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖苷,金和欢酸内酯3-O-β-D-吡喃木糖基(1→2)-α-L-吡喃阿拉伯糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖苷。
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The influence of polymerization degree and alcoholysis degree of polyvinyl alcohol, the ratio of Span - 20 to Tween - 20, the amount of polyvinyl alcohol, the amount of water - soluble inhibitor, pretreatment and after - treatment processes and et al on the hydrophobic property and stability of the water -repellent is investigated.
研制了一种以聚乙烯醇、2种非离子表面活性剂——Span-20和Tween-20、水溶性缓蚀剂等为原料的水性憎水剂;考察了聚乙烯醇的聚合度和醇解度、2种非离子表面活性剂之间的配比、聚乙烯醇含量、乳化剂含量、水溶性缓蚀剂含量、预处理和后处理工序等因素对憎水剂憎水效果及稳定性的影响。
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It is discovered that the Newton direction of Peng et al can be obtained from an algebraically equivalent path.
与此同时,分析了该方法与Peng等人近期工作的联系,发现互补条件的右端可表示成熵函数的负梯度。
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Fischer et al.in 1973. Since these compounds have various particular reactions in organic synthesis,especially in vitamins,peptides,synthesis of anti-cancer drugs and natural products,and as olefins, alkyne polymerization catalysts demonstrated its unique advantages and broad application prospects.
由于这类化合物有各种奇特的反应性能,在有机合成中,尤其是在维生素,多肽,抗癌药物和天然产物的合成,和作为烯烃,炔烃聚合催化剂方面显示出其独特的优越性和广阔的应用前景。
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Historically, the discovery of the buckminsterfullerene molecule by Kroto et. al in 1985 when they investigated the nature of carbon present in interstellar space is unique since it is one and only new allotrope discovered in the 20th century.
从历史角度来看,1985年Kroto等人发现富勒烯C〓的这件事可以说是独一无二的,因为C〓是整个二十世纪发现的唯一一种新的同素异形体。
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Fullerene, the third carbon allotrope besides graphite and diamond, was discovered by Kroto et al. in 1985. Since then, the studies of fullerenes has become the worldwide hot topic and significant progresses in many fields have been achieved.
富勒烯为除金刚石和石墨外碳元素的第三种同素异形体,自Kroto等1985年发现以来,对富勒烯的研究一直是世界性的热点话题,并在多个方面取得重要进展。
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Lightfoot et al have developed one of these iridium-based systems for the stereocontrolled synthesis of lilial by asymmetric reduction of an allyl alcohol and subsequent oxidation of the alcohol.
Lightfoot等发展了一种基于铱的系统,通过烯丙醇和第二阶段酒精氧化的不对称还原,用来进行铃兰醛的立体控制合成。
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This regimen has been shown to reduce mortality in a small clinical trial published by Amato et al .
阿玛托等人公开的小型临床试验显示,该种治疗法能减少肺损伤的死亡率。
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Contemporary teenager must have persistence to obey collective, respect individual, stress the righteous, initiate the trustworthiness and emphasize the industry and thrift moral value mindset, combine the amenability with active, harmonize with compete, guard with creative, et al, in order to adapt to the knowledge-based economy society development.
当代青少年只有坚持服从集体、尊重个人、讲究道义、倡导诚信、崇尚勤俭的道德价值取向。并将顺从与主动、和谐与竞争、守成与创新、内省与开放等人格特质有机地结合起来,才能有效地完成自身的现代人格建构,适应经济全球化和知识经济社会发展的需要。
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The result of the analysis of variance for succinic acid is in agreement with Giudici et al.
差异分析的结果为2等是与 Giudici意见的一致。
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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.
曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。
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The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.
稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。
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When I was in school, the rabbi explained everythingin the Bible two different ways.
当我上学的时候,老师解释《圣经》用两种不同的方法。