查询词典 esterification

Esterification process of a reversible step wereresolved as two irreversible steps,then chemical decomposition of wood components weredecreased in liquid acid catalyst.Experiments showed that crosslinking catalysts took catalysisrole on two process in the esterification,(1)five cyclic anhydrides formed by dehydration ofpolycarboxylic acids,(2)esters occurred by substitution between five cyclic anhydrides andwood.

实验中的反应过程使一般的酯化一步可逆反应，分解为两步不可逆反应，减少了液相酸催化过程的木材组分化学降解；交联反应催化剂对于多元羧酸类化合物与木材组分的酯化反应具有两个过程的催化作用：(1)多元羧酸脱水形成五元环酸酐中间体；(2)木材与五元酸酐中间体亲核取代反应形成酯。

In this paper the study on optimizing the esterification of cellulose and some character of CAB(the degree of substitution of cellulose, solubility, the thermal properties and molecular weight) was discussed. The mechanism of the esterification of cellulose in butyric acid/ acetic acid/ butyric anhydride which comprises the creation of the acetic butyric anhydride, acetyl cation and butyryl cation was investigated by the study of the effect of the content of the organic acid and anhydride on the degree of acetyl and butyryl substitution of cellulose.

最后本文根据纤维素在丁酸/乙酸/丁酸酐中的酯化反应中有机酸以及酸酐的添加量对最后产物纤维素醋酸丁酸酯中乙酯或者丁酯取代度的影响，提出纤维素在丁酸/乙酸/丁酸酐中的酯化反应经历一个混和酸酐以及乙酰碳正离子、丁酰碳正离子的生成过程。

To explore their catalytical capability, the esterification of phenyl formate and 1-butanol was chosen. It is found that the esterification yield exceeds 80%, which demonstrates the heteropoly acid has higher catalytic activity.

为了探索所得杂多酸的催化性能，考察了H_4PMo_(11)VO_(40)对苯甲酸和正丁醇酯化反应的催化效果，发现在最佳条件下酯收率达到80％多，证明其为一种较好的酸催化剂。

There are two synthetic methods for the two carboxylates starting from pyrrole,(1) the carbonylation of pyrrole using trichloroacetyl chloride and then the esterification reaction in methanol, or 2-MPC can be directly synthesized from pyrrole and methyl chloroformate,(2) the insertation of CO2 to pyrrole for the corresponding 1-pyrrole carboxylic acid or 2-pyrrole carboxylic acid and then the esterification reaction in methanol.

两种吡咯甲酸甲酯的合成从吡咯为起始原料有两种方法：（1）使用酰氯将吡咯酰化，然后与甲醇完成酯化反应，或者吡咯与氯甲酸甲酯直接合成吡咯甲酸甲酯；（2）先将吡咯通过CO2插入反应得到1-吡咯甲酸或2-吡咯甲酸，然后与甲醇反应完成酯化。

Isoamyl isovalerate was synthesized through esterification reaction by using isovaleric acid and isoamyl alcohol as raw materials and nano-H4SiW12O40/SiO2 as catalyst, the influencing factors in the reaction were studied, and the results showed that the esterification rate could reach 98.6 % under the conditions of the ratio of alcohol-acid 1.4∶1, the use level of catalyst 5 %, and the reaction time 1.5 h.

以纳米复合钨硅杂多酸为催化剂，异戊酸和异戊醇为原料，通过酯化反应合成苹果油，对酯化反应的影响因素进行了研究，结果表明，在醇酸物质的量比为1.4∶1，催化剂用量5%，反应时间1.5h的条件下，酯化率可达98.6%。

Poly/montmorillonite/2-Carboxyethyl phosphinic acid (PET/MMT/CEPP) nanocomposites were prepared through direct-esterification process by adding reactive flame retardant before esterification, and organic MMT was added before polycondensation.

采用直接酯化法，将共聚型阻燃剂羧乙基苯基次磷酸和对苯二甲酸以及乙二醇混合后酯化，在酯化产物中加入经过有机改性的蒙脱土，缩聚制备了阻燃聚酯／蒙脱土纳米复合材料(PET/MMT/CEPP)。

As to the high polarity, high boiling point resultant—trimesic acid, the analysis methods of infrared spetrum, gas chromatography-mass spectroscopy, vapour-phase chromatography, acid number titration and so on are seperately used to characterize its property. Infrared spetrum and gas chromatography-mass spectroscopy are used to have a qualitative analysis on the resultant and are compared with the stand diagram. Sulfuric acid-methanol esterification and rapid esterification are used to prepare the trimesic acid trimethyl-ester and have a FID quantitative analysis. So that we make sure the purity of trimesic acid in the resultant and also we have an acid alkali titration on the resultant to get its acid number, in order to verify the purity of trimesic acid in the resultant.

对于高极性、高沸点的固体产物均苯三甲酸，分别采用红外光谱、气质联用、气相色谱、酸值滴定等分析手段进行了表征：利用红外光谱、气质联用的方法进行产物的定性分析，并与在同一仪器、同一条件下做出的标准谱图进行比对；采用硫酸-甲醇酯化法和快速酯化法制备出均苯三甲酸三甲酯，对其进行气相色谱FID定量分析，进而确定固体产物中均苯三甲酸的纯度；用酸碱滴定法确定固体产物的酸值，以对固体产物中均苯三甲酸的纯度进行验证。

The optimal conditions determineded by experiments were as follow: chloracetic acid : sodium carbonate : isopropyl xanthate : ethylamine=l : 0.58 : 1 : 1.05, water usage is 30 ml/O.lmol chloracetic acid, esterification temperature was 80癈, esterification time was 2h, ammonolysis temperature was 70 C, ammonolysis time was Ih.

实验得出最佳工艺条件为：一氯乙酸：碳酸钠：异丙基黄药：乙胺=1：0.58：1：1.05，水用量为30 ml／0.1mol一氯乙酸，酯化温度80℃，酯化时间2小时，氨解温度70℃，氨解时间1小时。

A set of high pressure esterification reaction apparatus has been designed and established. By comparison of ten kinds of esterification catalyst, ammonium molybdate and sodium tungstate were chosen as properly catalyst of this reaction.

自行设计、安装了一套高压酯化反应装置，经比较、筛选十种酯化反应催化剂，确定钼酸铵、钨酸钠为该反应适宜的催化剂。

In esterification of 2,6-NDA obtained from Henkel reaction of 1,8-naphthalenedicarboanhydride catalyzed non-cadmium catalyst zinc carbonate, the effect of process parameters like esterification catalyst and its amount used, reaction temperature and time, and methanol/anhydride molar ration, etc, was investigated.

在碳酸锌催化和二氧化碳气氛中1，8-萘二甲酸酐于300～340℃反应3～4小时，可以较高收率地获得2，6-萘二甲酸粗品，收率达到62％，该产物可以直接用于合成双酯的酯化反应中。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。