查询词典 enolate

The chelating ability of its enolate anion (TTF-ph-tfac) has been investigated with [MIICl_2·xH_2O] (M = Zn and Co) leading to complexes Zn(TTF-ph-tfac)_2(CH_3OH)_2 (7) and Co(TTF-ph-tfac)_2(CH_3OH)_2 (8), where the metal center is coordinated by two TTF-ph-tfac ligands. This redox active ligand shows promising features for the elaboration of hybrid organic-inorganic building blocks.

具有反铁磁行为的化合物5在110-120K观察到了相转变的发生，是目前已报道的该类化合物中最高的相变温度。3、TTF-ph-tfac烯醇阴离子具有很强的配位能力，与金属氯化物螯合配位分别生成了配合物Zn(TTF-ph-tfac)_2(CH_3OH)_2 (7)和Co(TTF-ph-tfac)_2(CH_3OH)_2 (8)，每个中心金属都桥连两个TTF-ph-tfac配体。

Subsequently,enol methylation of P in basic condition completed the synthesis of malyngamide O.Applied this route to the synthesis of malyngamides Q and R,the chiral unsaturated acid was connected with the vinyl chloride part by amidation,then the resulting product was converted into the corresponding aldehyde,followed by aldol condensation of the aldehyde with the chlorotitanium enolate of pyrrolidone to complete the skeleton of malyngamides Q and R,then the synthesis of them was completed via enol methylation in acid condition.

该合成路线拓展应用到malyngamides Q和R的合成时，首先用酰胺键将手性不饱和脂肪酸和烯氯片段连接，再转化成相应的醛，与乙酰基吡咯酮进行TiCl_4催化的aldol反应即得到malyngamides Q和R的骨架结构，再经过酸催化的烯醇甲基化反应完成了Q和R的全合成。

In Granards' reactionof fluorinated β-ketophosphonium salts we found differentGranard reagents give different reaction mechanisms andPhMgBr realized the enolate reaction of fluorinatedβ-keto-phosphonium salts.

在研究含氟β-酮基鏻盐的β位亲核加成反应中，我们利用含氟α-烷氧基-β-酮基鏻盐与有机锂试剂的亲核加成反应一锅法高度立体选择性地合成了E式或Z式三氟甲基的烯醚类化合物。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。