查询词典 enol

Additionally, the quantum chemical study on the isomeriaation mechanism of the enol ester of 2-acyl-l,3-cyclohexanedione was performed, which was discovered by Yang when he synthesized the derivate of 2-acyl-l,3-cyclohexanedione.

第三部分工作是对杨定亚在合成2-酰基-1，3-环己二酮类化合物的衍生物时意外发现的烯酯异构化反应机理进行了研究。

The results showed that the ligand DBM was coordinated to the metal ions acting as the enol form isomer, the main absorption peaks of the ligands in IR, UV spectra were bathochromic due to the influence of chelating effect.

研究表明：配体DBM以烯醇式异构体与金属离子螯合，受螯合效应的影响，配体的IR、UV特徵吸收峰均发生红移，染料在540nm~400nm近紫外区有强烈的电子吸收。

Over the years, Masson's food additive brand -"Silver Valley" has been at the forefront of China Food Additive Industry forefront of the reform In 1984, the first in the domestic market development and production of soybean products for human consumption antifoamer; in 1988, took the lead in the domestic market development and production of edible spices - cyclopentyl enol methyl ketone; in 1989, took the lead in the domestic market to develop speed-fat cake oil; In 1992, the first in the domestic market development and production of ice cream and beverage emulsion stabilizer; in 1999, introduced the internationally advanced level molecular distillation Monoglyceride domestic exclusive CPP realize industrial production

多年来，美晨公司的食品添加剂品牌--"银谷"一直站在中国食品添加剂工业改革的潮头 1984年，率先在国内市场开发生产豆制品食用消泡剂；1988年，率先在国内市场开发生产食用香料--甲基环戊烯醇酮；1989年，率先在国内市场开发速发蛋糕油；1992年，率先在国内市场开发生产冰淇淋和饮料乳化稳定剂；1999年，推出具有国际先进水平的分子蒸馏单甘酯，在国内独家实现CPP工业化生产

Since the aldehyde groups can be reversibly converted into enol groups depending on acidity and alkalescence of environment, the inter-and intra-molecule interaction of CMDA can be adjusted by changing the pH of medium, as a result, the self-assembly behavior of CMDA may be altered.

结果表明，CMDA在水中自组装形成纳米自聚集体，在pH=4.0和pH=10.83溶液中CMDA的临界聚集量浓度值分别为0.002mg／mL和0.005mg／mL，比中性环境中的临界聚集量浓度（0.02mg／mL）低了1个数量级。3种pH条件下自聚集体溶液表面张力具有共同的变化趋势，但在酸性与碱性条件下具有更好的表面活性。

A novel carbonyl transposition led by anilines'nucleophilic addition to methyl 2-keto α-D-glucopyranoside was discovered. And the mechanism of the reaction concerned to an enol rearrangment was provided through tracing the change of 〓H-NMR and 〓C-NMR of a hemiacetal intermediate which was obtained in the reaction of o-phenylene diamine with 2-keto glycoside. Both the intermediate and the converting product were identified by 〓H-NMR,〓C-NMR,〓H-〓H COSY and HMQC.

一、发现了2-位氧化α-甲基D-葡萄糖苷的芳胺亲核加成引起羰基转位的新方法，利用核磁共振氢谱及碳谱对邻苯二胺与2-位氧化α-甲基D-葡萄糖苷加成生成的稳定中间体半缩酮化合物在氘代丙酮中的变化进行跟踪，结合对转化产物的氢氢相关谱和HMQC结构确证，提出了该反应中2-位羰基通过烯醇化互变而转至3-位的机理并得到了验证。

Nsted acid for the activation of the imine and acetic acid (20 mol %) as the non-chiral proton source for the shift of the keto-enol equilibrium.

94%酸、活化的亚胺乙酸(20摩尔%)的非手质子源为转移的酮-烯醇平衡。

Co2+,Mn2+ and Pb2+ ions performed headgroup configurational changeof keto→zwitterion→enol form and coordination to Schiff base moiety in LB films ismore difficult and it is more easy that Ni2+ ion coordinate to SBC18 in LB film bypenetrating to LB films.

FTIR透射光谱和UV-vis电子吸收光谱进一步证实了π-A等温线的宏观结果，即两组分间的吸引主要来源于头基间的相互租用，为以后研究混合膜的性质和功能提供了一定的依据。2。

The method based on CE is simple and fast, and can be used to study the kinetics of keto-enol tautomerism of other compounds.

所建立的方法简单、快速，可以被用于其他羰基化合物的烯醇互变动力学研究。

Understand keto-enol tautomerism, reactivity of enolate ions.

A5 E3J3 了解酮－烯醇互变异构性，烯醇离子的反应性。

Capillary electrophoresis, enantioseparation, on-line preconcentration, keto-enol tautomerism

中文关键词：毛细管电泳，手性拆分，在线富集，烯醇互变动力学

It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发，分析对称连杆曲线上鲍尔点的产生条件，提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品，年生产总值3000万美元，产品价廉物美、选料上乘、质量保证，深受国内外客户的青睐