查询词典 equilibria

The enthalpic term is dominant in the determination of tautomeric equilibria.

讨论了水溶剂化作用对异构体的能量、电荷分布和偶极矩的影响。

The entropy effect on the Gibbs free energy of 5-fluorouracil and 5-chlorouracil is very small and there is little significance for the tautomeric equilibria.

讨论了水溶剂化作用对异构体的能量、电荷分布和偶极矩的影响。

The results are in good agreement with available experimental results. The entropy effect on the Gibbs free energies of 6-thioxanthine base is very small and there is little significance for the tautomeric equilibria of the base.

计算结果同已有实验结果一致。6-硫代黄嘌呤异构化的熵效应小，对互变异构平衡几乎没有显著的影响，而焓变对互变异构产生了主要的影响。

In the first part, the prototropic hydroxy-oxo tautomerisms of 2 (1H)- pyridones/2-hydorxypyridines, one of the most important model systems in molecular biology, have been investigated with self-consistent reaction field method based on continuum model. The influence of the nature and position of substituent groups, the existence of intramolecular hydrogen bonding and tautomeric competition between 2-hydroxy and 4-hydroxy on the tautomeric equilibria have also been examined.

第一部分，首先从溶剂敏感的异构化性质入手，用基于连续介质的自洽反应场理论方法对一类重要的生化模型体系—2（1H）-吡啶酮／2-羟基吡啶互变异构体系进行了研究，系统地考察了取代基性质、取代基位置、分子内氢键的形成以及互变异构竞争的存在对异构化平衡的影响。

The results obtained form theoretical calculations indicate that the hydroxyl-tautomer predominate in the gas phase or nonpolar solvents, while in solvents of high dielectric constant, the tautomeric equilibria is shift in favor of the oxo-tautomer can be mainly ascribed to the polarization effects.

结果表明，2（1H）-吡啶酮类化合物在极性溶剂中表现出与气相或非极性溶剂中截然不同的的优势结构主要是由于各异构体分子极性上的差异引起的。

The total energy, standard enthalpy, standard entropy and standard free energy were obtained. The calculations show that 5-fluorouracil and 5-chlorouracil existing as the dione forms are the predominant isomers in the gas and aqueous phases. The entropy effect on the Gibbs free energy of 5-fluorouracil and 5-chlorouracil is very small and there is little significance for the tautomeric equilibria.

Onsager反应场溶剂模型用于水相的计算计算结果表明，5-氟尿嘧啶和5-氯尿嘧啶在气相中和水相中主要以双酮形式存在5-氟尿嘧啶和5-氯尿嘧啶的熵效应小，对互变异构平衡没有显著的影响，而焓变对互变异构产生了主要的影响。

Results showed that extraction abilities depends on the hydrophobic of solutes which pK〓 values are similar, e. g. acetic, propionic, butyric and valeric acids, while pK〓 values affect dominantly the extraction abilities of acids with similar hydrophobic, e. g. formic, acetic, chloroacetic, dichloroacetic, and trichloroacetic acids. Meanwhile, diluents and TOA concentration also affect the extraction equilibria of acids through the specific basicity of TOA .

TOA对酸性差别很小的一元羧酸如乙酸、丙酸、丁酸、戊酸的萃取能力主要取决于羧酸的疏水性参数logP；TOA对疏水性参数差别较小的羧酸如甲酸、乙酸、一氯乙酸、二氯乙酸、三氯乙酸的萃取能力主要取决于羧酸的电性参数；稀释剂的种类、TOA的浓度都会影响TOA的表观碱度pH〓，并通过TOA的表观碱度影响羧酸的萃取平衡。

The present paper mainly focused on the phase equilibria and crystallization separation of the multi-component aqueous salt system for cleaner production of chromium trioxide in the electro-synthesis process. And these diagrams of the above system was studied for the first time.

本文研究了该产业链中电催化法生产铬酸酐清洁工艺中多元水盐体系相平衡，首次构筑了体系相图，建立了铬酸酐多元复杂体系的结晶分离方法，为电催化法生产铬酸酐工艺路线的设计及优化提供理论依据，论文的主要内容包括如下几个方面： 1。

Rubber sheathed flexible cable with intermediate frequency, low-consumption and equilibria for aviation

航空用中频低耗平衡橡套软电缆适用于中频 400HZ ，交流额定电压 250V 及以下的航空机场供电及检测电器用的连接线

By rescaling the system,we obtain the Lorenz-Stenflo system with slow variation of the flow rotation. Based on Routh-Hurwitz criteria,the stabilities of the equilibria are analyzed and the bifurcation sets are sought to divide the parameter plane into different regions,corresponding to different types of the solutions.

通过对系统的重新标度，得到了气流旋转缓慢变化时的Lorenz-Stenflo系统；基于Routh-Hurwitz准则，分析了平衡点的稳定性问题，得到了参数平面上的分岔集，这些分岔集将参数平面划分为不同的区域，在各个不同的区域对应于系统不同的解。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。