查询词典 esterification

The amidation and esterification of different cyclic anhydride s with aniline and phenol gave different major products,and the routes were optimized.

结果表明，环酐的分子结构直接影响反应结果，当酸酐分子存在共轭结构时以N-芳基内酰胺为主要产物。

From the optically active 2, 2'-dihydroxy-1,1 '-binaphthyl, through esterification, Kumada coupling, bromization, hydrolization and Wittig elimination reaction, 2,2'-diethynyl-1,1'-binaphthyl was obtained.

从光学活性的2，2'-二羟基-1，1'-联萘出发，经过酯化，Kumada偶联，溴化，水解和Wittig消除反应五个步骤，成功地获得了具有单一手性的的2，2'-二乙炔基-1，1'-联萘。

Starting from 3, 5-dihydroxybenzoic acid, a total of 16 kinds of salicylicaldehyde derivatives have been synthesized by the esterification, substitution, reduction, formylation, condensation, brominate, functional group protection and deprotection reactions, of which 11 have not been reported yet. Enatiomerically pure 2-amino-2'-hydroxy-1, 1'-binaphthyl has been easily obtained from its racemic mixture by the eantioselective formation of inclusion crystals with N-benzylcinchoninium chloride.

树枝状大分子希夫碱三齿手性配体的设计与合成从3，5-二羟基苯甲酸出发，通过酯化、取代、还原、甲酰化、缩合、官能团的保护与去保护等反应合成了四个系列16种水杨醛衍生物，其中11中是未见文献报道的新化合物。

Bornyl oxalate was formed smoothly by esterification of β-pinene with anhydrous oxalic acid using solid superacid as catalyst. Borneol was obtained by saponification of bornyl oxalate with NaOH solution.

在固体超强酸催化作用下β-蒎烯和无水草酸平稳地发生酯化反应，生成草酸龙脑酯；加入氢氧化钠溶液发生皂化反应得到龙脑。

The total synthesis of the title compound 10 was accomplished starting from 3,5-dimethoxybenzoic acid (1) and p-hydroxybenzaldehyde (6). In the process, esterification, reduction, bromination and Wittig-Homer reaction were performed.

以3，5-二甲氧基苯甲酸为起始原料，经过甲醇酯化、氢化铝锂还原、四溴化碳溴代和Wittig-Homer反应，高产率的合成了Wittig-Homer试剂(5)。

The target compound 1 was successfully prepared via esterification, reduction, bromization and cyanation processes by using L--malic acid (2), which is an inexpensive and easily available starting material. The overall yield was 56.7%.

以廉价、易得的L--苹果酸为起始原料，经酯化、还原、溴代和氰化四步反应得到目标化合物-4-氰基-3-羟基丁酸乙酯，合成总收率为56.7%。

The overall yield was 43.6%.The yield of reduce of ester was increased nearly one times than the past method because of KBH4-LiCl as the reducing agent instead of NaBH4. Changing the reaction conditions of bromization, the one-way yield enhanced 30%. The yield of reduce of the bromide was added by one times by improving the process. Tefluthrin was achieved by the catalytic esterification of DCC and DMAP.

优化后工艺对四氟对苯二甲酯的还原采用了廉价高效的还原试剂KBH4-LiCl，使收率比NaBH4法提高了近一倍；对溴化反应条件进行了优化，单程收率提高了30%；对溴化物还原条件的优化，使其收率提高了近一倍；采用了催化剂DCC和DMAP合成了最终产品七氟菊酯。

Study on an efficient process for the preparation of trifloxystrobin starting from 2-methylacetophenone bypartial oxidation,esterification,reaction with methoxyamine,bromization and condensation with 3'- acetophenone oxime.

以邻甲基苯乙酮为原料，经过高锰酸钾的碱性氧化，甲醇酯化，再与甲氧基胺盐酸盐肟化后，用N-溴丁二酰亚胺溴化，最后和间三氟甲基苯乙酮肟缩合得到目标产物肟菌酯。

Oxo-(4-solanesylaminophenyl)retinoate was successively synthesized from 13-cis-retinoic acid and solanesol by oxidation, bromization and esterification.

以异维A酸和茄尼醇为原料，经氧化、溴化、酯化等一系列反应合成了4-羰基异维A酸(4-N-茄尼基氨基苯酚)酯，其结构经1H NMR，IR和MS表征。

Novel sodium 2-2-(alkylaryloxy-alkylamidoethanesulfonates (m+nAr-T, m, n: carbon numbers; Ar: aromatic nucleus; T: taurine) with high purity were synthesized through bromization, esterification, Fries rearrangement, Pd-catalyzed hydrogenation, Williamson reaction, and acylation, et al, using carboxylic acid, phenol and taurine as starting materials. The structures and purities were characterized.

以羧酸、苯酚和牛磺酸为原料，通过溴代反应、酯化反应、Fries重排反应、催化氢化反应、Williamson反应以及催化酰胺化反应等过程，首次成功合成并表征了系列结构明确的高纯度N-酰基牛磺酸钠(m+nAr-T，m、n为烷基链碳数，Ar为芳环，T表示taurine)。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。