查询词典 elemental analysis

Yields from chiral bisoxazolines (5a) with diethyl oxalate using NaOCH〓 as base for the first time. The structures of chiral multioxazolines and their intermediates, multi (β-hydroxylamide) s, were characterized by 〓H NMR, IR, mass spectra and elemental analysis. The catalytic activities and enantioselectivities of chiral multi (β-hydroxylamide) s (4) and chiral multioxazolines (5～8) were investigated by using acetophenone and β-acetonaphthone as former chiral ketone, KBH〓 or NaBH〓 as reductive reagent in chapter three.

在此基础上，对合成方法作了创新，以羧酸或酯为原料，在无催化剂的条件下与手性α-氨基醇反应，通过回流分水或脱醇的方法，一步反应合成了手性多噁唑啉（5～8），产率为89.2%～98.4%；以手性双噁唑啉（5a）为原料，在NaOCH〓的作用下，与草酸二乙酯反应，首次合成了呋喃类双嗯唑啉（6a），产率为72.9%～75.6%。

Chemiluminescent immunoassay is one of the advanced immunoassay ofnon-radioisotopic immunoassay because of its high sensitivity, wide dynamic range,high accuracy, stable labeled protein, full automation and extensive application field.CLIA using acridinium ester derivatives as chemiluminescent label has advantages oflow background, high signal-to-noise ratio, no need of catalyst and simpleluminescence system. Different aspects associating the DMAE·NHS-based CLIA were studied in thisthesis, including synthesis of acridinium ester, chemiluminescentcharacteristics of DMAE·NHS, labelling antibody or streptavidin with DMAE·NHS,two-site sandwich chemiluminescent immunoassay for TSH, two-sitesandwich chemiluminescent immunoassay involved biotin-streptavidinsystem for TSH, and competitive chemiluminescent immunoassay usingbiotin-streptavidin system for TT〓. The desired acridinium ester, DMAE·NHS, was synthesized according to thereference method with some modifications. The products were identified by IR, NMR,MS and elemental analysis. In our method, KOH was used in place of NaOH tosynthesize benzyl ester of 3,5-dimethyl-4-hydroxybenzoic acid,2',6'-dimethyl-4'-(n-succinimidyloxycarbonyl) phenyl-acridinium-9-carboxylate waspurified on a silica gel column with chloroform/ethylacetate(4:1, v/v) as eluent andfurther purified by triturating with hexane/acetone(2:1, v/v).

DMAE·NHS的合成是本论文的关键和难点，我们对文献方法进行改进：文献方法用氢氧化钠与3，5-二甲基-4-羟基苯甲酸反应制得3，5-二甲基-4-羟基苯甲酸钠，再用3，5-二甲基-4-羟基苯甲酸钠与苄氯作用制备3，5-二甲基-4-羟基苯甲酸苄酯，我们用氢氧化钾代替氢氧化钠，使合成取得成功；在合成2'，6'-二甲基-4'-苯基-吖啶-9-甲酸酯时，文献方法对粗产品进行两次硅胶柱层析纯化，第一次柱层析用氯仿／乙酸乙酯(4∶1，V∶V)作溶剂和淋洗剂，第二次柱层析用己烷／丙酮(2∶1，V∶V)作溶剂和淋洗剂，按照文献方法得到的不是所需要的化合物，我们只进行第一次柱层析纯化，然后用己烷／丙酮(2∶1，V∶V)进行研磨，过滤，洗涤，除去溶于己烷／丙酮(2∶1，V∶V)的部分，得到所需要的产品。

In search of environmentally benign insecticides with high activity, low toxicity and low residue, a novel series of anthranilic acid esters containing N-pyridylpyrazole were designed and synthesized. All of the compounds were characterized and confirmed by IR, 1H NMR, MS and elemental analysis.

设计，合成了8个新的含N-吡啶基吡唑杂环的邻氨基苯甲酸酯类化合物，结构经FTIR， MS， 1H NMR 和元素分析确证，并且采用X-射线衍射分析方法确证了具有较好生物活性的化合物14d的结构。

One of the reaction products in the solid state reaction between silver behenate and phthalic acid — di-silver phthalate (Ag2PA) was prepared by liquid deposition method, and was characterized with elemental analysis, ICP-AES and FT-IR.

采用液相沉淀法合成了山嵛酸银与邻苯二甲酸的固相反应产物邻苯二甲酸二银，并通过元素分析、ICP-AES、FT-IR等方法对其进行了表征分析。

2,7-di-diphenylamine-spiro[fiuorene -7,9'-benzofluorene] was successfully synthesized .Its structure was determined by 1HNMR、MS、IR and Elemental Analysis.Yield of each reaction was more than 70%.

设计并合成了一种新型的含二苯胺基团的螺芴化合物2，7-双二苯胺-螺环-[芴-7，9'-苯并芴]，并通过了1HNMR、MS、IR、元素分析图谱检验，每步反应的产率均在70%以上。

Four novel benzothiazole-phosphites were prepared from benzothiazole derivatives. Their structures were confirmed by IR, NMR and elemental analysis.

为了寻找具有更高杀菌活性的化合物，将苯并噻唑衍生物与亚磷酸反应，得到了4个苯并噻唑衍生物的亚磷酸盐，其结构均经IR、NMR及元素分析确证。

BAReO (boronic acid adducts of rhenium dioxime) complexes were synthesized and characterized with IR and UV/Vis spectra and elemental analysis. This analogous work was very helpful in under-standing the BATOs chemistry.

了为更好地了解BATO的络合物化学，又尝试合成和表征了两种类似BATO的BAReO络合物，〓和〓给出了它们的IR、UV/Vis光谱及元素分析结果。

A mixed ligand complex of manganese carbohydrazide azide, Mn2(N3)2 (CHZ=carbohydrazide), was synthesized and characterized by using elemental analysis and Fourier transform infrared spectrum.

合成了以碳酰肼为配体，以叠氮离子为混合配体的配合物：Mn2(N3)2，并对其进行了元素分析及红外表征。

Part two: Using chloroformic ester reacted with potassuim thiocyanate to get thiocyanic esters. Then reacted with biological substituted pyrimidinamine to synthesize forty two thiourea compounds, thirty eight of them are new compounds. Their structures have been charactered by IR, 1H NMR and elemental analysis.

第二部分：先以氯甲酸酯和硫氰酸钾为原料合成异硫氰酸酯，再与有生物活性的取代氨基嘧啶反应，合成了一系列新的取代嘧啶基硫脲类化合物，合成的42个化合物中有38个为首次合成的新化合物，结构经元素分析、IR及~1H NMR得到确证。

The chalcogenidometalates were characterized by elemental analysis, IR and X-ray crystallographic, and their thermal stability and optical properties were also investigated.

三、用元素分析、红外光谱、热重分析和单晶X射线衍射仪对合成的化合物进行了表征，测定了化合物的热稳定性和光学性质。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了