查询词典 electrophilic

The speed of electrophilic addition reaction of Alkene is well-connected to the nature of substituting group on C=C.

对于烯烃的亲电加成反应速度，与C=C上直接连接的取代基的性质有关。

Benzene undergoes metabolic oxidation by cytochrome P450 enzymes to form an electrophilic epoxide which can alkylate protein and DNA.

苯在细胞色素P450酶氧化代谢下，形成一种能烷化蛋白质和DNA的电环氧化物。

Electrophilic substitutions of anisole with ICl have also been theoretically studied by DFT.

ICl与苯甲醚可能存在碘化、氯化以及碘代产物-氯代产物互相转化三条反应路径。

According to the electrophilic substitution of α-Allocryptopin by ICl, it can be suggested that there are competitions of n-donors (such as N and O atom occurred in alkaloid or solvent molecules) with the conjugated π system in alkaloid molecule for iodine monochloride when charge-transfer complexes are formed, which may block the formation of pre-reactive π-complex intermediate, and thus suppress the electrophilic substitution.

这一方法标记过程简便，标记产物富集于有机相，易于进一步纯化，其放射化学纯度接近95%，标记率超过70%；ICl与α-别隐品碱的亲电碘化反应结果表明，生物碱底物或溶剂分子中的N、O等n电子给体可能与亲电试剂形成电荷转移络合物，竞争芳香亲电取代反应π络合物反应前体的形成，从而抑制碘化反应的发生。

Grasp sulphonation mechanism of aromatics, including the process of producing electrophilic particle, the process of electrophilic particle attacking aromatics, reaction dynamics and influence factor.

掌握芳香族磺化反应历程，包括产生亲电质点的过程和亲电质点进攻芳环进行磺化反应的过程、反应动力学及影响因素。

Chlorine atoms were selectively introduced into the chlorin ring based on different reactivity between vinyl group at 3-position and 20-meso position by electrophilic addition and electrophilic substitution using hydrogen peroxide/hydrochloric acid, N-chlorosuccinimide, hydrogen chloride (or concentrated hydrochloric acid) as chlorinating reagent.

以过氧化氢/盐酸、N-氯代丁二酰亚胺、氯化氢为氯化剂，根据3-乙烯基和20-meso-位的不同化学反应活性，通过亲电加成和亲电取代反应，在二氢卟吩环上选择性地引进氯原子，完成8种未见报道的具有叶绿素-a基本碳架的氯代二氢卟吩衍生物的合成。

Chiral nonracemic fluoro-organic molecules with a fluorine atom on a stereogenic center are readily prepared via chiral electrophilic fluorinating reagent-mediated enantioselective fluorinations, substrate-controlled enantioselective electrophilic fluorinations, chiral metal complexes and asymmetric catalyst—directed catalytic enantioselective fluorinations.

高光学活性的手性氟化物可通过手性亲电氟化试剂诱导的立体选择性氟化反应，基于底物的手性氟化反应以及手性催化剂诱导的不对称催化氟化反应等来制备。

In which actors with nucleophiles known nucleophilic substitution reaction, and the role of electrophilic reagents are known as electrophilic substitution reaction.

其中与亲核试剂作用者称为亲核取代反应，与亲电试剂作用者称为亲电取代反应。

Difficulty: The process of producing electrophilic particle and electrophilic particle attacking aromatics.

难点：产生亲电质点的过程和亲电质点进攻芳环进行磺化反应的过程。

Halogen, proton acids, sub-halogen acid are electrophilic reagents, olefin addition reaction is the electrophilic addition reaction .

卤素、质子酸，次卤酸等都是亲电试剂，烯烃的加成反应是亲电加成反应。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。