查询词典 electroreduction

The value of current density and the apparent active energy of electroreduction of substituted nitrobenzene depend on the electronic effect of substituted group and space resistance. o,m,p-chloronitrobenzene will be electroreduced to azoxy compounds by taking three electrons, o,m-nitrotoulene and o,m-nitrobenzoic acid will be reduced to phenol compounds by taking four electrons, and p-nitrotoulene will be reduced to the aniline by taking six electrons. According to these results, the electroreduction mechanism of the substituted aryl nitro-compounds was studied in detail.

在电还原过程中，还原峰电流和表观活化能的大小均与取代基的电子效应和空间位阻相关，同时取代硝基氯苯得3个电子将还原生成氧化偶氮苯类化合物：邻、间硝基甲苯、硝基苯甲酸得4个电子将还原生成酚类化合物；对硝基甲苯得6个电子将还原生成胺类化合物，在此基础上，探讨了各芳族硝基化合物的电还原机理。

It is found that the indirect electroreduction of maleic acid to butane diacid was achieved by Ti~/Ti~ redox system on the nanocrystalline TiO2 film surface, the electrode reaction mechanism is the called catalytic mechanism.

其中TiO_2/Ti_2O_3电对对马来酸具有异相电催化还原活性，纳米TiO_2膜中的Ti~/Ti~氧化还原电对作为媒质间接电还原马来酸为丁二酸，反应机理为电化学偶联随后化学催化反应机理。

Direct electroreduction led to the formation of the hydrodimers and saturated ester.

直接电还原生成相应的氢化二聚物和饱和酯。

It is reported that the electrolytic process of oxalic to glyoxalic acid by electroreduction on titanium cathode in this paper.

本文报道在钛阴极上草酸还原制乙醛酸的电解工艺。

The electroreduction of nitrobenzene in room temperature ionic liquid——EMimBF4 on Pt electrode was investigated.

采用循环伏安法和恒电位电解法研究了离子液体EMimBF4中硝基苯在微铂电极上的选择性电还原特性。

Effect of cathodic surface modification on oxygen electroreduction and application of the process to electrosynthesis of organic compounds and waste water treatment are idscussed in detail.

本文综述了氧阴极电还原的研究进展，着重介绍了阴极表面修饰对该过程的影响以及氧阴极电还原在有机物电合成与废水处理方面的研究进展。

The electroreduction of nitrobenzene in room temperature ionic liquidEMimBF4 on Pt electrode was investigated.

采用循环伏安法和恒电位电解法研究了离子液体EMimBF4中硝基苯在微铂电极上的选择性电还原特性。

The results showed that WC/CNT nanocomposite exhibited better catalytic activity for the electroreduction of nitrobenzene than separate WC nanoparticles and CNTs,and it also had good electrochemical stability during the process of electroreduction of nitrobenzene in acid solution.

结果表明，WC/CNT纳米复合材料对硝基苯的电催化活性优于纳米WC和CNT，且WC/CNT纳米复合材料在硝基苯电还原过程中保持良好的化学稳定性。

And the electroreduction process of nitrobenzene on WC powder electrode in basic solution is investigated by cyclic voltammetry, linear potential sweep and chronoamperometry. In the process of electroreduction of nitrobenzene on WC powder electrode, liquid phase mass transferring may be the control step.

并且也用循环伏安、线性扫描和恒电位阶跃等测试方法研究了碳化钨粉末电极在碱性介质中析氢和还原硝基苯的电化学特性，发现碳化钨在电催化还原硝基苯过程中，可能主要受反应物的液相传质控制。

The main research work of this dissertation is as follows: Based on the chemical reaction engineering theory and the nitrobenzene electroreduction mechanism, the plate and frame electrolyzer was designed and applied to the process of electroreduction nitrobenzene to p-aminophenol. This dissertation measured the residence time distribution data of the electrolyzer by means of the pulse response method and studied the rule of flow pattern along with the current capacity change. Under different conditions ,this dissertation studied the cyclic voltammetry properties of nitrobenzene on different electrodes by means of the dynamic cyclic voltammetry method and the electrode materials applied to the NB electroreduction have been selected primarily.Baseed on the results of cyclic voltammetry tests, this dissertation used p-electrode systems to measure the steady-state- polarization curves of nitrobenzene on different electrodes in H-type diaphragm cell, and obtained each primary factor s influence rule and the exchange current density value of each electrode.And then on the basis of the conclusions of fundamental researchs upword, the effects of influence factors on the the yield of p-aminophenol and the current efficiency,such as electrode material, current density, quantity of electricity circulated, nitrobenzene concentration . sulpuric acid concentration and so on, have been studied in detail in the systems of hign temperature , strong acidity and oxygen-poorthrough a series of electrolysis experiments in this paper.After all using Pb as anode Monel metal as cathode Dupont Nafion 417 cation-exchange membrane as membrane, this dissertation obtained the optimum technological condition: reaction temperature about 85C, current density 500A m-2, sulphuric acid concentration 20%wt.

论文的主要研究工作为：运用化学反应工程理论，结合硝基苯的电还原机理，设计出用于硝基苯直接电还原合成对氨基苯酚实验的板框式电解槽，并利用脉冲响应法测定了该板框式电解槽的停留时间分布数据，研究了流型随流量变化的规律；通过动态循环伏安法研究了硝基苯在不同电极上、不同条件下的循环伏安特性，初步评选出了用于硝基苯电还原的电极材料；结合循环伏安的测定结果，在H型隔膜电解槽中采用三电极体系测定了硝基苯在不同电极上、不同条件下的稳态极化曲线，得到了各主要因素的影响规律及硝基苯在各个电极上电还原的交换电流密度数值；在基础研究结论指导下，采用板框式电解槽，在高温、强酸、贫氧系统中，进行了一系列的电解实验，分别考察了电极材料、电流密度、通电量、硝基苯浓度、硫酸浓度等因素对收率及电流效率的影响，最终选择以蒙乃尔合金电极作为阴极、铅合金为阳极、Dupont Nofion 417阳离子交换膜为隔膜，得到由硝基苯直接电还原制对氨基苯酚的最佳电解工艺条件：反应温度85℃，电流密度500A·m~(-2)，硫酸浓度20％wt。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。